ELECTRODE AND POWER STORAGE DEVICE COMPRISING GRAPHENE COMPOUND | Matter42 Literature
Patent
Atlas literature
Patent
US 12,308,421 B2
ELECTRODE AND POWER STORAGE DEVICE COMPRISING GRAPHENE COMPOUND
Mayumi Mikami, Yohei Momma, Minoru Takahashi, Hiroshi Kadoma et al.
Semiconductor Energy Laboratory Co., Ltd., Kanagawa-ken (JP)·May 20, 2025·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIGS. 1A to 1C illustrate a cross section of an electrode of one embodiment of the present invention and part of the cross section of the electrode;
FIG. 2
FIG. 2 illustrates part of an electrode of one embodiment of the present invention;
FIG. 3
FIGS. 3A and 3B each illustrate an operation of a power storage device;
FIG. 4
FIG. 4 illustrates an operation of a power storage device;
FIG. 5
FIGS. 5A and 5B each illustrate a cross section of an active material;
FIG. 6
FIGS. 6A and 6B illustrate part of a cross section of an electrode;
FIG. 7
FIG. 7 illustrates a storage battery;
FIG. 8
FIGS. 8A and 8B illustrate cross-sectional views of a storage battery;
FIG. 9
FIGS. 9A and 9B illustrate a method for fabricating a storage battery;
FIG. 10
FIGS. 10A and 10B illustrate a method for fabricating a storage battery;
FIG. 11
FIG. 11 illustrates a storage battery;
FIG. 12
FIGS. 12A to 12C illustrate a radius of curvature of a surface;
FIG. 13
FIGS. 13A to 13D illustrate a radius of curvature of a film;
FIG. 14
FIGS. 14A and 14B illustrate a coin-type storage battery;
FIG. 15
FIGS. 15A and 15B illustrate a cylindrical storage battery;
FIG. 16
FIGS. 16A to 16C each illustrate part of a cross-sectional view of a storage battery;
FIG. 17
FIGS. 17A and 17B each illustrate part of a cross- sectional view of a storage battery;
FIG. 18
FIGS. 18A to 18C illustrate parts of a cross-sectional view of a storage battery;
FIG. 19
FIGS. 19A to 19C illustrate an example of a storage battery;
FIG. 20
FIGS. 20A to 20C illustrate an example of a storage battery;
FIG. 21
FIGS. 21A and 21B illustrate an example of a power storage system;
FIG. 22
FIG. 22B-1, the antennas 914 and 915 are provided on one of the opposite surfaces of the storage battery 913 with the layer 916 interposed therebetween, and as …
FIG. 23
FIGS. 23A and 23B illustrate examples of power storage systems;
FIG. 24
FIGS. 24A to 24G illustrate examples of electronic devices;
FIG. 25
FIGS. 25A to 25C illustrate an example of an electronic device;
FIG. 26
FIG. 26 illustrates examples of electronic devices;
FIG. 27
FIGS. 27A and 27B illustrate examples of electronic devices;
FIG. 28
FIG. 28 shows cycle characteristics of a storage battery; and
FIG. 29
FIGS. 29A and 29B show cycle characteristics of storage batteries.
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
2 independent · 10 dependent
1
Independentgraphene compound with formula (G₁)active material comprising element A and element M (manganese/nickel)conductive additivepower storage device (formula G1 graphene compound)
A power storage device comprising: a positive electrode; and a negative electrode over the positive electrode, wherein the positive electrode comprises: a current collector; an active material layer over and in contact with the current collector; and a layer over and in contact with the active material layer, wherein the active material layer comprises an active material and a conductive additive, wherein the layer comprises a graphene compound, wherein the active material comprises an element A and an element M, wherein the element A is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2, wherein the element M is one or more elements selected from manganese and nickel, B₂ wherein the graphene compound has a structure repre-sented by a following formula (G₁): (G₁) R₂ O O R₁ Si OH, O O G layer wherein G layer represents a graphene layer, wherein R₁ represents a substituted alkylene group, wherein R₂ represents a substituted or unsubstituted alkyl group, and wherein the substituted alkylene group comprises a substituent selected from an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 10 carbon atoms, fluorine, and trifluoromethane.
2
Dependent← claim 1graphene compound with formula (G₁)
The power storage device according to claim 1, wherein the substituted alkylene group comprises an alkylene group having 1 to 20 carbon atoms.
4
Dependent← claim 1graphene compound with formula (G₁)active material comprising element A and element M (manganese/nickel)
The power storage device according to claim 1, wherein the graphene compound is capable of trapping the element M.
The power storage device according to claim 1, further comprising: an exterior; and an electrolyte solution.
6
Dependent← claim 1graphene compound with formula (G₁)
The power storage device according to claim 1, wherein the substituted alkylene group comprises the substituent selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 1-naphthyl group, a 2-naphthyl group, fluorine, and trifluoromethane.
7
Independentgraphene compound with formula (G₂)active material comprising element A and element M (manganese/nickel)conductive additivepower storage device (formula G2 graphene compound)
A power storage device comprising: a positive electrode; and a negative electrode over the positive electrode, wherein the positive electrode comprises: a current collector; an active material layer over and in contact with the current collector; and a layer over and in contact with the active material layer, wherein the active material layer comprises an active material and a conductive additive, wherein the layer comprises a graphene compound, wherein the active material comprises an element A and an element M, wherein the element A is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2, wherein the element M is one or more elements selected from manganese and nickel, wherein the graphene compound has a structure repre-sented by a following formula (G₂): (G₂) R₂ O O R₁ Si OH, O O G layer wherein G layer represents a graphene layer, wherein R₁ represents a substituted alkylene group, wherein R₂ represents hydrogen or a substituted or unsub-stituted alkyl group, and wherein the substituted alkylene group comprises a substituent selected from an alkyl group having 1 to 6 B₂ carbon atoms, an aryl group having 6 to 10 carbon atoms, fluorine, and trifluoromethane.
8
Dependent← claim 7graphene compound with formula (G₂)
The power storage device according to claim 7, wherein the substituted alkylene group comprises an alkylene group having 1 to 20 carbon atoms.
10
Dependent← claim 7graphene compound with formula (G₂)active material comprising element A and element M (manganese/nickel)
The power storage device according to claim 7, wherein the graphene compound is capable of trapping the element M.
The power storage device according to claim 7, further comprising: an exterior; and an electrolyte solution.
12
Dependent← claim 7graphene compound with formula (G₂)
The power storage device according to claim 7, wherein the substituted alkylene group comprises the substituent selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 1-naphthyl group, a 2-naphthyl group, fluorine, and trifluoromethane. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
power storage device (formula G₁ graphene compound)
graphene compound with formula (G₁)graphene compound layer
active material comprising element A and element M (manganese/nickel)active material layer
currentcollectorcurrent collector
power storage device (formula G₂ graphene compound)
graphene compound with formula (G₂)graphene compound layer
active material comprising element A and element M (manganese/nickel)
Materials
Materials described outside the worked examples.
graphene compound with formula (G₁)
Conductive Coating Layer Material
active material comprising element A and element M (manganese/nickel)
Active Material
conductive additive
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 249
US 4,302,518 A4,302,518 A 11/1981 Goodenough et al.
US 4,668,595 A4,668,595 A 5/1987 Yoshino et al.
CN 101148263 ACN 101148263 A 3/2008
CN 102610806 ACN 102610806 A 7/2012
US 5,240,794 A5,240,794 A 8/1993 Thackeray et al.
US 5,443,929 A5,443,929 A 8/1995 Yamamoto et al.
US 5,604,396 A5,604,396 A 2/1997 Watanabe et al.
Why these are connected
Related documents with shared materials, methods, properties, or citations.
ELECTRODE AND POWER STORAGE DEVICE COMPRISING GRAPHENE COMPOUND
Mayumi Mikami, Yohei Momma, Minoru Takahashi, Hiroshi Kadoma et al.
Semiconductor Energy Laboratory Co., Ltd., Kanagawa-ken (JP)·May 20, 2025·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIGS. 1A to 1C illustrate a cross section of an electrode of one embodiment of the present invention and part of the cross section of the electrode;
FIG. 2
FIG. 2 illustrates part of an electrode of one embodiment of the present invention;
FIG. 3
FIGS. 3A and 3B each illustrate an operation of a power storage device;
FIG. 4
FIG. 4 illustrates an operation of a power storage device;
FIG. 5
FIGS. 5A and 5B each illustrate a cross section of an active material;
FIG. 6
FIGS. 6A and 6B illustrate part of a cross section of an electrode;
FIG. 7
FIG. 7 illustrates a storage battery;
FIG. 8
FIGS. 8A and 8B illustrate cross-sectional views of a storage battery;
FIG. 9
FIGS. 9A and 9B illustrate a method for fabricating a storage battery;
FIG. 10
FIGS. 10A and 10B illustrate a method for fabricating a storage battery;
FIG. 11
FIG. 11 illustrates a storage battery;
FIG. 12
FIGS. 12A to 12C illustrate a radius of curvature of a surface;
FIG. 13
FIGS. 13A to 13D illustrate a radius of curvature of a film;
FIG. 14
FIGS. 14A and 14B illustrate a coin-type storage battery;
FIG. 15
FIGS. 15A and 15B illustrate a cylindrical storage battery;
FIG. 16
FIGS. 16A to 16C each illustrate part of a cross-sectional view of a storage battery;
FIG. 17
FIGS. 17A and 17B each illustrate part of a cross- sectional view of a storage battery;
FIG. 18
FIGS. 18A to 18C illustrate parts of a cross-sectional view of a storage battery;
FIG. 19
FIGS. 19A to 19C illustrate an example of a storage battery;
FIG. 20
FIGS. 20A to 20C illustrate an example of a storage battery;
FIG. 21
FIGS. 21A and 21B illustrate an example of a power storage system;
FIG. 22
FIG. 22B-1, the antennas 914 and 915 are provided on one of the opposite surfaces of the storage battery 913 with the layer 916 interposed therebetween, and as …
FIG. 23
FIGS. 23A and 23B illustrate examples of power storage systems;
FIG. 24
FIGS. 24A to 24G illustrate examples of electronic devices;
FIG. 25
FIGS. 25A to 25C illustrate an example of an electronic device;
FIG. 26
FIG. 26 illustrates examples of electronic devices;
FIG. 27
FIGS. 27A and 27B illustrate examples of electronic devices;
FIG. 28
FIG. 28 shows cycle characteristics of a storage battery; and
FIG. 29
FIGS. 29A and 29B show cycle characteristics of storage batteries.
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
2 independent · 10 dependent
1
Independentgraphene compound with formula (G₁)active material comprising element A and element M (manganese/nickel)conductive additivepower storage device (formula G1 graphene compound)
A power storage device comprising: a positive electrode; and a negative electrode over the positive electrode, wherein the positive electrode comprises: a current collector; an active material layer over and in contact with the current collector; and a layer over and in contact with the active material layer, wherein the active material layer comprises an active material and a conductive additive, wherein the layer comprises a graphene compound, wherein the active material comprises an element A and an element M, wherein the element A is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2, wherein the element M is one or more elements selected from manganese and nickel, B₂ wherein the graphene compound has a structure repre-sented by a following formula (G₁): (G₁) R₂ O O R₁ Si OH, O O G layer wherein G layer represents a graphene layer, wherein R₁ represents a substituted alkylene group, wherein R₂ represents a substituted or unsubstituted alkyl group, and wherein the substituted alkylene group comprises a substituent selected from an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 10 carbon atoms, fluorine, and trifluoromethane.
2
Dependent← claim 1graphene compound with formula (G₁)
The power storage device according to claim 1, wherein the substituted alkylene group comprises an alkylene group having 1 to 20 carbon atoms.
4
Dependent← claim 1graphene compound with formula (G₁)active material comprising element A and element M (manganese/nickel)
The power storage device according to claim 1, wherein the graphene compound is capable of trapping the element M.
The power storage device according to claim 1, further comprising: an exterior; and an electrolyte solution.
6
Dependent← claim 1graphene compound with formula (G₁)
The power storage device according to claim 1, wherein the substituted alkylene group comprises the substituent selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 1-naphthyl group, a 2-naphthyl group, fluorine, and trifluoromethane.
7
Independentgraphene compound with formula (G₂)active material comprising element A and element M (manganese/nickel)conductive additivepower storage device (formula G2 graphene compound)
A power storage device comprising: a positive electrode; and a negative electrode over the positive electrode, wherein the positive electrode comprises: a current collector; an active material layer over and in contact with the current collector; and a layer over and in contact with the active material layer, wherein the active material layer comprises an active material and a conductive additive, wherein the layer comprises a graphene compound, wherein the active material comprises an element A and an element M, wherein the element A is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2, wherein the element M is one or more elements selected from manganese and nickel, wherein the graphene compound has a structure repre-sented by a following formula (G₂): (G₂) R₂ O O R₁ Si OH, O O G layer wherein G layer represents a graphene layer, wherein R₁ represents a substituted alkylene group, wherein R₂ represents hydrogen or a substituted or unsub-stituted alkyl group, and wherein the substituted alkylene group comprises a substituent selected from an alkyl group having 1 to 6 B₂ carbon atoms, an aryl group having 6 to 10 carbon atoms, fluorine, and trifluoromethane.
8
Dependent← claim 7graphene compound with formula (G₂)
The power storage device according to claim 7, wherein the substituted alkylene group comprises an alkylene group having 1 to 20 carbon atoms.
10
Dependent← claim 7graphene compound with formula (G₂)active material comprising element A and element M (manganese/nickel)
The power storage device according to claim 7, wherein the graphene compound is capable of trapping the element M.
The power storage device according to claim 7, further comprising: an exterior; and an electrolyte solution.
12
Dependent← claim 7graphene compound with formula (G₂)
The power storage device according to claim 7, wherein the substituted alkylene group comprises the substituent selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 1-naphthyl group, a 2-naphthyl group, fluorine, and trifluoromethane. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
power storage device (formula G₁ graphene compound)
graphene compound with formula (G₁)graphene compound layer
active material comprising element A and element M (manganese/nickel)active material layer
currentcollectorcurrent collector
power storage device (formula G₂ graphene compound)
graphene compound with formula (G₂)graphene compound layer
active material comprising element A and element M (manganese/nickel)
Materials
Materials described outside the worked examples.
graphene compound with formula (G₁)
Conductive Coating Layer Material
active material comprising element A and element M (manganese/nickel)
Active Material
conductive additive
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 249
US 4,302,518 A4,302,518 A 11/1981 Goodenough et al.
