A manufacturing method for producing conductive adhesive with spherical graphene, comprising: step 1: preparing a monomer, an initiator, a dispersing agent and a solvent to manufacture a monomer mixture compound, and use using the monomer mixture compound to produce a polymer microsphere micro ball; step 2: heating pre-treatment or plasma etching pretreatment to the said polymer microsphere micro ball; step3: by chemical vapor deposition, the polymer microsphere micro ball after pre-treatment from step 2 to grow graphene on the outside surfaces of or inside the polymer microsphere micro ball, and then obtain the spherical graphene; step 4: producing an epoxy gel system made by epoxy, hardener and accelerant with a certain ratio mixing homogeneously; step 5: dispersing the spherical graphene from step 3 into the epoxy gel system to produce a pre-material of conductive adhesive withef spherical graphene; and Step 6: defoa r ming the pre-material of conductive adhesive of spherical graphene, and then obtain the conductive adhesive withef spherical graphene; wherein the plasma etching pre-treatment in step 2 is to obtain an active polymer microsphere by etching the polymer microsphere with inductively coupled plasma in sulfur hexafluoride and dioxygen, at 80-150"C for 2min-lh.

canceled

A manufacturing method for producing conductive adhesive with spherical graphene, comprising: step 1: preparing a monomer, an initiator, a dispersing agent and a solvent to manufacture a monomer mixture compound, and using use the monomer mixture compound to produce a polymer microsphere micro ball; step 2: heating pre-treatment or plasma etching pretreatment to the said polymer microsphere micro ball; step3: by chemical vapor deposition, the polymer micro ball after pre-treatment from step 2 to grow graphene inside or outside the polymer microsphere micro ball, and then obtain the spherical graphene; step 4: producing an epoxy gel system is-made by epoxy, hardener and accelerant with a certain ratio mixing homogeneously; Page 11 of 15 Application No.: 14/398,978 Attorney Docket No.: CD₁₄₁₂₀ Reply to Office Action dated Dec. 0 5, 2016 step 5: dispersing the spherical graphene from step3 into the epoxy gel system to produce a pre-material of conductive adhesive withef spherical graphene; and Step 6: defoa rrm ing the pre-material of conductive adhesive withef spherical graphene, and then obtain the conductive adhesive withef spherical graphene;, wherein in the step 1, the monomer is acrylic acid, phenylethene, methyl methacrylate or divinylbenzene; the initiator is comprising at least one from azobisisobutyronitrile or benzoyl peroxide; the dispersing agent is polyvinylpyrrolidone, polyethylene glycol, polyglycolic acid or polyacrylic acid; the solvent is comprising water and a composition mixed at least one selected from ethanol, methanol or isopropanol; wherein an amount of ratio for t he monomer to the monomer mixture polymer is between 8wt%'42wt%; an amount of ratio for the initiator to the monomer mixture polymer is between 0.1 1wt%~5.2wt%; an amount of ratio for t he dispersing agent to the monomer mixture polymer is between 4.9wt%'21wt%; an amount of ratio for the solvent to the monomer mixture polymer is between 3wt%'56wt%, wherein in the step 2, the method of the heating pre-treatment is to obtain a porous polymer microsphere micro balls by dispersing the polymer microsphere micro balls into inert atmosphere at 100-500"C for 0.5-5h;- wherein in the step 2, the method of the plasma etching pre-treatment is to obtain an active polymer microsphere micro balls by etching the polymer microsphere micro balls with inductively coupled plasma in- sulfur hexafluoride and dioxygen, at 80-150"C for 2min~ lh;- wherein in the step 3, steps of the chemical vapor deposition are dispersing the pretreated polymer microsphere micro balls after pre-treatment from the step 2 into a sealed space of chemical vapor deposition; next, inserting a mixture gas of methane, hydrogen and other auxiliary gas inside the sealed space after vacuuming; and then growing graphene on the outside surfaces of or inside the polymer microsphere balls by via heating the polymer microsphere micro ball pretreated from-in step 2 after pre-treatment by with at least one way listed as following: infrared ray, thermal radiation, laser, micro-wave, plasma body, ultraviolet ray or heat Page 12 of 15 Application No.: 14/398,978 Attorney Docket No.: CD₁₄₁₂₀ Reply to Office Action dated Dec. 0 5, 2016 induction heating; wherein a volume ratio for the methane to the mixture gas is 1 %~ 10%; a volume ratio for the hydrogen to the mixture gas is 50%'99%; the other auxiliary gas is comprising at least one selected from vapor, nitrogen, or argon; wherein in the step 4, the epoxy is bisphenol A epoxy resins E44, bisphenol A epoxy resins E51, bisphenol A epoxy resins E54, bisphenol A epoxy resins EPON₈₂₆ or bisphenol A epoxy resins EPON828; the hardener is hexahydrophthalic anhydride, tetrahydrophthalic anhydride, succinic dihydrazide, adipic acid dihydrazide, dicyandiamide or phenylenediamine; the accelerant is 2-ethyl-4-methylimidazole, imidazole, 2-methylimidazole or triethylamine; an amount o f ratio for the epoxy to the epoxy gel system is 80wt%'95wt%; an amount of ratio for the hardener to the epoxy gel system is lwt%~ 12wt%; and an amount o f ratio for the accelerant to the epoxy gel system is 0.3wt%~5wt%; Wherein in the step 5, a mass ratio for the epoxy system to the spherical graphene is 100: 2~30.