US 4,668,595 A4,668,595 A 5/1987 Yoshino et al.
CN 101148263 ACN 101148263 A 3/2008
CN 102610806 ACN 102610806 A 7/2012
US 5,240,794 A5,240,794 A 8/1993 Thackeray et al.
US 5,443,929 A5,443,929 A 8/1995 Yamamoto et al.
US 5,604,396 A5,604,396 A 2/1997 Watanabe et al.
Why these are connected
Related documents with shared materials, methods, properties, or citations.
ELECTRODE AND POWER STORAGE DEVICE COMPRISING GRAPHENE COMPOUND
Mayumi Mikami, Yohei Momma, Minoru Takahashi, Hiroshi Kadoma et al.
Semiconductor Energy Laboratory Co., Ltd., Kanagawa-ken (JP)·May 20, 2025·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIGS. 1A to 1C illustrate a cross section of an electrode of one embodiment of the present invention and part of the cross section of the electrode;
FIG. 2
FIG. 2 illustrates part of an electrode of one embodiment of the present invention;
FIG. 3
FIGS. 3A and 3B each illustrate an operation of a power storage device;
FIG. 4
FIG. 4 illustrates an operation of a power storage device;
FIG. 5
FIGS. 5A and 5B each illustrate a cross section of an active material;
FIG. 6
FIGS. 6A and 6B illustrate part of a cross section of an electrode;
FIG. 7
FIG. 7 illustrates a storage battery;
FIG. 8
FIGS. 8A and 8B illustrate cross-sectional views of a storage battery;
FIG. 9
FIGS. 9A and 9B illustrate a method for fabricating a storage battery;
FIG. 10
FIGS. 10A and 10B illustrate a method for fabricating a storage battery;
FIG. 11
FIG. 11 illustrates a storage battery;
FIG. 12
FIGS. 12A to 12C illustrate a radius of curvature of a surface;
FIG. 13
FIGS. 13A to 13D illustrate a radius of curvature of a film;
FIG. 14
FIGS. 14A and 14B illustrate a coin-type storage battery;
FIG. 15
FIGS. 15A and 15B illustrate a cylindrical storage battery;
FIG. 16
FIGS. 16A to 16C each illustrate part of a cross-sectional view of a storage battery;
FIG. 17
FIGS. 17A and 17B each illustrate part of a cross- sectional view of a storage battery;
FIG. 18
FIGS. 18A to 18C illustrate parts of a cross-sectional view of a storage battery;
FIG. 19
FIGS. 19A to 19C illustrate an example of a storage battery;
FIG. 20
FIGS. 20A to 20C illustrate an example of a storage battery;
FIG. 21
FIGS. 21A and 21B illustrate an example of a power storage system;
FIG. 22
FIG. 22B-1, the antennas 914 and 915 are provided on one of the opposite surfaces of the storage battery 913 with the layer 916 interposed therebetween, and as …
FIG. 23
FIGS. 23A and 23B illustrate examples of power storage systems;
FIG. 24
FIGS. 24A to 24G illustrate examples of electronic devices;
FIG. 25
FIGS. 25A to 25C illustrate an example of an electronic device;
FIG. 26
FIG. 26 illustrates examples of electronic devices;
FIG. 27
FIGS. 27A and 27B illustrate examples of electronic devices;
FIG. 28
FIG. 28 shows cycle characteristics of a storage battery; and
FIG. 29
FIGS. 29A and 29B show cycle characteristics of storage batteries.
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
2 independent · 10 dependent
1
Independentgraphene compound with formula (G₁)active material comprising element A and element M (manganese/nickel)conductive additivepower storage device (formula G1 graphene compound)
A power storage device comprising: a positive electrode; and a negative electrode over the positive electrode, wherein the positive electrode comprises: a current collector; an active material layer over and in contact with the current collector; and a layer over and in contact with the active material layer, wherein the active material layer comprises an active material and a conductive additive, wherein the layer comprises a graphene compound, wherein the active material comprises an element A and an element M, wherein the element A is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2, wherein the element M is one or more elements selected from manganese and nickel, B₂ wherein the graphene compound has a structure repre-sented by a following formula (G₁): (G₁) R₂ O O R₁ Si OH, O O G layer wherein G layer represents a graphene layer, wherein R₁ represents a substituted alkylene group, wherein R₂ represents a substituted or unsubstituted alkyl group, and wherein the substituted alkylene group comprises a substituent selected from an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 10 carbon atoms, fluorine, and trifluoromethane.
2
Dependent← claim 1graphene compound with formula (G₁)
The power storage device according to claim 1, wherein the substituted alkylene group comprises an alkylene group having 1 to 20 carbon atoms.
4
Dependent← claim 1graphene compound with formula (G₁)active material comprising element A and element M (manganese/nickel)
The power storage device according to claim 1, wherein the graphene compound is capable of trapping the element M.
The power storage device according to claim 1, further comprising: an exterior; and an electrolyte solution.
6
Dependent← claim 1graphene compound with formula (G₁)
The power storage device according to claim 1, wherein the substituted alkylene group comprises the substituent selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 1-naphthyl group, a 2-naphthyl group, fluorine, and trifluoromethane.
7
Independentgraphene compound with formula (G₂)active material comprising element A and element M (manganese/nickel)conductive additivepower storage device (formula G2 graphene compound)
A power storage device comprising: a positive electrode; and a negative electrode over the positive electrode, wherein the positive electrode comprises: a current collector; an active material layer over and in contact with the current collector; and a layer over and in contact with the active material layer, wherein the active material layer comprises an active material and a conductive additive, wherein the layer comprises a graphene compound, wherein the active material comprises an element A and an element M, wherein the element A is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2, wherein the element M is one or more elements selected from manganese and nickel, wherein the graphene compound has a structure repre-sented by a following formula (G₂): (G₂) R₂ O O R₁ Si OH, O O G layer wherein G layer represents a graphene layer, wherein R₁ represents a substituted alkylene group, wherein R₂ represents hydrogen or a substituted or unsub-stituted alkyl group, and wherein the substituted alkylene group comprises a substituent selected from an alkyl group having 1 to 6 B₂ carbon atoms, an aryl group having 6 to 10 carbon atoms, fluorine, and trifluoromethane.
8
Dependent← claim 7graphene compound with formula (G₂)
The power storage device according to claim 7, wherein the substituted alkylene group comprises an alkylene group having 1 to 20 carbon atoms.
10
Dependent← claim 7graphene compound with formula (G₂)active material comprising element A and element M (manganese/nickel)
The power storage device according to claim 7, wherein the graphene compound is capable of trapping the element M.
The power storage device according to claim 7, further comprising: an exterior; and an electrolyte solution.
12
Dependent← claim 7graphene compound with formula (G₂)
The power storage device according to claim 7, wherein the substituted alkylene group comprises the substituent selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 1-naphthyl group, a 2-naphthyl group, fluorine, and trifluoromethane. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
power storage device (formula G₁ graphene compound)
graphene compound with formula (G₁)graphene compound layer
active material comprising element A and element M (manganese/nickel)active material layer
currentcollectorcurrent collector
power storage device (formula G₂ graphene compound)
graphene compound with formula (G₂)graphene compound layer
active material comprising element A and element M (manganese/nickel)
Materials
Materials described outside the worked examples.
graphene compound with formula (G₁)
Conductive Coating Layer Material
active material comprising element A and element M (manganese/nickel)
Active Material
conductive additive
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 249
US 4,302,518 A4,302,518 A 11/1981 Goodenough et al.
US 4,668,595 A4,668,595 A 5/1987 Yoshino et al.
CN 101148263 ACN 101148263 A 3/2008
CN 102610806 ACN 102610806 A 7/2012
US 5,240,794 A5,240,794 A 8/1993 Thackeray et al.
US 5,443,929 A5,443,929 A 8/1995 Yamamoto et al.
US 5,604,396 A5,604,396 A 2/1997 Watanabe et al.
Why these are connected
Related documents with shared materials, methods, properties, or citations.
ELECTRODE AND POWER STORAGE DEVICE COMPRISING GRAPHENE COMPOUND
Mayumi Mikami, Yohei Momma, Minoru Takahashi, Hiroshi Kadoma et al.
Semiconductor Energy Laboratory Co., Ltd., Kanagawa-ken (JP)·May 20, 2025·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIGS. 1A to 1C illustrate a cross section of an electrode of one embodiment of the present invention and part of the cross section of the electrode;
FIG. 2
FIG. 2 illustrates part of an electrode of one embodiment of the present invention;
FIG. 3
FIGS. 3A and 3B each illustrate an operation of a power storage device;
FIG. 4
FIG. 4 illustrates an operation of a power storage device;
FIG. 5
FIGS. 5A and 5B each illustrate a cross section of an active material;
FIG. 6
FIGS. 6A and 6B illustrate part of a cross section of an electrode;
FIG. 7
FIG. 7 illustrates a storage battery;
FIG. 8
FIGS. 8A and 8B illustrate cross-sectional views of a storage battery;
FIG. 9
FIGS. 9A and 9B illustrate a method for fabricating a storage battery;
FIG. 10
FIGS. 10A and 10B illustrate a method for fabricating a storage battery;
FIG. 11
FIG. 11 illustrates a storage battery;
FIG. 12
FIGS. 12A to 12C illustrate a radius of curvature of a surface;
FIG. 13
FIGS. 13A to 13D illustrate a radius of curvature of a film;
FIG. 14
FIGS. 14A and 14B illustrate a coin-type storage battery;
FIG. 15
FIGS. 15A and 15B illustrate a cylindrical storage battery;
FIG. 16
FIGS. 16A to 16C each illustrate part of a cross-sectional view of a storage battery;
FIG. 17
FIGS. 17A and 17B each illustrate part of a cross- sectional view of a storage battery;
FIG. 18
FIGS. 18A to 18C illustrate parts of a cross-sectional view of a storage battery;
FIG. 19
FIGS. 19A to 19C illustrate an example of a storage battery;
FIG. 20
FIGS. 20A to 20C illustrate an example of a storage battery;
FIG. 21
FIGS. 21A and 21B illustrate an example of a power storage system;
FIG. 22
FIG. 22B-1, the antennas 914 and 915 are provided on one of the opposite surfaces of the storage battery 913 with the layer 916 interposed therebetween, and as …
FIG. 23
FIGS. 23A and 23B illustrate examples of power storage systems;
FIG. 24
FIGS. 24A to 24G illustrate examples of electronic devices;
FIG. 25
FIGS. 25A to 25C illustrate an example of an electronic device;
FIG. 26
FIG. 26 illustrates examples of electronic devices;
FIG. 27
FIGS. 27A and 27B illustrate examples of electronic devices;
FIG. 28
FIG. 28 shows cycle characteristics of a storage battery; and
FIG. 29
FIGS. 29A and 29B show cycle characteristics of storage batteries.
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
2 independent · 10 dependent
1
Independentgraphene compound with formula (G₁)active material comprising element A and element M (manganese/nickel)conductive additivepower storage device (formula G1 graphene compound)
A power storage device comprising: a positive electrode; and a negative electrode over the positive electrode, wherein the positive electrode comprises: a current collector; an active material layer over and in contact with the current collector; and a layer over and in contact with the active material layer, wherein the active material layer comprises an active material and a conductive additive, wherein the layer comprises a graphene compound, wherein the active material comprises an element A and an element M, wherein the element A is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2, wherein the element M is one or more elements selected from manganese and nickel, B₂ wherein the graphene compound has a structure repre-sented by a following formula (G₁): (G₁) R₂ O O R₁ Si OH, O O G layer wherein G layer represents a graphene layer, wherein R₁ represents a substituted alkylene group, wherein R₂ represents a substituted or unsubstituted alkyl group, and wherein the substituted alkylene group comprises a substituent selected from an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 10 carbon atoms, fluorine, and trifluoromethane.
2
Dependent← claim 1graphene compound with formula (G₁)
The power storage device according to claim 1, wherein the substituted alkylene group comprises an alkylene group having 1 to 20 carbon atoms.
4
Dependent← claim 1graphene compound with formula (G₁)active material comprising element A and element M (manganese/nickel)
The power storage device according to claim 1, wherein the graphene compound is capable of trapping the element M.
The power storage device according to claim 1, further comprising: an exterior; and an electrolyte solution.
6
Dependent← claim 1graphene compound with formula (G₁)
The power storage device according to claim 1, wherein the substituted alkylene group comprises the substituent selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 1-naphthyl group, a 2-naphthyl group, fluorine, and trifluoromethane.
7
Independentgraphene compound with formula (G₂)active material comprising element A and element M (manganese/nickel)conductive additivepower storage device (formula G2 graphene compound)
A power storage device comprising: a positive electrode; and a negative electrode over the positive electrode, wherein the positive electrode comprises: a current collector; an active material layer over and in contact with the current collector; and a layer over and in contact with the active material layer, wherein the active material layer comprises an active material and a conductive additive, wherein the layer comprises a graphene compound, wherein the active material comprises an element A and an element M, wherein the element A is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2, wherein the element M is one or more elements selected from manganese and nickel, wherein the graphene compound has a structure repre-sented by a following formula (G₂): (G₂) R₂ O O R₁ Si OH, O O G layer wherein G layer represents a graphene layer, wherein R₁ represents a substituted alkylene group, wherein R₂ represents hydrogen or a substituted or unsub-stituted alkyl group, and wherein the substituted alkylene group comprises a substituent selected from an alkyl group having 1 to 6 B₂ carbon atoms, an aryl group having 6 to 10 carbon atoms, fluorine, and trifluoromethane.
8
Dependent← claim 7graphene compound with formula (G₂)
The power storage device according to claim 7, wherein the substituted alkylene group comprises an alkylene group having 1 to 20 carbon atoms.
10
Dependent← claim 7graphene compound with formula (G₂)active material comprising element A and element M (manganese/nickel)
The power storage device according to claim 7, wherein the graphene compound is capable of trapping the element M.
The power storage device according to claim 7, further comprising: an exterior; and an electrolyte solution.
12
Dependent← claim 7graphene compound with formula (G₂)
The power storage device according to claim 7, wherein the substituted alkylene group comprises the substituent selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 1-naphthyl group, a 2-naphthyl group, fluorine, and trifluoromethane. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
power storage device (formula G₁ graphene compound)
graphene compound with formula (G₁)graphene compound layer
active material comprising element A and element M (manganese/nickel)active material layer
currentcollectorcurrent collector
power storage device (formula G₂ graphene compound)
graphene compound with formula (G₂)graphene compound layer
active material comprising element A and element M (manganese/nickel)
Materials
Materials described outside the worked examples.
graphene compound with formula (G₁)
Conductive Coating Layer Material
active material comprising element A and element M (manganese/nickel)
Active Material
conductive additive
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 249
US 4,302,518 A4,302,518 A 11/1981 Goodenough et al.
US 4,668,595 A4,668,595 A 5/1987 Yoshino et al.
CN 101148263 ACN 101148263 A 3/2008
CN 102610806 ACN 102610806 A 7/2012
US 5,240,794 A5,240,794 A 8/1993 Thackeray et al.
US 5,443,929 A5,443,929 A 8/1995 Yamamoto et al.
US 5,604,396 A5,604,396 A 2/1997 Watanabe et al.
Why these are connected
Related documents with shared materials, methods, properties, or citations.
US 5,910,382 A5,910,382 A 6/1999 Goodenough et al.
US 6,085,015 A6,085,015 A 7/2000 Armand et al.
US 6,218,050 B16,218,050 B1 4/2001 Yoon et al.
US 6,346,348 B16,346,348 B1 2/2002 Nakajima et al.
US 6,458,487 B16,458,487 B1 10/2002 Takeuchi et al.
US 6,514,640 B16,514,640 B1 2/2003 Armand et al.
US 6,582,814 B26,582,814 B2 6/2003 Swiler et al.
US 6,680,143 B26,680,143 B2 1/2004 Thackeray et al.
US 6,737,195 B26,737,195 B2 5/2004 Kweon et al.
US 6,753,111 B26,753,111 B2 6/2004 Kweon et al.
US 6,846,592 B26,846,592 B2 1/2005 Kweon et al.
US 6,919,144 B26,919,144 B2 7/2005 Miyazaki et al.
US 6,974,601 B26,974,601 B2 12/2005 Kweon et al.
US 6,984,469 B26,984,469 B2 1/2006 Kweon et al.
US 7,018,741 B27,018,741 B2 3/2006 Suhara et al.
US 7,138,209 B27,138,209 B2 11/2006 Kweon et al.
US 7,294,435 B27,294,435 B2 11/2007 Miyamoto et al.
US 7,303,840 B27,303,840 B2 12/2007 Thackeray et al.
US 7,309,546 B27,309,546 B2 12/2007 Kweon et al.
US 7,368,071 B27,368,071 B2 5/2008 Dahn et al.
US 7,393,476 B27,393,476 B2 7/2008 Shiozaki et al.
US 7,635,536 B27,635,536 B2 12/2009 Johnson et al.
US 7,709,148 B27,709,148 B2 5/2010 Kawasato et al.
US 7,709,151 B27,709,151 B2 5/2010 Inoue et al.
US 7,736,807 B27,736,807 B2 6/2010 Hasegawa et al.
US 7,790,308 B27,790,308 B2 9/2010 Johnson et al.
US 7,892,679 B27,892,679 B2 2/2011 Shimizu et al.
US 7,927,506 B27,927,506 B2 4/2011 Park
US 7,935,270 B27,935,270 B2 5/2011 Park
US 8,003,256 B28,003,256 B2 8/2011 Ohishi
US 8,007,941 B28,007,941 B2 8/2011 Kweon et al.
US 8,034,486 B28,034,486 B2 10/2011 Kweon et al.
US 8,080,340 B28,080,340 B2 12/2011 Thackeray et al.
US 8,236,449 B28,236,449 B2 8/2012 Nakura
US 8,470,477 B28,470,477 B2 6/2013 Miwa et al.
US 8,476,510 B28,476,510 B2 7/2013 Swager et al.
US 8,557,440 B28,557,440 B2 10/2013 Yu et al.
US 8,685,569 B28,685,569 B2 4/2014 Oguni et al.
US 8,685,570 B28,685,570 B2 4/2014 Miwa et al.
US 8,709,654 B28,709,654 B2 4/2014 Takeuchi et al.
US 8,753,532 B28,753,532 B2 6/2014 Levasseur et al.
US 8,808,918 B28,808,918 B2 8/2014 Jung et al.
US 8,877,377 B28,877,377 B2 11/2014 Hosoya
US 8,877,381 B28,877,381 B2 11/2014 Yasuda et al.
US 8,883,351 B28,883,351 B2 11/2014 Todoriki et al.
US 8,906,547 B28,906,547 B2 12/2014 Taniguchi et al.
US 8,927,148 B28,927,148 B2 1/2015 Kawakami
US 8,945,770 B28,945,770 B2 2/2015 Koo et al.
US 8,945,772 B28,945,772 B2 2/2015 Kawakami et al.
US 9,225,003 B29,225,003 B2 12/2015 Yukawa
US 9,227,850 B29,227,850 B2 1/2016 Ooishi
US 9,293,236 B29,293,236 B2 3/2016 Kawakami et al.
US 9,362,557 B29,362,557 B2 6/2016 Watanabe et al.
US 9,391,322 B29,391,322 B2 7/2016 Liu et al.
US 9,478,796 B29,478,796 B2 10/2016 Li et al.
US 9,505,631 B29,505,631 B2 11/2016 Masukuni et al.
US 9,515,313 B29,515,313 B2 12/2016 Umeyama et al.
US 9,601,764 B29,601,764 B2 3/2017 Kawakami et al.
US 9,666,326 B29,666,326 B2 5/2017 Kawakami et al.
US 9,698,420 B29,698,420 B2 7/2017 Ishizaki et al.
US 9,786,903 B29,786,903 B2 10/2017 Ryu et al.
US 9,899,664 B29,899,664 B2 2/2018 Yamaki et al.
US 9,923,244 B29,923,244 B2 3/2018 Takanashi et al.
US 10,128,495 B210,128,495 B2 11/2018 Satow et al.
US 10,243,215 B210,243,215 B2 3/2019 Shitaba et al.
US 10,361,432 B210,361,432 B2 7/2019 Takaichi et al.
US 10,938,035 B210,938,035 B2 3/2021 Yamakaji et al.
US 2001/0010807 A12001/0010807 A1 8/2001 Matsubara
US 2002/0102459 A12002/0102459 A1 8/2002 Hosoya et al.
US 2002/0110736 A12002/0110736 A1 8/2002 Kweon et al.
US 2002/0164156 A12002/0164156 A1 11/2002 Bilbrey
US 2002/0195591 A12002/0195591 A1 12/2002 Ravet et al.
US 2003/0104279 A12003/0104279 A1 6/2003 Miyazaki et al.
US 2003/0134186 A12003/0134186 A1 7/2003 Shizuki
US 2004/0229123 A12004/0229123 A1 11/2004 Takahashi et al.
US 2004/0229124 A12004/0229124 A1 11/2004 Miyamoto et al.
US 2004/0234857 A12004/0234857 A1 11/2004 Shiozaki et al.
US 2005/0019662 A12005/0019662 A1 1/2005 Suhara et al.
US 2006/0051671 A12006/0051671 A1 3/2006 Thackeray et al.
US 2006/0051673 A12006/0051673 A1 3/2006 Johnson et al.
US 2006/0121352 A12006/0121352 A1 6/2006 Kejha et al.
US 2006/0188780 A12006/0188780 A1 8/2006 Fujii et al.
US 2006/0275664 A12006/0275664 A1 12/2006 Ohzuku et al.
US 2006/0286459 A12006/0286459 A1 12/2006 Zhao et al.
US 2007/0026315 A12007/0026315 A1 2/2007 Lampe-Onnerud et al.
US 2007/0099086 A12007/0099086 A1 5/2007 Kang et al.
US 2007/0117014 A12007/0117014 A1 5/2007 Saito et al.
US 2007/0122712 A12007/0122712 A1 5/2007 Kang et al.
US 2007/0148546 A12007/0148546 A1 6/2007 Shimizu et al.
US 2007/0160906 A12007/0160906 A1 7/2007 Tooyama et al.
US 2007/0212609 A12007/0212609 A1 9/2007 Iwami
US 2007/0224506 A12007/0224506 A1 9/2007 Ooyama et al.
US 2008/0131780 A12008/0131780 A1 6/2008 Kawasato et al.
US 2008/0166637 A12008/0166637 A1 7/2008 Inagaki et al.
US 2008/0241693 A12008/0241693 A1 10/2008 Fukuchi et al.
US 2009/0011335 A12009/0011335 A1 1/2009 Takeda et al.
US 2009/0087731 A12009/0087731 A1 4/2009 Fukui et al.
US 2009/0104532 A12009/0104532 A1 4/2009 Hosoya
US 2009/0123813 A12009/0123813 A1 5/2009 Chiang et al.
US 2009/0123842 A12009/0123842 A1 5/2009 Thackeray et al.
US 2009/0220862 A12009/0220862 A1 9/2009 Toyama et al.
US 2010/0019194 A12010/0019194 A1 1/2010 Fujiwara et al.
US 2010/0035147 A12010/0035147 A1 2/2010 Kotato et al.
US 2010/0129714 A12010/0129714 A1 5/2010 Toyama et al.
US 2010/0129715 A12010/0129715 A1 5/2010 Saito et al.
US 2010/0143784 A12010/0143784 A1 6/2010 Johnson et al.
US 2010/0143799 A12010/0143799 A1 6/2010 Park
US 2010/0159330 A12010/0159330 A1 6/2010 Sugiura et al.
US 2010/0178464 A12010/0178464 A1 * 7/2010 Choi...................... B82Y 30/00examiner
US 2010/0216024 A12010/0216024 A1 8/2010 Kanno et al.
US 2010/0233542 A12010/0233542 A1 9/2010 Endo et al.
US 2010/0247986 A12010/0247986 A1 9/2010 Toyama et al.
US 2010/0248033 A12010/0248033 A1 9/2010 Kumar et al.
US 2011/0033749 A12011/0033749 A1 2/2011 Uchida et al.
US 2011/0059367 A12011/0059367 A1 3/2011 Morita et al.
US 2011/0076564 A12011/0076564 A1 3/2011 Yu et al.
US 2011/0200879 A12011/0200879 A1 8/2011 Saito et al.
US 2011/0229757 A12011/0229757 A1 9/2011 Kawakami et al.
US 2011/0256437 A12011/0256437 A1 10/2011 Katsuki. et al.
US 2011/0269023 A12011/0269023 A1 11/2011 Kawakami et al.
US 2011/0297876 A12011/0297876 A1 12/2011 Masukuni et al.
US 2011/0300441 A12011/0300441 A1 12/2011 Kawakami
US 2012/0034516 A12012/0034516 A1 2/2012 Koo et al.
US 2012/0045692 A12012/0045692 A1 2/2012 Takemura et al.
US 2012/0064406 A12012/0064406 A1 3/2012 Sato et al.
US 2012/0064409 A12012/0064409 A1 3/2012 Zhamu et al.
US 2012/0088151 A12012/0088151 A1 4/2012 Yamazaki et al.
US 2012/0088156 A12012/0088156 A1 4/2012 Nomoto et al.
US 2012/0118149 A12012/0118149 A1 5/2012 Dabrowski et al.
US 2012/0177974 A12012/0177974 A1 7/2012 Nakajima et al.
US 2012/0244430 A12012/0244430 A1 9/2012 Yamazaki et al.
US 2012/0256337 A12012/0256337 A1 10/2012 Yokoyama et al.
US 2012/0258358 A12012/0258358 A1 10/2012 Yura et al.
US 2012/0258365 A12012/0258365 A1 10/2012 Yokoyama et al.
US 2012/0258369 A12012/0258369 A1 10/2012 Yokoyama et al.
US 2012/0261622 A12012/0261622 A1 10/2012 Honma
US 2012/0295163 A12012/0295163 A1 11/2012 Yanagita et al.
US 2012/0308891 A12012/0308891 A1 12/2012 Todoriki et al.
US 2012/0315544 A12012/0315544 A1 12/2012 Yasuda et al.
US 2012/0328951 A12012/0328951 A1 12/2012 Hirohashi et al.
US 2012/0328956 A12012/0328956 A1 12/2012 Oguni et al.
US 2012/0330044 A12012/0330044 A1 * 12/2012 Hou....................... B82Y 30/00examiner
US 2013/0017435 A12013/0017435 A1 1/2013 Sato et al.
US 2013/0040193 A12013/0040193 A1 2/2013 Tsuchida et al.
US 2013/0045418 A12013/0045418 A1 2/2013 Oguni et al.
US 2013/0052547 A12013/0052547 A1 2/2013 Ogino et al.
US 2013/0065120 A12013/0065120 A1 3/2013 Miwa et al.
US 2013/0078516 A12013/0078516 A1 3/2013 Taniguchi et al.
US 2013/0084384 A12013/0084384 A1 4/2013 Yamakaji
US 2013/0130103 A12013/0130103 A1 5/2013 Kim et al.
US 2013/0134051 A12013/0134051 A1 5/2013 Takahashi et al.
US 2013/0156683 A12013/0156683 A1 6/2013 Holzapfel et al.
US 2013/0156942 A12013/0156942 A1 6/2013 Yamakaji et al.
US 2013/0157034 A12013/0157034 A1 6/2013 Choi et al.
US 2013/0164619 A12013/0164619 A1 6/2013 Yamakaji et al.
US 2013/0177806 A12013/0177806 A1 7/2013 Caldwell et al.
US 2013/0183579 A12013/0183579 A1 7/2013 Kim et al.
US 2013/0189585 A12013/0189585 A1 7/2013 Kang et al.