A manufacturing method for producing conductive adhesive with spherical graphene, comprising: step 1: preparing a monomer, an initiator, a dispersing agent and a solvent to manufacture a monomer mixture compound, and use using the monomer mixture compound to produce a polymer microsphere micro ball; step 2: heating pre-treatment or plasma etching pretreatment to the said polymer microsphere micro ball; step3: by chemical vapor deposition, the polymer microsphere micro ball after pre-treatment from step 2 to grow graphene on the outside surfaces of or inside the polymer microsphere micro ball, and then obtain the spherical graphene; step 4: producing an epoxy gel system made by epoxy, hardener and accelerant with a certain ratio mixing homogeneously; step 5: dispersing the spherical graphene from step 3 into the epoxy gel system to produce a pre-material of conductive adhesive withef spherical graphene; and Step 6: defoa r ming the pre-material of conductive adhesive of spherical graphene, and then obtain the conductive adhesive withef spherical graphene; wherein the plasma etching pre-treatment in step 2 is to obtain an active polymer microsphere by etching the polymer microsphere with inductively coupled plasma in sulfur hexafluoride and dioxygen, at 80-150"C for 2min-lh.

canceled

A manufacturing method for producing conductive adhesive with spherical graphene, comprising: step 1: preparing a monomer, an initiator, a dispersing agent and a solvent to manufacture a monomer mixture compound, and using use the monomer mixture compound to produce a polymer microsphere micro ball; step 2: heating pre-treatment or plasma etching pretreatment to the said polymer microsphere micro ball; step3: by chemical vapor deposition, the polymer micro ball after pre-treatment from step 2 to grow graphene inside or outside the polymer microsphere micro ball, and then obtain the spherical graphene; step 4: producing an epoxy gel system is-made by epoxy, hardener and accelerant with a certain ratio mixing homogeneously; Page 11 of 15 Application No.: 14/398,978 Attorney Docket No.: CD₁₄₁₂₀ Reply to Office Action dated Dec. 0 5, 2016 step 5: dispersing the spherical graphene from step3 into the epoxy gel system to produce a pre-material of conductive adhesive withef spherical graphene; and Step 6: defoa rrm ing the pre-material of conductive adhesive withef spherical graphene, and then obtain the conductive adhesive withef spherical graphene;, wherein in the step 1, the monomer is acrylic acid, phenylethene, methyl methacrylate or divinylbenzene; the initiator is comprising at least one from azobisisobutyronitrile or benzoyl peroxide; the dispersing agent is polyvinylpyrrolidone, polyethylene glycol, polyglycolic acid or polyacrylic acid; the solvent is comprising water and a composition mixed at least one selected from ethanol, methanol or isopropanol; wherein an amount of ratio for t he monomer to the monomer mixture polymer is between 8wt%'42wt%; an amount of ratio for the initiator to the monomer mixture polymer is between 0.1 1wt%~5.2wt%; an amount of ratio for t he dispersing agent to the monomer mixture polymer is between 4.9wt%'21wt%; an amount of ratio for the solvent to the monomer mixture polymer is between 3wt%'56wt%, wherein in the step 2, the method of the heating pre-treatment is to obtain a porous polymer microsphere micro balls by dispersing the polymer