US 2013/0190449 A12013/0190449 A1 7/2013 Kinloch et al.
US 2013/0202953 A12013/0202953 A1 8/2013 Sharma et al.
US 2013/0212879 A12013/0212879 A1 8/2013 Ogino
US 2013/0266858 A12013/0266858 A1 10/2013 Inoue et al.
US 2013/0266859 A12013/0266859 A1 10/2013 Todoriki et al.
US 2013/0313471 A12013/0313471 A1 11/2013 Endo et al.
US 2013/0316237 A12013/0316237 A1 11/2013 Miki
US 2013/0337320 A12013/0337320 A1 12/2013 Yukawa
US 2014/0004412 A12014/0004412 A1 1/2014 Ogino
US 2014/0023920 A12014/0023920 A1 1/2014 Yamazaki et al.
US 2014/0079995 A12014/0079995 A1 3/2014 Wakada
US 2014/0099554 A12014/0099554 A1 4/2014 Inoue et al.
US 2014/0127567 A12014/0127567 A1 5/2014 Kuriki et al.
US 2014/0127568 A12014/0127568 A1 * 5/2014 Kawakami.......... H01M 4/1393examiner
US 2014/0131633 A12014/0131633 A1 5/2014 Ito et al.
US 2014/0162132 A12014/0162132 A1 6/2014 Ishii et al.
US 2014/0166946 A12014/0166946 A1 6/2014 Miwa et al.
US 2014/0184172 A12014/0184172 A1 7/2014 Momo et al.
US 2014/0234700 A12014/0234700 A1 8/2014 Moriwaka et al.
US 2014/0275323 A12014/0275323 A1 9/2014 Thibodeau et al.
US 2014/0295068 A12014/0295068 A1 10/2014 Nanba et al.
US 2014/0315083 A12014/0315083 A1 * 10/2014 Liu....................... H01M 4/622examiner
US 2014/0332715 A12014/0332715 A1 11/2014 Kawakami et al.
US 2014/0370184 A12014/0370184 A1 12/2014 Takemura. et al.
US 2015/0014581 A12015/0014581 A1 1/2015 Kawakami et al.
US 2015/0014605 A12015/0014605 A1 1/2015 Kawakami et al.
US 2015/0064565 A12015/0064565 A1 3/2015 Todoriki et al.
US 2015/0093648 A12015/0093648 A1 4/2015 Son et al.
US 2015/0099178 A12015/0099178 A1 4/2015 Kawakami et al.
US 2015/0099179 A12015/0099179 A1 4/2015 Ikenuma et al.
US 2015/0123050 A12015/0123050 A1 5/2015 Yamazaki et al.
US 2015/0155556 A12015/0155556 A1 6/2015 Kawakami et al.
US 2015/0166348 A12015/0166348 A1 6/2015 Ikenuma et al.
US 2015/0262762 A12015/0262762 A1 9/2015 Ikenuma et al.
US 2015/0325855 A12015/0325855 A1 11/2015 Kawakami et al.
US 2015/0333320 A12015/0333320 A1 11/2015 Tamaki et al.
US 2015/0333324 A12015/0333324 A1 11/2015 Umeyama et al.
US 2015/0357641 A12015/0357641 A1 12/2015 Sugie et al.
US 2015/0380737 A12015/0380737 A1 12/2015 Kawasato et al.
US 2016/0006032 A12016/0006032 A1 1/2016 Paulsen et al.
US 2016/0028080 A12016/0028080 A1 1/2016 Sugiura
US 2016/0046771 A12016/0046771 A1 2/2016 Thibodeau et al.
US 2016/0064726 A12016/0064726 A1 3/2016 Ikenuma et al.
US 2016/0087315 A12016/0087315 A1 3/2016 Oyama
US 2016/0118646 A12016/0118646 A1 4/2016 Ikenuma
US 2016/0118658 A12016/0118658 A1 4/2016 Kawakami et al.
US 2016/0156030 A12016/0156030 A1 6/2016 Sun et al.
US 2016/0164089 A12016/0164089 A1 6/2016 Kawakami et al.
US 2016/0276658 A12016/0276658 A1 9/2016 Choi et al.
US 2016/0285102 A12016/0285102 A1 9/2016 Shitaba et al.
US 2016/0329533 A12016/0329533 A1 11/2016 Tajima
US 2016/0349905 A12016/0349905 A1 12/2016 Momma et al.
US 2016/0380271 A12016/0380271 A1 12/2016 Ochiai et al.
US 2017/0005364 A12017/0005364 A1 1/2017 Yamazaki et al.
US 2017/0040594 A12017/0040594 A1 2/2017 Yamaki et al.
US 2017/0062819 A12017/0062819 A1 3/2017 Ikenuma
US 2017/0069907 A12017/0069907 A1 3/2017 Zhu et al.
US 2017/0117589 A12017/0117589 A1 4/2017 Tajima et al.
US 2017/0187035 A12017/0187035 A1 6/2017 Yanagihara et al.
US 2017/0207444 A12017/0207444 A1 7/2017 Yanagihara et al.
US 2017/0256817 A12017/0256817 A1 9/2017 Kadoma et al.
US 2017/0309910 A12017/0309910 A1 10/2017 Jo et al.
US 2018/0013130 A12018/0013130 A1 1/2018 Ochiai et al.
US 2018/0019462 A12018/0019462 A1 1/2018 Kadoma et al.
US 2018/0040888 A12018/0040888 A1 2/2018 Park et al.
US 2018/0040897 A12018/0040897 A1 2/2018 Park et al.
US 2018/0102536 A12018/0102536 A1 4/2018 Kawakami et al.
US 2018/0108944 A12018/0108944 A1 4/2018 Yamakaji
US 2018/0145317 A12018/0145317 A1 5/2018 Momma et al.
US 2018/0145368 A12018/0145368 A1 5/2018 Ochiai et al.
US 2018/0254477 A12018/0254477 A1 9/2018 Horikawa et al.
US 2018/0331365 A12018/0331365 A1 * 11/2018 Joo..................... H01M 4/0404examiner
US 2018/0366729 A12018/0366729 A1 12/2018 Yanagita et al.
US 2020/0144601 A12020/0144601 A1 5/2020 Takahashi et al.
US 2020/0152961 A12020/0152961 A1 5/2020 Momma et al.
US 2020/0176770 A12020/0176770 A1 6/2020 Takahashi et al.
US 2021/0175507 A12021/0175507 A1 6/2021 Yamakaji et al.
CN 102694201 ACN 102694201 A 9/2012
CN 102569775 BCN 102569775 B 1/2017
Cited non-patent literature · 74
Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Bat- teries. Joshi.T et al., “Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Bat- teries”, J. Electrochem. SOC. (Journal of the Electrochemical Society), 2014, vol. 161, No. 12, pp. A1915-A1921.
High-energy cathode material for long-life and safe lithium batteries. Sun.Y et al., “High-energy cathode material for long-life and safe lithium batteries”, Nature Materials, Mar. 22, 2009, vol. 8, pp. 320-324.
Li2MnO3-stabilized LiMO2(M=Mn, Ni, Co) electrodes for lithium-ion batteries. Thackeray.M et al., “Li2MnO3-stabilized LiMO2(M=Mn, Ni, Co) electrodes for lithium-ion batteries”, J. Mater. Chem. (Journal of Materials Chemistry), 2007, vol. 17, pp. 3112-3125.
Magnetic properties of the chemically delithiated LixMn2O4 with 0.07 ≤x≤1. Mukalk et al., “Magnetic properties of the chemically delithiated LixMn2O4 with 0.07 ≤x≤1”, Journal of Solid State Chemistry, May 1, 2011, vol. 184, No. 5, pp. 1096-1104.
Antiferromagnetic ordering in Li2MnO3 single crys- tals with a two-dimensional honeycomb lattice. Lee.S et al., “Antiferromagnetic ordering in Li2MnO3 single crys- tals with a two-dimensional honeycomb lattice”, Journal of Physics: Condensed Matter, Nov. 14, 2012, vol. 24, No. 45, pp. 456004-1- 456004-9.
The Chemistry of Graphene Oxide. Dreyer.D et al., “The Chemistry of Graphene Oxide”, Chemical Society Reviews, Nov. 3, 2009, vol. 39, No. 1, pp. 228-240.
EELS analysis of cation valence states and oxygen vacancies in magnetic oxides. Wang.Z et al., “EELS analysis of cation valence states and oxygen vacancies in magnetic oxides”, Micron, Oct. 1, 2000, vol. 31, No. 5, pp. 571-580, Elsevier.
Oxidation state and chemical shift investigation in transition metal oxides by EELS. Tan.H et al., “Oxidation state and chemical shift investigation in transition metal oxides by EELS”, Ultramicroscopy, May 1, 2012, vol. 116, pp. 24-33, Elsevier.
Thermogravimetry and X-Ray Diffraction Study of the Thermal Decomposition Processes in xLi2CO3—MnCO3 Mixtures. Berbenni.V et al., “Thermogravimetry and X-Ray Diffraction Study of the Thermal Decomposition Processes in xLi2CO3—MnCO3 Mixtures”, Journal of Analytical and Applied Pyrolysis, 2002, vol. 62, pp. 45-62.
Lithium-manganese oxide electrodes with layered- spinel composite structures xLi2MnO3 v (1-x)Li1+yMn2- yO4(0<x<1,0≤y≤0.33) for lithium batteries. Johnson.C et al., “Lithium-manganese oxide electrodes with layered- spinel composite structures xLi2MnO3 v (1-x)Li1+yMn2- yO4(0<x<1,0≤y≤0.33) for lithium batteries”, Electrochemistry Com- munications, May 1, 2005, vol. 7, No. 5, pp. 528-536, Elsevier.
Growth modes in two-dimensional heteroepitaxy on an elasticsubstrate. Katsuno.H et al., “Growth modes in two-dimensional heteroepitaxy on an elasticsubstrate”, J. Cryst. Growth (Journal of Crystal Growth), Feb. 15, 2005, vol. 275, No. 1-2, pp. e263-e288, Elsevier.
Characterization of MgO-coated-LiCoO2 par- ticles by analytical transmission electron microscopy. Taguchi.N et al., “Characterization of MgO-coated-LiCoO2 par- ticles by analytical transmission electron microscopy”, Journal of Power Sources, 2016, vol. 328, pp. 161-166, Elsevier.
Structural Studies on the Effects of ZrO2 Coating on LiCoO2 during Cycling Using In Situ X-Ray Diffraction Tech- nique. Chung.K et al., “Structural Studies on the Effects of ZrO2 Coating on LiCoO2 during Cycling Using In Situ X-Ray Diffraction Tech- nique”, J. Electrochem. Soc. (Journal of the Electrochemical Soci- ety), 2006, vol. 153, No. 11, pp. A2152-A2157.
Electrochemical and In Situ Synchrotron XRD Studies on Al2O3-Coated LiCoO2 Cathode Material. Liu.L et al., “Electrochemical and In Situ Synchrotron XRD Studies on Al2O3-Coated LiCoO2 Cathode Material”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2004, vol. 151, No. 9, pp. A1344-A1351.
LICoO2 Degradation Behavior in the High-Voltage Phase Transition Region and Improved Reversibility with surface Coating. Yano.A et al., “LICoO2 Degradation Behavior in the High-Voltage Phase Transition Region and Improved Reversibility with surface Coating”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2017, vol. 164, No. 1, pp. A6116-A6122.
Staging PhaseTransitions in LixCoO2. Chen.Z et al., “Staging PhaseTransitions in LixCoO2”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2002, vol. 149, No. 12, pp. A1604-A1609.
The spinel and cubic rocksalt solid-solutions in the Li—Mn—Ni oxide pseudo-ternary system. McCalla.E et al., “The spinel and cubic rocksalt solid-solutions in the Li—Mn—Ni oxide pseudo-ternary system”, Solid State Ionics, May 2, 2013, vol. 242, pp. 1-9, Elsevier.
Characterization of Spinel LixCo204-Coated LiCo02 Prepared with Post-Thermal Treatment as a Cathode Material for Lithium ion Batteries. Shim.J et al., “Characterization of Spinel LixCo204-Coated LiCo02 Prepared with Post-Thermal Treatment as a Cathode Material for Lithium ion Batteries”, Chem. Mater. (Chemistry of Materials), Apr. 10, 2015, vol. 27, No. 9, pp. 3273-3279.
Correlation of lithium ion distribution and X-ray absorption near-edge structure in O3- and O2-lithium cobalt oxides from first-principle calculation. Okumura.T et al., “Correlation of lithium ion distribution and X-ray absorption near-edge structure in O3- and O2-lithium cobalt oxides from first-principle calculation”, Journal of Materials Chemistry, 2012, vol. 22, pp. 17340-17348.
Electronic phase diagram of the layered cobalt oxide system LixCoO2 (0.0≤x≤1.0). Motohashi.T et al., “Electronic phase diagram of the layered cobalt oxide system LixCoO2 (0.0≤x≤1.0)”, Phys. Rev. B (Physical Review. B), Oct. 9, 2009, vol. 80, No. 16, pp. 165114-1-155114-9.
Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide TEM Investigation. Gabrisch.H et al., “Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide TEM Investigation”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2004, vol. 151, No. 6, pp. A891-A897.
Khedr.A et al., “Synthesis, Structure, and Electrochemistry of Sm-Modified LiMn2O4 Cathode Materials for Lithium-Ion Batter-
ies”, J. Electron. Mater.(Journal of Electronic Materials), Apr. 23, 2013, vol. 42, No. 6, pp. 1275-1281.
Fluoride Model Systems: II, The Binary Systems CaF2—BeF2, MgF2—BeF2, and LiF—MgF2. Counts.W et al., “Fluoride Model Systems: II, The Binary Systems CaF2—BeF2, MgF2—BeF2, and LiF—MgF2”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), 1953, vol. 36, No. 1, pp. 12-17.
Synthesis of Mg and Mn Doped LiCoO2 and Effects on High Voltage Cycling. Liu.A et al., “Synthesis of Mg and Mn Doped LiCoO2 and Effects on High Voltage Cycling”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Jun. 2, 2017, vol. 164, No. 7, pp. A1655- A1664.