microsphere micro balls into inert atmosphere at 100-500"C for 0.5-5h;- wherein in the step 2, the method of the plasma etching pre-treatment is to obtain an active polymer microsphere micro balls by etching the polymer microsphere micro balls with inductively coupled plasma in- sulfur hexafluoride and dioxygen, at 80-150"C for 2min~ lh;- wherein in the step 3, steps of the chemical vapor deposition are dispersing the pretreated polymer microsphere micro balls after pre-treatment from the step 2 into a sealed space of chemical vapor deposition; next, inserting a mixture gas of methane, hydrogen and other auxiliary gas inside the sealed space after vacuuming; and then growing graphene on the outside surfaces of or inside the polymer microsphere balls by via heating the polymer microsphere micro ball pretreated from-in step 2 after pre-treatment by with at least one way listed as following: infrared ray, thermal radiation, laser, micro-wave, plasma body, ultraviolet ray or heat Page 12 of 15 Application No.: 14/398,978 Attorney Docket No.: CD₁₄₁₂₀ Reply to Office Action dated Dec. 0 5, 2016 induction heating; wherein a volume ratio for the methane to the mixture gas is 1 %~ 10%; a volume ratio for the hydrogen to the mixture gas is 50%'99%; the other auxiliary gas is comprising at least one selected from vapor, nitrogen, or argon; wherein in the step 4, the epoxy is bisphenol A epoxy resins E44, bisphenol A epoxy resins E51, bisphenol A epoxy resins E54, bisphenol A epoxy resins EPON₈₂₆ or bisphenol A epoxy resins EPON828; the hardener is hexahydrophthalic anhydride, tetrahydrophthalic anhydride, succinic dihydrazide, adipic acid dihydrazide, dicyandiamide or phenylenediamine; the accelerant is 2-ethyl-4-methylimidazole, imidazole, 2-methylimidazole or triethylamine; an amount o f ratio for the epoxy to the epoxy gel system is 80wt%'95wt%; an amount of ratio for the hardener to the epoxy gel system is lwt%~ 12wt%; and an amount o f ratio for the accelerant to the epoxy gel system is 0.3wt%~5wt%; Wherein in the step 5, a mass ratio for the epoxy system to the spherical graphene is 100: 2~30.

A manufacturing method for producing conductive adhesive with spherical graphene, comprising: step 1: preparing a monomer, an initiator, a dispersing agent and a solvent to manufacture a monomer mixture compound, and use using the monomer mixture compound to produce a polymer microsphere micro ball; step 2: heating pre-treatment or plasma etching pretreatment to the said polymer microsphere micro ball; step3: by chemical vapor deposition, the polymer microsphere micro ball after pre-treatment from step 2 to grow graphene on the outside surfaces of or inside the polymer microsphere micro ball, and then obtain the spherical graphene; step 4: producing an epoxy gel system made by epoxy, hardener and accelerant with a certain ratio mixing homogeneously; step 5: dispersing the spherical graphene from step 3 into the epoxy gel system to produce a pre-material of conductive adhesive withef spherical graphene; and Step 6: defoa r ming the pre-material of conductive adhesive of spherical graphene, and then obtain the conductive adhesive withef spherical graphene; wherein the plasma etching pre-treatment in step 2 is to obtain an active polymer microsphere by etching the polymer microsphere with inductively coupled plasma in sulfur hexafluoride and dioxygen, at 80-150"C for 2min-lh.

canceled

A manufacturing method for producing conductive adhesive with spherical graphene, comprising: step 1: preparing a monomer, an initiator, a dispersing agent and a solvent to manufacture a monomer mixture compound, and using use the monomer mixture compound to produce a polymer microsphere micro ball; step 2: heating pre-treatment or plasma etching pretreatment to the said polymer microsphere micro ball; step3: by chemical vapor deposition, the polymer micro ball after pre-treatment from step 2 to grow graphene inside or outside the polymer microsphere micro ball, and then obtain the spherical graphene; step 4: producing an epoxy gel system is-made by epoxy, hardener and accelerant with a certain ratio mixing homogeneously; Page 11 of 15 Application No.: 14/398,978 Attorney Docket No.: CD₁₄₁₂₀ Reply to Office Action dated Dec. 0 5, 2016 step 5: dispersing the spherical graphene from step3 into the epoxy gel system to produce a pre-material of conductive adhesive withef spherical graphene; and Step 6: defoa rrm ing the pre-material of conductive adhesive withef spherical graphene, and then obtain the conductive adhesive withef spherical graphene;, wherein in the step 1, the monomer is acrylic acid, phenylethene, methyl methacrylate or divinylbenzene; the initiator is comprising at least one from azobisisobutyronitrile or benzoyl peroxide; the dispersing agent is polyvinylpyrrolidone, polyethylene glycol, polyglycolic acid or polyacrylic acid; the solvent is comprising water and a composition mixed at least one selected from ethanol, methanol or isopropanol; wherein an amount of ratio for t he monomer to the monomer mixture polymer is between 8wt%'42wt%; an amount of ratio for the initiator to the monomer mixture polymer is between 0.1 1wt%~5.2wt%; an amount of ratio for t he dispersing agent to the monomer mixture polymer is between 4.9wt%'21wt%; an amount of ratio for the solvent to the monomer mixture polymer is between 3wt%'56wt%, wherein in the step 2, the method of the heating pre-treatment is to obtain a porous polymer microsphere micro balls by dispersing the polymer microsphere micro balls into inert atmosphere at 100-500"C for 0.5-5h;- wherein in the step 2, the method of the plasma etching pre-treatment is to obtain an active polymer microsphere micro balls by etching the polymer microsphere micro balls with inductively coupled plasma in- sulfur hexafluoride and dioxygen, at 80-150"C for 2min~ lh;- wherein in the step 3, steps of the chemical vapor deposition are dispersing the pretreated polymer microsphere micro balls after pre-treatment from the step 2 into a sealed space of chemical vapor deposition; next, inserting a mixture gas of methane, hydrogen and other auxiliary gas inside the sealed space after vacuuming; and then growing graphene on the outside surfaces of or inside the polymer microsphere balls by via heating the polymer microsphere micro ball pretreated from-in step 2 after pre-treatment by with at least one way listed as following: infrared ray, thermal radiation, laser, micro-wave, plasma body, ultraviolet ray or heat Page 12 of 15 Application No.: 14/398,978 Attorney Docket No.: CD₁₄₁₂₀ Reply to Office Action dated Dec. 0 5, 2016 induction heating; wherein a volume ratio for the methane to the mixture gas is 1 %~ 10%; a volume ratio for the hydrogen to the mixture gas is 50%'99%; the other auxiliary gas is comprising at least one selected from vapor, nitrogen, or argon; wherein in the step 4, the epoxy is bisphenol A epoxy resins E44, bisphenol A epoxy resins E51, bisphenol A epoxy resins E54, bisphenol A epoxy resins EPON₈₂₆ or bisphenol A epoxy resins EPON828; the hardener is hexahydrophthalic anhydride, tetrahydrophthalic anhydride, succinic dihydrazide, adipic acid dihydrazide, dicyandiamide or phenylenediamine; the accelerant is 2-ethyl-4-methylimidazole, imidazole, 2-methylimidazole or triethylamine; an amount o f ratio for the epoxy to the epoxy gel system is 80wt%'95wt%; an amount of ratio for the hardener to the epoxy gel system is lwt%~ 12wt%; and an amount o f ratio for the accelerant to the epoxy gel system is 0.3wt%~5wt%; Wherein in the step 5, a mass ratio for the epoxy system to the spherical graphene is 100: 2~30.

A manufacturing method for producing conductive adhesive with spherical graphene, comprising: step 1: preparing a monomer, an initiator, a dispersing agent and a solvent to manufacture a monomer mixture compound, and use using the monomer mixture compound to produce a polymer microsphere micro ball; step 2: heating pre-treatment or plasma etching pretreatment to the said polymer microsphere micro ball; step3: by chemical vapor deposition, the polymer microsphere micro ball after pre-treatment from step 2 to grow graphene on the outside surfaces of or inside the polymer microsphere micro ball, and then obtain the spherical graphene; step 4: producing an epoxy gel system made by epoxy, hardener and accelerant with a certain ratio mixing homogeneously; step 5: dispersing the spherical graphene from step 3 into the epoxy gel system to produce a pre-material of conductive adhesive withef spherical graphene; and Step 6: defoa r ming the pre-material of conductive adhesive of spherical graphene, and then obtain the conductive adhesive withef spherical graphene; wherein the plasma etching pre-treatment in step 2 is to obtain an active polymer microsphere by etching the polymer microsphere with inductively coupled plasma in sulfur hexafluoride and dioxygen, at 80-150"C for 2min-lh.