Electronic Conductivity of LICoO2 and Its Enhancement by Magnesium Doping. Tukamoto.H et al., “Electronic Conductivity of LICoO2 and Its Enhancement by Magnesium Doping”, J. Electrochem. Soc. (Jour- nal of the Electrochemical Society), Sep. 1, 1997, vol. 144, No. 9, pp. 3164-3168.
Solid-State Redox Reactions of LiCoO2 (R-3m) for 4 Volt Secondary Lithium Cells. Ohzuku.T et al., “Solid-State Redox Reactions of LiCoO2 (R-3m) for 4 Volt Secondary Lithium Cells”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Nov. 1, 1994, vol. 141, No. 11, pp. 2972-2977.
CoO2, The End Member of the LixCoO2 Solid Solution. Amatucci.G et al., “CoO2, The End Member of the LixCoO2 Solid Solution”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Mar. 1, 1996, vol. 143, No. 3, pp. 1114-1123.
Structural and electrochemical characterizations of surface-modified LiCoO2 cathode materials for Li-ion batteries. Wang.Z et al., “Structural and electrochemical characterizations of surface-modified LiCoO2 cathode materials for Li-ion batteries”, Solid State Ionics, Jun. 2, 2002, vol. 148, No. 3-4, pp. 335-342, Elsevier.
Synthesis and Electrochemical Performance of High Voltage Cycling LiM0.05Co0.95O2 as Cathode Material for Lithium Rechargeable Cells. Zou.M et al., “Synthesis and Electrochemical Performance of High Voltage Cycling LiM0.05Co0.95O2 as Cathode Material for Lithium Rechargeable Cells”, Electrochemical and Solid-State Letters, 2004, vol. 7, No. 7, pp. A176-A179.
Improving the cycling stability of LiCoO2 at 4.5 V through co-modification by Mg doping and zirconium oxyfluoride coating. Wang.Z et al., “Improving the cycling stability of LiCoO2 at 4.5 V through co-modification by Mg doping and zirconium oxyfluoride coating”, Ceramics Internationa, 2015, vol. 41, No. 1, pp. 469-474.
High Performance LiCoO2 Cathode Materials at 60° C. for Lithium Secondary Batteries Prepared by the Facile Nanoscale Dry-Coating Method. Cho.Y et al., “High Performance LiCoO2 Cathode Materials at 60° C. for Lithium Secondary Batteries Prepared by the Facile Nanoscale Dry-Coating Method”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), 2010, vol. 157, No. 5, pp. A617-A624.
Mg doping and zirconium oxyfluoride coating co-modification to enhance the high-voltage performance of LiCoO2 for lithium ion battery. Wang.Z et al., “Mg doping and zirconium oxyfluoride coating co-modification to enhance the high-voltage performance of LiCoO2 for lithium ion battery”, Journal of Alloys and Compounds, Feb. 5, 2015, vol. 621, pp. 212-219.
Effect of Mg doping and MgO-surface modi- fication on the cycling stability of LiCoO2 electrodes.. Mladenov.M et al., “Effect of Mg doping and MgO-surface modi- fication on the cycling stability of LiCoO2 electrodes.”, Electro- chemistry Communications, Aug. 1, 2001, vol. 3, No. 8, pp. 410-416.
Effects of metal oxide coatings on the thermal stability and electrical performance of LiCoCO2 in a Li-ion cell. Kweon.H et al., “Effects of metal oxide coatings on the thermal stability and electrical performance of LiCoCO2 in a Li-ion cell”, Journal of Power Sources, Feb. 16, 2004, vol. 126, pp. 156-162, Elsevier.
Effects of MgO Coating on the Structural and Electrochemical Characteristics of LiCoO2 as Cathode Materials for Lithium Ion Battery. Shim.J et al., “Effects of MgO Coating on the Structural and Electrochemical Characteristics of LiCoO2 as Cathode Materials for Lithium Ion Battery”, Chem. Mater. (Chemistry of Materials), Mar. 24, 2014, vol. 26, No. 8, pp. 2537-2543.
Improvement of electrochemical stability of LiCoO2 cathode by a nano-crystalline coating. Zhao.H et al., “Improvement of electrochemical stability of LiCoO2 cathode by a nano-crystalline coating”, Journal of Power Sources, May 20, 2004, vol. 132, pp. 195-200, Elsevier.
Effects of surface modification by MgO on interfacial reactions of lithium cobalt oxide thin film electrode. Iriyama.Y et al., “Effects of surface modification by MgO on interfacial reactions of lithium cobalt oxide thin film electrode”, Journal of Power Sources, Oct. 5, 2004, vol. 137, pp. 111-116, Elsevier.
Origin of surface Coating Effect for MgO on LiCoO2 to Improve the Interfacial Reaction between Electrode and Electrolyte. Orikasa.Y et al., “Origin of surface Coating Effect for MgO on LiCoO2 to Improve the Interfacial Reaction between Electrode and Electrolyte”, Adv. Mater.Interfaces (Advanced Materials Inter- faces), Aug. 28, 2014, vol. 1, No. 9, pp. 1400195-1-1400195-8.
Stabilization of the Electronic Structure at the Cathode/Electrolyte Interface via MgO Ultra-thin Layer during Lithium-ions Insertion/Extraction. Yamamoto.K et al., “Stabilization of the Electronic Structure at the Cathode/Electrolyte Interface via MgO Ultra-thin Layer during Lithium-ions Insertion/Extraction”, Electrochemistry, Oct. 5, 2014, vol. 82, No. 10, pp. 891-896.
Synergistic effects of coating and doping for lithium ion battery cathode materials: synthesis and characterization of lithium titanate-coated LiCoO2 with Mg doping. Shim.J et al., “Synergistic effects of coating and doping for lithium ion battery cathode materials: synthesis and characterization of lithium titanate-coated LiCoO2 with Mg doping”, Electrochimica Acta, Dec. 20, 2015, vol. 186, pp. 201-208, Elesevier.
in situ Total-Reflection Fluorescence X-Ray Absorption Spectroscopic Study on Stability at LiFePO4/Electro- lyte Interface. Yamamoto.K et al., “in situ Total-Reflection Fluorescence X-Ray Absorption Spectroscopic Study on Stability at LiFePO4/Electro- lyte Interface”, 224th ECS Meeting Abstract, Oct. 27, 2013, p. 923.
Electrochemical Evaluation and Structural Charac- terization of Commercial LiCoO2 Surfaces Modified with MgO for Lithium-Ion Batteries. Wang.Z et al., “Electrochemical Evaluation and Structural Charac- terization of Commercial LiCoO2 Surfaces Modified with MgO for Lithium-Ion Batteries”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), Mar. 4, 2002, vol. 149, No. 4, pp. A466-A471.
Phase Transition of Bare and Coated LixCoO2 (x=0.4 and 0.24) at 300° C.. Lee.Y et al., “Phase Transition of Bare and Coated LixCoO2 (x=0.4 and 0.24) at 300° C.”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), Jul. 28, 2005, vol. 152, No. 9, pp. A1824- A1827.
Impact of active material surface area on thermal stability of LiCoO2 cathode. Geder.J et al., “Impact of active material surface area on thermal stability of LiCoO2 cathode”, Journal of Power Sources, Jul. 1, 2014, vol. 257, pp. 286-292, Elsevier.
Effect of LiF on Hot-Pressing of MgO. Benecke.M et al., “Effect of LiF on Hot-Pressing of MgO”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), Jul. 1, 1967, vol. 50, No. 7, pp. 365-368.
Densification Mechanisms in Hot-Pressing of Mag- nesia with a Fugitive Liquid. Hart.P et al., “Densification Mechanisms in Hot-Pressing of Mag- nesia with a Fugitive Liquid”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), Feb. 1, 1970, vol. 53, No. 2, pp. 83-86.
New developments in the Inorganic Crystal Struc- ture Database (ICSD): Accessibility in support of materials research and design.. Belsky.A et al., “New developments in the Inorganic Crystal Struc- ture Database (ICSD): Accessibility in support of materials research and design.”, Acta. Cryst (Acta Crystallographica Section B), Jun. 1, 2002, vol. B58, No. 3, pp. 364-369.
SPES, 6Li MAS NMR, and Ni3+ EPR evidence for the formation of Co2+-containing spinel phases in LiCoO2 cycled electrode materials. Alcantara.R et al., “SPES, 6Li MAS NMR, and Ni3+ EPR evidence for the formation of Co2+-containing spinel phases in LiCoO2 cycled electrode materials”, Journal of Electroanalytical Chemistry, Aug. 28, 1998, vol. 454, No. 1-2, pp. 173-181.
Enhanced cycling stability of Li[Li 0.2Mn0.54Ni0. 13Co0.13]O2 by surface modification of MgO with melting impreg- nation method. Shi.S et al., “Enhanced cycling stability of Li[Li 0.2Mn0.54Ni0. 13Co0.13]O2 by surface modification of MgO with melting impreg- nation method”, Electrochimica Acta, Nov. 1, 2012, vol. 88, pp. 671-679.
Preparation and Characterization of LiCoO2 Thin Films by Laser Ablation Deposition. Antaya.M et al., “Preparation and Characterization of LiCoO2 Thin Films by Laser Ablation Deposition”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Mar. 1, 1993, vol. 140, No. 3, pp. 575-578. Koyama. Y et al., “Co K-edge XANES of LiCoO2 and CoO2 with a variety of structures by supercell density functional calculations with a core hole”, Phys. Rev. B (Physical Review. B), Feb. 27, 2012, vol. 85, No. 7, pp. 075129-1-075129-7.
XPS Investigation of the Electrolyte Induced Stabilization of LiCoO2 and “AlPO4. Quinlan.R et al., “XPS Investigation of the Electrolyte Induced Stabilization of LiCoO2 and “AlPO4”-Coated LiCoO2 Composite Electrodes”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Dec. 3, 2015, vol. 163, No. 2, pp. A300-A308.
Comparison of Al2O3- and AlPO4-coated LiCoO2 cathode materials for a Li-ion cell. Cho.J et al., “Comparison of Al2O3- and AlPO4-coated LiCoO2 cathode materials for a Li-ion cell”, Journal of Power Sources, 2005, vol. 146, pp. 58-64, Elsevier.
Electrochemical Characterizations of Commercial LiCoO2 Powders with surface Modified by Li3PO4 Nanoparticles. Jin.Y et al., “Electrochemical Characterizations of Commercial LiCoO2 Powders with surface Modified by Li3PO4 Nanoparticles”, Electrochemical and Solid-State Letters, Apr. 3, 2006, vol. 9, No. 6, pp. A273-A276.
Modification of LiCoO2 by surface Coating with MgO/TiO2/SiO2 for High-Performance Lithium-Ion Battery. Hong.W et al., “Modification of LiCoO2 by surface Coating with MgO/TiO2/SiO2 for High-Performance Lithium-Ion Battery”, Elec- trochemical and Solid-State Letters, Dec. 20, 2005, vol. 9, No. 2, pp. A82-A85.
M3(PO4)2-Nanoparticle-Coated LiCoO2 vs LiCo0. 96M0.04O2(M=Mg and Zn) on Electrochemical and Storage Char- acteristics. Eom.J et al., “M3(PO4)2-Nanoparticle-Coated LiCoO2 vs LiCo0. 96M0.04O2(M=Mg and Zn) on Electrochemical and Storage Char- acteristics”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Jan. 8, 2008, vol. 155, No. 3, pp. A201-A205.
Suppression of Cobalt Dissolution from the LiCoO2 Cathodes with Various Metal-Oxide Coatings. Kim.Y et al., “Suppression of Cobalt Dissolution from the LiCoO2 Cathodes with Various Metal-Oxide Coatings”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2003, vol. 150, No. 12, pp. A1723-A1725.
Effect of calcination temperature on the electro- chemical behavior of ZnO-coated LiCoO2 cathode. Fang.T et al., “Effect of calcination temperature on the electro- chemical behavior of ZnO-coated LiCoO2 cathode”, Surface & Coatings Technology, Apr. 19, 2006, vol. 201, No. 3-4, pp. 1886-1893, Elsevier.
Novel surface Modification Technique to Improve Electrochemical Performance of LiCoO2 at High Voltage. Park.S et al., “Novel surface Modification Technique to Improve Electrochemical Performance of LiCoO2 at High Voltage”, Elec- trochemical and Solid-State Letters, Apr. 21, 2005, vol. 8, No. 6, pp. A299-A302.
An effective method to reduce residual lithium com- pounds on Ni-rich Li[Ni0.6Co0.2Mn0.2]O2 active material using a phosphoric acid derived Li3PO4 nanolayer. Jo.C et al., “An effective method to reduce residual lithium com- pounds on Ni-rich Li[Ni0.6Co0.2Mn0.2]O2 active material using a phosphoric acid derived Li3PO4 nanolayer”, Nano Research, Dec. 4, 2014, vol. 8, No. 5, pp. 1464-1479, Springer.
Mechanisms of LiCoO2 Cathode Degradation by Reaction with HF and Protection by Thin Oxide Coatings. Tebbe.J et al., “Mechanisms of LiCoO2 Cathode Degradation by Reaction with HF and Protection by Thin Oxide Coatings”, ACS Applied Materials & Interfaces, Oct. 12, 2015, vol. 7, No. 43, pp. 24265-24278.
Review on Synthesis, Characterizations, and Electrochemical Properties of Cathode Materials for Lithium Ion Batteries. Bensalah.N et al., “Review on Synthesis, Characterizations, and Electrochemical Properties of Cathode Materials for Lithium Ion Batteries”, Journal of Material Science & Engineering, 2016, vol. 5, No. 4, pp. 1000258-1-1000258-21.
Recent progress on lithium-ion batteries with high electrochemical performance. Lu.Y et al., “Recent progress on lithium-ion batteries with high electrochemical performance”, Science China Chemistry, Feb. 25, 2019, vol. 62, No. 5, pp. 533-548. Xiao.B, “Surface Modifification of Electrode Materials for Lithium- Ion Batteries”, Graduate Program in Mechanical and Materials Engineering, 2006, pp. 1-235.