canceled

A manufacturing method for producing conductive adhesive with spherical graphene, comprising: step 1: preparing a monomer, an initiator, a dispersing agent and a solvent to manufacture a monomer mixture compound, and using use the monomer mixture compound to produce a polymer microsphere micro ball; step 2: heating pre-treatment or plasma etching pretreatment to the said polymer microsphere micro ball; step3: by chemical vapor deposition, the polymer micro ball after pre-treatment from step 2 to grow graphene inside or outside the polymer microsphere micro ball, and then obtain the spherical graphene; step 4: producing an epoxy gel system is-made by epoxy, hardener and accelerant with a certain ratio mixing homogeneously; Page 11 of 15 Application No.: 14/398,978 Attorney Docket No.: CD₁₄₁₂₀ Reply to Office Action dated Dec. 0 5, 2016 step 5: dispersing the spherical graphene from step3 into the epoxy gel system to produce a pre-material of conductive adhesive withef spherical graphene; and Step 6: defoa rrm ing the pre-material of conductive adhesive withef spherical graphene, and then obtain the conductive adhesive withef spherical graphene;, wherein in the step 1, the monomer is acrylic acid, phenylethene, methyl methacrylate or divinylbenzene; the initiator is comprising at least one from azobisisobutyronitrile or benzoyl peroxide; the dispersing agent is polyvinylpyrrolidone, polyethylene glycol, polyglycolic acid or polyacrylic acid; the solvent is comprising water and a composition mixed at least one selected from ethanol, methanol or isopropanol; wherein an amount of ratio for t he monomer to the monomer mixture polymer is between 8wt%'42wt%; an amount of ratio for the initiator to the monomer mixture polymer is between 0.1 1wt%~5.2wt%; an amount of ratio for t he dispersing agent to the monomer mixture polymer is between 4.9wt%'21wt%; an amount of ratio for the solvent to the monomer mixture polymer is between 3wt%'56wt%, wherein in the step 2, the method of the heating pre-treatment is to obtain a porous polymer microsphere micro balls by dispersing the polymer microsphere micro balls into inert atmosphere at 100-500"C for 0.5-5h;- wherein in the step 2, the method of the plasma etching pre-treatment is to obtain an active polymer microsphere micro balls by etching the polymer microsphere micro balls with inductively coupled plasma in- sulfur hexafluoride and dioxygen, at 80-150"C for 2min~ lh;- wherein in the step 3, steps of the chemical vapor deposition are dispersing the pretreated polymer microsphere micro balls after pre-treatment from the step 2 into a sealed space of chemical vapor deposition; next, inserting a mixture gas of methane, hydrogen and other auxiliary gas inside the sealed space after vacuuming; and then growing graphene on the outside surfaces of or inside the polymer microsphere balls by via heating the polymer microsphere micro ball pretreated from-in step 2 after pre-treatment by with at least one way listed as following: infrared ray, thermal radiation, laser, micro-wave, plasma body, ultraviolet ray or heat Page 12 of 15 Application No.: 14/398,978 Attorney Docket No.: CD₁₄₁₂₀ Reply to Office Action dated Dec. 0 5, 2016 induction heating; wherein a volume ratio for the methane to the mixture gas is 1 %~ 10%; a volume ratio for the hydrogen to the mixture gas is 50%'99%; the other auxiliary gas is comprising at least one selected from vapor, nitrogen, or argon; wherein in the step 4, the epoxy is bisphenol A epoxy resins E44, bisphenol A epoxy resins E51, bisphenol A epoxy resins E54, bisphenol A epoxy resins EPON₈₂₆ or bisphenol A epoxy resins EPON828; the hardener is hexahydrophthalic anhydride, tetrahydrophthalic anhydride, succinic dihydrazide, adipic acid dihydrazide, dicyandiamide or phenylenediamine; the accelerant is 2-ethyl-4-methylimidazole, imidazole, 2-methylimidazole or triethylamine; an amount o f ratio for the epoxy to the epoxy gel system is 80wt%'95wt%; an amount of ratio for the hardener to the epoxy gel system is lwt%~ 12wt%; and an amount o f ratio for the accelerant to the epoxy gel system is 0.3wt%~5wt%; Wherein in the step 5, a mass ratio for the epoxy system to the spherical graphene is 100: 2~30.