Investigation of the surface degradation of LiCoO2 particles in the cathode materials of Li-ion batteries using FIB-TOF-SIMS. Ohnishi.M et al., “Investigation of the surface degradation of LiCoO2 particles in the cathode materials of Li-ion batteries using FIB-TOF-SIMS”, Journal of surface Analysis, 2013, vol. 20, No. 2, pp. 99-110.
Impact of Lithium-Ion Ordering on surface Elec- tronic States of LixCoO2. Iwaya.K et al., “Impact of Lithium-Ion Ordering on surface Elec- tronic States of LixCoO2”, Phys. Rev. Lett. (Physical Review Letters), Sep. 20, 2013, vol. 111, No. 12, pp. 126104-1-126104-5.
Synthesis of High-Voltage (4.5 V) Cycling Doped LiCoO2 for Use in Lithium Rechargeable Cells. Zou.M et al., “Synthesis of High-Voltage (4.5 V) Cycling Doped LiCoO2 for Use in Lithium Rechargeable Cells”, Chem. Mater. (Chemistry of Materials), Dec. 16, 2003, vol. 15, No. 25, pp. 4699-4702.
Study of Cathode Materials for Lithium-Ion Batteries: Recent Progress and New Challenges. Schipper.F et al., “Study of Cathode Materials for Lithium-Ion Batteries: Recent Progress and New Challenges”, Inorganics, Apr. 28, 2017, vol. 5, No. 2, pp. 1-29.
Phase Transitions and High-Voltage Electrochemical Behavior of LiCoO2 Thin Films Grown by Pulsed Laser Deposi- tion. Xia.H et al., “Phase Transitions and High-Voltage Electrochemical Behavior of LiCoO2 Thin Films Grown by Pulsed Laser Deposi- tion”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2007, vol. 154, No. 4, pp. A337-A342.
Role of AlF3 Coating on LiCoO2 Particles during Cycling to Cutoff Voltage above 4.5 V. Sun.Y et al., “Role of AlF3 Coating on LiCoO2 Particles during Cycling to Cutoff Voltage above 4.5 V”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2009, vol. 156, No. 12, pp. A1005-A1010.
Electrochemical properties of LiNi1/3Co1/3Mn1/3O2 cathode material modified by coating withAl2O3 nanoparticles. Araki.K et al., “Electrochemical properties of LiNi1/3Co1/3Mn1/3O2 cathode material modified by coating withAl2O3 nanoparticles”, Journal of Power Sources, 2014, vol. 269, pp. 236-243.
Capacity fading behavior of Ni-rich layered cathode materials in Li-ion full cells. Kim.H et al., “Capacity fading behavior of Ni-rich layered cathode materials in Li-ion full cells”, Journal of Electroanalytical Chem- istry, 2016, vol. 782, pp. 168-173.
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries. Lin.F et al., “Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries”, Nature Communications, Mar. 27, 2014, vol. 5, pp. 3529-1-3529-9.
Surface Structure and High-Voltage Charge/Discharge Characteristics of Al-Oxide Coated LiNi1/3Co1/3Mn1/3O2 Cathodes. Yano.A et al., “Surface Structure and High-Voltage Charge/Discharge Characteristics of Al-Oxide Coated LiNi1/3Co1/3Mn1/3O2 Cathodes”, J. Electrochem. Soc. (Journal of the Electrochemi- cal Society), 2015, vol. 162, No. 2, pp. A3137-A3144.
Surface Structure and High-Voltage Charging/Discharging Performance of Low-Content Zr-Oxide-Coated LiNi1/3Co1/3Mn1/3O2. Yano.A et al., “Surface Structure and High-Voltage Charging/Discharging Performance of Low-Content Zr-Oxide-Coated LiNi1/3Co1/3Mn1/3O2”, J. Electrochem. Soc. (Journal of the Electro- chemical Society), 2016, vol. 163, No. 2, pp. A75-A82. Exhibit 1032 of IPR2023-01016, portions of JP-2015-201432A and Full translation. Exhibit 1028 of IPR2023-01349, Full translation of JP-2015- 201432A. Appendix C of EPR 90/019,447, portions of JP-2015-201432A and Full translation. Exhibit 1041 of EPR 90/019,535, JP-2015-201432A and Full trans- lation. Appendix LL of EPR 90/019,447, portions of JP-2012-074366A and Full translation.
US 5,910,382 A5,910,382 A 6/1999 Goodenough et al.
US 6,085,015 A6,085,015 A 7/2000 Armand et al.
US 6,218,050 B16,218,050 B1 4/2001 Yoon et al.
US 6,346,348 B16,346,348 B1 2/2002 Nakajima et al.
US 6,458,487 B16,458,487 B1 10/2002 Takeuchi et al.
US 6,514,640 B16,514,640 B1 2/2003 Armand et al.
US 6,582,814 B26,582,814 B2 6/2003 Swiler et al.
US 6,680,143 B26,680,143 B2 1/2004 Thackeray et al.
US 6,737,195 B26,737,195 B2 5/2004 Kweon et al.
US 6,753,111 B26,753,111 B2 6/2004 Kweon et al.
US 6,846,592 B26,846,592 B2 1/2005 Kweon et al.
US 6,919,144 B26,919,144 B2 7/2005 Miyazaki et al.
US 6,974,601 B26,974,601 B2 12/2005 Kweon et al.
US 6,984,469 B26,984,469 B2 1/2006 Kweon et al.
US 7,018,741 B27,018,741 B2 3/2006 Suhara et al.
US 7,138,209 B27,138,209 B2 11/2006 Kweon et al.
US 7,294,435 B27,294,435 B2 11/2007 Miyamoto et al.
US 7,303,840 B27,303,840 B2 12/2007 Thackeray et al.
US 7,309,546 B27,309,546 B2 12/2007 Kweon et al.
US 7,368,071 B27,368,071 B2 5/2008 Dahn et al.
US 7,393,476 B27,393,476 B2 7/2008 Shiozaki et al.
US 7,635,536 B27,635,536 B2 12/2009 Johnson et al.
US 7,709,148 B27,709,148 B2 5/2010 Kawasato et al.
US 7,709,151 B27,709,151 B2 5/2010 Inoue et al.
US 7,736,807 B27,736,807 B2 6/2010 Hasegawa et al.
US 7,790,308 B27,790,308 B2 9/2010 Johnson et al.
US 7,892,679 B27,892,679 B2 2/2011 Shimizu et al.
US 7,927,506 B27,927,506 B2 4/2011 Park
US 7,935,270 B27,935,270 B2 5/2011 Park
US 8,003,256 B28,003,256 B2 8/2011 Ohishi
US 8,007,941 B28,007,941 B2 8/2011 Kweon et al.
US 8,034,486 B28,034,486 B2 10/2011 Kweon et al.
US 8,080,340 B28,080,340 B2 12/2011 Thackeray et al.
US 8,236,449 B28,236,449 B2 8/2012 Nakura
US 8,470,477 B28,470,477 B2 6/2013 Miwa et al.
US 8,476,510 B28,476,510 B2 7/2013 Swager et al.
US 8,557,440 B28,557,440 B2 10/2013 Yu et al.
US 8,685,569 B28,685,569 B2 4/2014 Oguni et al.
US 8,685,570 B28,685,570 B2 4/2014 Miwa et al.
US 8,709,654 B28,709,654 B2 4/2014 Takeuchi et al.
US 8,753,532 B28,753,532 B2 6/2014 Levasseur et al.
US 8,808,918 B28,808,918 B2 8/2014 Jung et al.
US 8,877,377 B28,877,377 B2 11/2014 Hosoya
US 8,877,381 B28,877,381 B2 11/2014 Yasuda et al.
US 8,883,351 B28,883,351 B2 11/2014 Todoriki et al.
US 8,906,547 B28,906,547 B2 12/2014 Taniguchi et al.
US 8,927,148 B28,927,148 B2 1/2015 Kawakami
US 8,945,770 B28,945,770 B2 2/2015 Koo et al.
US 8,945,772 B28,945,772 B2 2/2015 Kawakami et al.
US 9,225,003 B29,225,003 B2 12/2015 Yukawa
US 9,227,850 B29,227,850 B2 1/2016 Ooishi
US 9,293,236 B29,293,236 B2 3/2016 Kawakami et al.
US 9,362,557 B29,362,557 B2 6/2016 Watanabe et al.
US 9,391,322 B29,391,322 B2 7/2016 Liu et al.
US 9,478,796 B29,478,796 B2 10/2016 Li et al.
US 9,505,631 B29,505,631 B2 11/2016 Masukuni et al.
US 9,515,313 B29,515,313 B2 12/2016 Umeyama et al.
US 9,601,764 B29,601,764 B2 3/2017 Kawakami et al.
US 9,666,326 B29,666,326 B2 5/2017 Kawakami et al.
US 9,698,420 B29,698,420 B2 7/2017 Ishizaki et al.
US 9,786,903 B29,786,903 B2 10/2017 Ryu et al.
US 9,899,664 B29,899,664 B2 2/2018 Yamaki et al.
US 9,923,244 B29,923,244 B2 3/2018 Takanashi et al.
US 10,128,495 B210,128,495 B2 11/2018 Satow et al.
US 10,243,215 B210,243,215 B2 3/2019 Shitaba et al.
US 10,361,432 B210,361,432 B2 7/2019 Takaichi et al.
US 10,938,035 B210,938,035 B2 3/2021 Yamakaji et al.
US 2001/0010807 A12001/0010807 A1 8/2001 Matsubara
US 2002/0102459 A12002/0102459 A1 8/2002 Hosoya et al.
US 2002/0110736 A12002/0110736 A1 8/2002 Kweon et al.
US 2002/0164156 A12002/0164156 A1 11/2002 Bilbrey
US 2002/0195591 A12002/0195591 A1 12/2002 Ravet et al.
US 2003/0104279 A12003/0104279 A1 6/2003 Miyazaki et al.
US 2003/0134186 A12003/0134186 A1 7/2003 Shizuki
US 2004/0229123 A12004/0229123 A1 11/2004 Takahashi et al.
US 2004/0229124 A12004/0229124 A1 11/2004 Miyamoto et al.
US 2004/0234857 A12004/0234857 A1 11/2004 Shiozaki et al.
US 2005/0019662 A12005/0019662 A1 1/2005 Suhara et al.
US 2006/0051671 A12006/0051671 A1 3/2006 Thackeray et al.
US 2006/0051673 A12006/0051673 A1 3/2006 Johnson et al.
US 2006/0121352 A12006/0121352 A1 6/2006 Kejha et al.
US 2006/0188780 A12006/0188780 A1 8/2006 Fujii et al.
US 2006/0275664 A12006/0275664 A1 12/2006 Ohzuku et al.
US 2006/0286459 A12006/0286459 A1 12/2006 Zhao et al.
US 2007/0026315 A12007/0026315 A1 2/2007 Lampe-Onnerud et al.
US 2007/0099086 A12007/0099086 A1 5/2007 Kang et al.
US 2007/0117014 A12007/0117014 A1 5/2007 Saito et al.
US 2007/0122712 A12007/0122712 A1 5/2007 Kang et al.
US 2007/0148546 A12007/0148546 A1 6/2007 Shimizu et al.
US 2007/0160906 A12007/0160906 A1 7/2007 Tooyama et al.
US 2007/0212609 A12007/0212609 A1 9/2007 Iwami
US 2007/0224506 A12007/0224506 A1 9/2007 Ooyama et al.
US 2008/0131780 A12008/0131780 A1 6/2008 Kawasato et al.
US 2008/0166637 A12008/0166637 A1 7/2008 Inagaki et al.
US 2008/0241693 A12008/0241693 A1 10/2008 Fukuchi et al.
US 2009/0011335 A12009/0011335 A1 1/2009 Takeda et al.
US 2009/0087731 A12009/0087731 A1 4/2009 Fukui et al.
US 2009/0104532 A12009/0104532 A1 4/2009 Hosoya
US 2009/0123813 A12009/0123813 A1 5/2009 Chiang et al.
US 2009/0123842 A12009/0123842 A1 5/2009 Thackeray et al.
US 2009/0220862 A12009/0220862 A1 9/2009 Toyama et al.
US 2010/0019194 A12010/0019194 A1 1/2010 Fujiwara et al.
US 2010/0035147 A12010/0035147 A1 2/2010 Kotato et al.
US 2010/0129714 A12010/0129714 A1 5/2010 Toyama et al.
US 2010/0129715 A12010/0129715 A1 5/2010 Saito et al.
US 2010/0143784 A12010/0143784 A1 6/2010 Johnson et al.
US 2010/0143799 A12010/0143799 A1 6/2010 Park
US 2010/0159330 A12010/0159330 A1 6/2010 Sugiura et al.
US 2010/0178464 A12010/0178464 A1 * 7/2010 Choi...................... B82Y 30/00examiner
US 2010/0216024 A12010/0216024 A1 8/2010 Kanno et al.
US 2010/0233542 A12010/0233542 A1 9/2010 Endo et al.
US 2010/0247986 A12010/0247986 A1 9/2010 Toyama et al.
US 2010/0248033 A12010/0248033 A1 9/2010 Kumar et al.
US 2011/0033749 A12011/0033749 A1 2/2011 Uchida et al.
US 2011/0059367 A12011/0059367 A1 3/2011 Morita et al.
US 2011/0076564 A12011/0076564 A1 3/2011 Yu et al.
US 2011/0200879 A12011/0200879 A1 8/2011 Saito et al.
US 2011/0229757 A12011/0229757 A1 9/2011 Kawakami et al.
US 2011/0256437 A12011/0256437 A1 10/2011 Katsuki. et al.
US 2011/0269023 A12011/0269023 A1 11/2011 Kawakami et al.
US 2011/0297876 A12011/0297876 A1 12/2011 Masukuni et al.
US 2011/0300441 A12011/0300441 A1 12/2011 Kawakami
US 2012/0034516 A12012/0034516 A1 2/2012 Koo et al.
US 2012/0045692 A12012/0045692 A1 2/2012 Takemura et al.
US 2012/0064406 A12012/0064406 A1 3/2012 Sato et al.
US 2012/0064409 A12012/0064409 A1 3/2012 Zhamu et al.
US 2012/0088151 A12012/0088151 A1 4/2012 Yamazaki et al.
US 2012/0088156 A12012/0088156 A1 4/2012 Nomoto et al.
US 2012/0118149 A12012/0118149 A1 5/2012 Dabrowski et al.
US 2012/0177974 A12012/0177974 A1 7/2012 Nakajima et al.
US 2012/0244430 A12012/0244430 A1 9/2012 Yamazaki et al.
US 2012/0256337 A12012/0256337 A1 10/2012 Yokoyama et al.
US 2012/0258358 A12012/0258358 A1 10/2012 Yura et al.
US 2012/0258365 A12012/0258365 A1 10/2012 Yokoyama et al.
US 2012/0258369 A12012/0258369 A1 10/2012 Yokoyama et al.
US 2012/0261622 A12012/0261622 A1 10/2012 Honma
US 2012/0295163 A12012/0295163 A1 11/2012 Yanagita et al.
US 2012/0308891 A12012/0308891 A1 12/2012 Todoriki et al.
US 2012/0315544 A12012/0315544 A1 12/2012 Yasuda et al.
US 2012/0328951 A12012/0328951 A1 12/2012 Hirohashi et al.
US 2012/0328956 A12012/0328956 A1 12/2012 Oguni et al.
US 2012/0330044 A12012/0330044 A1 * 12/2012 Hou....................... B82Y 30/00examiner
US 2013/0017435 A12013/0017435 A1 1/2013 Sato et al.
US 2013/0040193 A12013/0040193 A1 2/2013 Tsuchida et al.
US 2013/0045418 A12013/0045418 A1 2/2013 Oguni et al.
US 2013/0052547 A12013/0052547 A1 2/2013 Ogino et al.
US 2013/0065120 A12013/0065120 A1 3/2013 Miwa et al.
US 2013/0078516 A12013/0078516 A1 3/2013 Taniguchi et al.
US 2013/0084384 A12013/0084384 A1 4/2013 Yamakaji
US 2013/0130103 A12013/0130103 A1 5/2013 Kim et al.
US 2013/0134051 A12013/0134051 A1 5/2013 Takahashi et al.
US 2013/0156683 A12013/0156683 A1 6/2013 Holzapfel et al.
US 2013/0156942 A12013/0156942 A1 6/2013 Yamakaji et al.
US 2013/0157034 A12013/0157034 A1 6/2013 Choi et al.
US 2013/0164619 A12013/0164619 A1 6/2013 Yamakaji et al.
US 2013/0177806 A12013/0177806 A1 7/2013 Caldwell et al.
US 2013/0183579 A12013/0183579 A1 7/2013 Kim et al.
US 2013/0189585 A12013/0189585 A1 7/2013 Kang et al.
US 2013/0190449 A12013/0190449 A1 7/2013 Kinloch et al.
US 2013/0202953 A12013/0202953 A1 8/2013 Sharma et al.
US 2013/0212879 A12013/0212879 A1 8/2013 Ogino
US 2013/0266858 A12013/0266858 A1 10/2013 Inoue et al.
US 2013/0266859 A12013/0266859 A1 10/2013 Todoriki et al.
US 2013/0313471 A12013/0313471 A1 11/2013 Endo et al.
US 2013/0316237 A12013/0316237 A1 11/2013 Miki
US 2013/0337320 A12013/0337320 A1 12/2013 Yukawa
US 2014/0004412 A12014/0004412 A1 1/2014 Ogino
US 2014/0023920 A12014/0023920 A1 1/2014 Yamazaki et al.
US 2014/0079995 A12014/0079995 A1 3/2014 Wakada
US 2014/0099554 A12014/0099554 A1 4/2014 Inoue et al.
US 2014/0127567 A12014/0127567 A1 5/2014 Kuriki et al.
US 2014/0127568 A12014/0127568 A1 * 5/2014 Kawakami.......... H01M 4/1393examiner
US 2014/0131633 A12014/0131633 A1 5/2014 Ito et al.
US 2014/0162132 A12014/0162132 A1 6/2014 Ishii et al.
US 2014/0166946 A12014/0166946 A1 6/2014 Miwa et al.
US 2014/0184172 A12014/0184172 A1 7/2014 Momo et al.
US 2014/0234700 A12014/0234700 A1 8/2014 Moriwaka et al.
US 2014/0275323 A12014/0275323 A1 9/2014 Thibodeau et al.
US 2014/0295068 A12014/0295068 A1 10/2014 Nanba et al.
US 2014/0315083 A12014/0315083 A1 * 10/2014 Liu....................... H01M 4/622examiner
US 2014/0332715 A12014/0332715 A1 11/2014 Kawakami et al.
US 2014/0370184 A12014/0370184 A1 12/2014 Takemura. et al.
US 2015/0014581 A12015/0014581 A1 1/2015 Kawakami et al.
US 2015/0014605 A12015/0014605 A1 1/2015 Kawakami et al.
US 2015/0064565 A12015/0064565 A1 3/2015 Todoriki et al.
US 2015/0093648 A12015/0093648 A1 4/2015 Son et al.
US 2015/0099178 A12015/0099178 A1 4/2015 Kawakami et al.
US 2015/0099179 A12015/0099179 A1 4/2015 Ikenuma et al.
US 2015/0123050 A12015/0123050 A1 5/2015 Yamazaki et al.
US 2015/0155556 A12015/0155556 A1 6/2015 Kawakami et al.
US 2015/0166348 A12015/0166348 A1 6/2015 Ikenuma et al.
US 2015/0262762 A12015/0262762 A1 9/2015 Ikenuma et al.
US 2015/0325855 A12015/0325855 A1 11/2015 Kawakami et al.
US 2015/0333320 A12015/0333320 A1 11/2015 Tamaki et al.
US 2015/0333324 A12015/0333324 A1 11/2015 Umeyama et al.
US 2015/0357641 A12015/0357641 A1 12/2015 Sugie et al.
US 2015/0380737 A12015/0380737 A1 12/2015 Kawasato et al.
US 2016/0006032 A12016/0006032 A1 1/2016 Paulsen et al.
US 2016/0028080 A12016/0028080 A1 1/2016 Sugiura
US 2016/0046771 A12016/0046771 A1 2/2016 Thibodeau et al.
US 2016/0064726 A12016/0064726 A1 3/2016 Ikenuma et al.
US 2016/0087315 A12016/0087315 A1 3/2016 Oyama
US 2016/0118646 A12016/0118646 A1 4/2016 Ikenuma
US 2016/0118658 A12016/0118658 A1 4/2016 Kawakami et al.
US 2016/0156030 A12016/0156030 A1 6/2016 Sun et al.
US 2016/0164089 A12016/0164089 A1 6/2016 Kawakami et al.
US 2016/0276658 A12016/0276658 A1 9/2016 Choi et al.
US 2016/0285102 A12016/0285102 A1 9/2016 Shitaba et al.
US 2016/0329533 A12016/0329533 A1 11/2016 Tajima
US 2016/0349905 A12016/0349905 A1 12/2016 Momma et al.
US 2016/0380271 A12016/0380271 A1 12/2016 Ochiai et al.
US 2017/0005364 A12017/0005364 A1 1/2017 Yamazaki et al.
US 2017/0040594 A12017/0040594 A1 2/2017 Yamaki et al.
US 2017/0062819 A12017/0062819 A1 3/2017 Ikenuma
US 2017/0069907 A12017/0069907 A1 3/2017 Zhu et al.
US 2017/0117589 A12017/0117589 A1 4/2017 Tajima et al.
US 2017/0187035 A12017/0187035 A1 6/2017 Yanagihara et al.
US 2017/0207444 A12017/0207444 A1 7/2017 Yanagihara et al.
US 2017/0256817 A12017/0256817 A1 9/2017 Kadoma et al.
US 2017/0309910 A12017/0309910 A1 10/2017 Jo et al.
US 2018/0013130 A12018/0013130 A1 1/2018 Ochiai et al.
US 2018/0019462 A12018/0019462 A1 1/2018 Kadoma et al.
US 2018/0040888 A12018/0040888 A1 2/2018 Park et al.
US 2018/0040897 A12018/0040897 A1 2/2018 Park et al.
US 2018/0102536 A12018/0102536 A1 4/2018 Kawakami et al.
US 2018/0108944 A12018/0108944 A1 4/2018 Yamakaji
US 2018/0145317 A12018/0145317 A1 5/2018 Momma et al.
US 2018/0145368 A12018/0145368 A1 5/2018 Ochiai et al.
US 2018/0254477 A12018/0254477 A1 9/2018 Horikawa et al.
US 2018/0331365 A12018/0331365 A1 * 11/2018 Joo..................... H01M 4/0404examiner
US 2018/0366729 A12018/0366729 A1 12/2018 Yanagita et al.
US 2020/0144601 A12020/0144601 A1 5/2020 Takahashi et al.
US 2020/0152961 A12020/0152961 A1 5/2020 Momma et al.
US 2020/0176770 A12020/0176770 A1 6/2020 Takahashi et al.
US 2021/0175507 A12021/0175507 A1 6/2021 Yamakaji et al.
CN 102694201 ACN 102694201 A 9/2012
CN 102569775 BCN 102569775 B 1/2017
Cited non-patent literature · 74
Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Bat- teries. Joshi.T et al., “Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Bat- teries”, J. Electrochem. SOC. (Journal of the Electrochemical Society), 2014, vol. 161, No. 12, pp. A1915-A1921.
High-energy cathode material for long-life and safe lithium batteries. Sun.Y et al., “High-energy cathode material for long-life and safe lithium batteries”, Nature Materials, Mar. 22, 2009, vol. 8, pp. 320-324.
Li2MnO3-stabilized LiMO2(M=Mn, Ni, Co) electrodes for lithium-ion batteries. Thackeray.M et al., “Li2MnO3-stabilized LiMO2(M=Mn, Ni, Co) electrodes for lithium-ion batteries”, J. Mater. Chem. (Journal of Materials Chemistry), 2007, vol. 17, pp. 3112-3125.
Magnetic properties of the chemically delithiated LixMn2O4 with 0.07 ≤x≤1. Mukalk et al., “Magnetic properties of the chemically delithiated LixMn2O4 with 0.07 ≤x≤1”, Journal of Solid State Chemistry, May 1, 2011, vol. 184, No. 5, pp. 1096-1104.
Antiferromagnetic ordering in Li2MnO3 single crys- tals with a two-dimensional honeycomb lattice. Lee.S et al., “Antiferromagnetic ordering in Li2MnO3 single crys- tals with a two-dimensional honeycomb lattice”, Journal of Physics: Condensed Matter, Nov. 14, 2012, vol. 24, No. 45, pp. 456004-1- 456004-9.
The Chemistry of Graphene Oxide. Dreyer.D et al., “The Chemistry of Graphene Oxide”, Chemical Society Reviews, Nov. 3, 2009, vol. 39, No. 1, pp. 228-240.
EELS analysis of cation valence states and oxygen vacancies in magnetic oxides. Wang.Z et al., “EELS analysis of cation valence states and oxygen vacancies in magnetic oxides”, Micron, Oct. 1, 2000, vol. 31, No. 5, pp. 571-580, Elsevier.
Oxidation state and chemical shift investigation in transition metal oxides by EELS. Tan.H et al., “Oxidation state and chemical shift investigation in transition metal oxides by EELS”, Ultramicroscopy, May 1, 2012, vol. 116, pp. 24-33, Elsevier.
Thermogravimetry and X-Ray Diffraction Study of the Thermal Decomposition Processes in xLi2CO3—MnCO3 Mixtures. Berbenni.V et al., “Thermogravimetry and X-Ray Diffraction Study of the Thermal Decomposition Processes in xLi2CO3—MnCO3 Mixtures”, Journal of Analytical and Applied Pyrolysis, 2002, vol. 62, pp. 45-62.
Lithium-manganese oxide electrodes with layered- spinel composite structures xLi2MnO3 v (1-x)Li1+yMn2- yO4(0<x<1,0≤y≤0.33) for lithium batteries. Johnson.C et al., “Lithium-manganese oxide electrodes with layered- spinel composite structures xLi2MnO3 v (1-x)Li1+yMn2- yO4(0<x<1,0≤y≤0.33) for lithium batteries”, Electrochemistry Com- munications, May 1, 2005, vol. 7, No. 5, pp. 528-536, Elsevier.
Growth modes in two-dimensional heteroepitaxy on an elasticsubstrate. Katsuno.H et al., “Growth modes in two-dimensional heteroepitaxy on an elasticsubstrate”, J. Cryst. Growth (Journal of Crystal Growth), Feb. 15, 2005, vol. 275, No. 1-2, pp. e263-e288, Elsevier.
Characterization of MgO-coated-LiCoO2 par- ticles by analytical transmission electron microscopy. Taguchi.N et al., “Characterization of MgO-coated-LiCoO2 par- ticles by analytical transmission electron microscopy”, Journal of Power Sources, 2016, vol. 328, pp. 161-166, Elsevier.
Structural Studies on the Effects of ZrO2 Coating on LiCoO2 during Cycling Using In Situ X-Ray Diffraction Tech- nique. Chung.K et al., “Structural Studies on the Effects of ZrO2 Coating on LiCoO2 during Cycling Using In Situ X-Ray Diffraction Tech- nique”, J. Electrochem. Soc. (Journal of the Electrochemical Soci- ety), 2006, vol. 153, No. 11, pp. A2152-A2157.
Electrochemical and In Situ Synchrotron XRD Studies on Al2O3-Coated LiCoO2 Cathode Material. Liu.L et al., “Electrochemical and In Situ Synchrotron XRD Studies on Al2O3-Coated LiCoO2 Cathode Material”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2004, vol. 151, No. 9, pp. A1344-A1351.
LICoO2 Degradation Behavior in the High-Voltage Phase Transition Region and Improved Reversibility with surface Coating. Yano.A et al., “LICoO2 Degradation Behavior in the High-Voltage Phase Transition Region and Improved Reversibility with surface Coating”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2017, vol. 164, No. 1, pp. A6116-A6122.
Staging PhaseTransitions in LixCoO2. Chen.Z et al., “Staging PhaseTransitions in LixCoO2”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2002, vol. 149, No. 12, pp. A1604-A1609.
The spinel and cubic rocksalt solid-solutions in the Li—Mn—Ni oxide pseudo-ternary system. McCalla.E et al., “The spinel and cubic rocksalt solid-solutions in the Li—Mn—Ni oxide pseudo-ternary system”, Solid State Ionics, May 2, 2013, vol. 242, pp. 1-9, Elsevier.
Characterization of Spinel LixCo204-Coated LiCo02 Prepared with Post-Thermal Treatment as a Cathode Material for Lithium ion Batteries. Shim.J et al., “Characterization of Spinel LixCo204-Coated LiCo02 Prepared with Post-Thermal Treatment as a Cathode Material for Lithium ion Batteries”, Chem. Mater. (Chemistry of Materials), Apr. 10, 2015, vol. 27, No. 9, pp. 3273-3279.
Correlation of lithium ion distribution and X-ray absorption near-edge structure in O3- and O2-lithium cobalt oxides from first-principle calculation. Okumura.T et al., “Correlation of lithium ion distribution and X-ray absorption near-edge structure in O3- and O2-lithium cobalt oxides from first-principle calculation”, Journal of Materials Chemistry, 2012, vol. 22, pp. 17340-17348.
Electronic phase diagram of the layered cobalt oxide system LixCoO2 (0.0≤x≤1.0). Motohashi.T et al., “Electronic phase diagram of the layered cobalt oxide system LixCoO2 (0.0≤x≤1.0)”, Phys. Rev. B (Physical Review. B), Oct. 9, 2009, vol. 80, No. 16, pp. 165114-1-155114-9.
Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide TEM Investigation. Gabrisch.H et al., “Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide TEM Investigation”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2004, vol. 151, No. 6, pp. A891-A897.
Khedr.A et al., “Synthesis, Structure, and Electrochemistry of Sm-Modified LiMn2O4 Cathode Materials for Lithium-Ion Batter-
ies”, J. Electron. Mater.(Journal of Electronic Materials), Apr. 23, 2013, vol. 42, No. 6, pp. 1275-1281.
Fluoride Model Systems: II, The Binary Systems CaF2—BeF2, MgF2—BeF2, and LiF—MgF2. Counts.W et al., “Fluoride Model Systems: II, The Binary Systems CaF2—BeF2, MgF2—BeF2, and LiF—MgF2”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), 1953, vol. 36, No. 1, pp. 12-17.
Synthesis of Mg and Mn Doped LiCoO2 and Effects on High Voltage Cycling. Liu.A et al., “Synthesis of Mg and Mn Doped LiCoO2 and Effects on High Voltage Cycling”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Jun. 2, 2017, vol. 164, No. 7, pp. A1655- A1664.
Electronic Conductivity of LICoO2 and Its Enhancement by Magnesium Doping. Tukamoto.H et al., “Electronic Conductivity of LICoO2 and Its Enhancement by Magnesium Doping”, J. Electrochem. Soc. (Jour- nal of the Electrochemical Society), Sep. 1, 1997, vol. 144, No. 9, pp. 3164-3168.
Solid-State Redox Reactions of LiCoO2 (R-3m) for 4 Volt Secondary Lithium Cells. Ohzuku.T et al., “Solid-State Redox Reactions of LiCoO2 (R-3m) for 4 Volt Secondary Lithium Cells”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Nov. 1, 1994, vol. 141, No. 11, pp. 2972-2977.
CoO2, The End Member of the LixCoO2 Solid Solution. Amatucci.G et al., “CoO2, The End Member of the LixCoO2 Solid Solution”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Mar. 1, 1996, vol. 143, No. 3, pp. 1114-1123.
Structural and electrochemical characterizations of surface-modified LiCoO2 cathode materials for Li-ion batteries. Wang.Z et al., “Structural and electrochemical characterizations of surface-modified LiCoO2 cathode materials for Li-ion batteries”, Solid State Ionics, Jun. 2, 2002, vol. 148, No. 3-4, pp. 335-342, Elsevier.
Synthesis and Electrochemical Performance of High Voltage Cycling LiM0.05Co0.95O2 as Cathode Material for Lithium Rechargeable Cells. Zou.M et al., “Synthesis and Electrochemical Performance of High Voltage Cycling LiM0.05Co0.95O2 as Cathode Material for Lithium Rechargeable Cells”, Electrochemical and Solid-State Letters, 2004, vol. 7, No. 7, pp. A176-A179.
Improving the cycling stability of LiCoO2 at 4.5 V through co-modification by Mg doping and zirconium oxyfluoride coating. Wang.Z et al., “Improving the cycling stability of LiCoO2 at 4.5 V through co-modification by Mg doping and zirconium oxyfluoride coating”, Ceramics Internationa, 2015, vol. 41, No. 1, pp. 469-474.
High Performance LiCoO2 Cathode Materials at 60° C. for Lithium Secondary Batteries Prepared by the Facile Nanoscale Dry-Coating Method. Cho.Y et al., “High Performance LiCoO2 Cathode Materials at 60° C. for Lithium Secondary Batteries Prepared by the Facile Nanoscale Dry-Coating Method”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), 2010, vol. 157, No. 5, pp. A617-A624.
Mg doping and zirconium oxyfluoride coating co-modification to enhance the high-voltage performance of LiCoO2 for lithium ion battery. Wang.Z et al., “Mg doping and zirconium oxyfluoride coating co-modification to enhance the high-voltage performance of LiCoO2 for lithium ion battery”, Journal of Alloys and Compounds, Feb. 5, 2015, vol. 621, pp. 212-219.
Effect of Mg doping and MgO-surface modi- fication on the cycling stability of LiCoO2 electrodes.. Mladenov.M et al., “Effect of Mg doping and MgO-surface modi- fication on the cycling stability of LiCoO2 electrodes.”, Electro- chemistry Communications, Aug. 1, 2001, vol. 3, No. 8, pp. 410-416.
Effects of metal oxide coatings on the thermal stability and electrical performance of LiCoCO2 in a Li-ion cell. Kweon.H et al., “Effects of metal oxide coatings on the thermal stability and electrical performance of LiCoCO2 in a Li-ion cell”, Journal of Power Sources, Feb. 16, 2004, vol. 126, pp. 156-162, Elsevier.
Effects of MgO Coating on the Structural and Electrochemical Characteristics of LiCoO2 as Cathode Materials for Lithium Ion Battery. Shim.J et al., “Effects of MgO Coating on the Structural and Electrochemical Characteristics of LiCoO2 as Cathode Materials for Lithium Ion Battery”, Chem. Mater. (Chemistry of Materials), Mar. 24, 2014, vol. 26, No. 8, pp. 2537-2543.
Improvement of electrochemical stability of LiCoO2 cathode by a nano-crystalline coating. Zhao.H et al., “Improvement of electrochemical stability of LiCoO2 cathode by a nano-crystalline coating”, Journal of Power Sources, May 20, 2004, vol. 132, pp. 195-200, Elsevier.
Effects of surface modification by MgO on interfacial reactions of lithium cobalt oxide thin film electrode. Iriyama.Y et al., “Effects of surface modification by MgO on interfacial reactions of lithium cobalt oxide thin film electrode”, Journal of Power Sources, Oct. 5, 2004, vol. 137, pp. 111-116, Elsevier.
Origin of surface Coating Effect for MgO on LiCoO2 to Improve the Interfacial Reaction between Electrode and Electrolyte. Orikasa.Y et al., “Origin of surface Coating Effect for MgO on LiCoO2 to Improve the Interfacial Reaction between Electrode and Electrolyte”, Adv. Mater.Interfaces (Advanced Materials Inter- faces), Aug. 28, 2014, vol. 1, No. 9, pp. 1400195-1-1400195-8.
Stabilization of the Electronic Structure at the Cathode/Electrolyte Interface via MgO Ultra-thin Layer during Lithium-ions Insertion/Extraction. Yamamoto.K et al., “Stabilization of the Electronic Structure at the Cathode/Electrolyte Interface via MgO Ultra-thin Layer during Lithium-ions Insertion/Extraction”, Electrochemistry, Oct. 5, 2014, vol. 82, No. 10, pp. 891-896.
Synergistic effects of coating and doping for lithium ion battery cathode materials: synthesis and characterization of lithium titanate-coated LiCoO2 with Mg doping. Shim.J et al., “Synergistic effects of coating and doping for lithium ion battery cathode materials: synthesis and characterization of lithium titanate-coated LiCoO2 with Mg doping”, Electrochimica Acta, Dec. 20, 2015, vol. 186, pp. 201-208, Elesevier.
in situ Total-Reflection Fluorescence X-Ray Absorption Spectroscopic Study on Stability at LiFePO4/Electro- lyte Interface. Yamamoto.K et al., “in situ Total-Reflection Fluorescence X-Ray Absorption Spectroscopic Study on Stability at LiFePO4/Electro- lyte Interface”, 224th ECS Meeting Abstract, Oct. 27, 2013, p. 923.
Electrochemical Evaluation and Structural Charac- terization of Commercial LiCoO2 Surfaces Modified with MgO for Lithium-Ion Batteries. Wang.Z et al., “Electrochemical Evaluation and Structural Charac- terization of Commercial LiCoO2 Surfaces Modified with MgO for Lithium-Ion Batteries”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), Mar. 4, 2002, vol. 149, No. 4, pp. A466-A471.
Phase Transition of Bare and Coated LixCoO2 (x=0.4 and 0.24) at 300° C.. Lee.Y et al., “Phase Transition of Bare and Coated LixCoO2 (x=0.4 and 0.24) at 300° C.”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), Jul. 28, 2005, vol. 152, No. 9, pp. A1824- A1827.
Impact of active material surface area on thermal stability of LiCoO2 cathode. Geder.J et al., “Impact of active material surface area on thermal stability of LiCoO2 cathode”, Journal of Power Sources, Jul. 1, 2014, vol. 257, pp. 286-292, Elsevier.
Effect of LiF on Hot-Pressing of MgO. Benecke.M et al., “Effect of LiF on Hot-Pressing of MgO”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), Jul. 1, 1967, vol. 50, No. 7, pp. 365-368.
Densification Mechanisms in Hot-Pressing of Mag- nesia with a Fugitive Liquid. Hart.P et al., “Densification Mechanisms in Hot-Pressing of Mag- nesia with a Fugitive Liquid”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), Feb. 1, 1970, vol. 53, No. 2, pp. 83-86.
New developments in the Inorganic Crystal Struc- ture Database (ICSD): Accessibility in support of materials research and design.. Belsky.A et al., “New developments in the Inorganic Crystal Struc- ture Database (ICSD): Accessibility in support of materials research and design.”, Acta. Cryst (Acta Crystallographica Section B), Jun. 1, 2002, vol. B58, No. 3, pp. 364-369.
SPES, 6Li MAS NMR, and Ni3+ EPR evidence for the formation of Co2+-containing spinel phases in LiCoO2 cycled electrode materials. Alcantara.R et al., “SPES, 6Li MAS NMR, and Ni3+ EPR evidence for the formation of Co2+-containing spinel phases in LiCoO2 cycled electrode materials”, Journal of Electroanalytical Chemistry, Aug. 28, 1998, vol. 454, No. 1-2, pp. 173-181.
Enhanced cycling stability of Li[Li 0.2Mn0.54Ni0. 13Co0.13]O2 by surface modification of MgO with melting impreg- nation method. Shi.S et al., “Enhanced cycling stability of Li[Li 0.2Mn0.54Ni0. 13Co0.13]O2 by surface modification of MgO with melting impreg- nation method”, Electrochimica Acta, Nov. 1, 2012, vol. 88, pp. 671-679.
Preparation and Characterization of LiCoO2 Thin Films by Laser Ablation Deposition. Antaya.M et al., “Preparation and Characterization of LiCoO2 Thin Films by Laser Ablation Deposition”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Mar. 1, 1993, vol. 140, No. 3, pp. 575-578. Koyama. Y et al., “Co K-edge XANES of LiCoO2 and CoO2 with a variety of structures by supercell density functional calculations with a core hole”, Phys. Rev. B (Physical Review. B), Feb. 27, 2012, vol. 85, No. 7, pp. 075129-1-075129-7.
XPS Investigation of the Electrolyte Induced Stabilization of LiCoO2 and “AlPO4. Quinlan.R et al., “XPS Investigation of the Electrolyte Induced Stabilization of LiCoO2 and “AlPO4”-Coated LiCoO2 Composite Electrodes”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Dec. 3, 2015, vol. 163, No. 2, pp. A300-A308.
Comparison of Al2O3- and AlPO4-coated LiCoO2 cathode materials for a Li-ion cell. Cho.J et al., “Comparison of Al2O3- and AlPO4-coated LiCoO2 cathode materials for a Li-ion cell”, Journal of Power Sources, 2005, vol. 146, pp. 58-64, Elsevier.
Electrochemical Characterizations of Commercial LiCoO2 Powders with surface Modified by Li3PO4 Nanoparticles. Jin.Y et al., “Electrochemical Characterizations of Commercial LiCoO2 Powders with surface Modified by Li3PO4 Nanoparticles”, Electrochemical and Solid-State Letters, Apr. 3, 2006, vol. 9, No. 6, pp. A273-A276.
Modification of LiCoO2 by surface Coating with MgO/TiO2/SiO2 for High-Performance Lithium-Ion Battery. Hong.W et al., “Modification of LiCoO2 by surface Coating with MgO/TiO2/SiO2 for High-Performance Lithium-Ion Battery”, Elec- trochemical and Solid-State Letters, Dec. 20, 2005, vol. 9, No. 2, pp. A82-A85.
M3(PO4)2-Nanoparticle-Coated LiCoO2 vs LiCo0. 96M0.04O2(M=Mg and Zn) on Electrochemical and Storage Char- acteristics. Eom.J et al., “M3(PO4)2-Nanoparticle-Coated LiCoO2 vs LiCo0. 96M0.04O2(M=Mg and Zn) on Electrochemical and Storage Char- acteristics”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Jan. 8, 2008, vol. 155, No. 3, pp. A201-A205.
Suppression of Cobalt Dissolution from the LiCoO2 Cathodes with Various Metal-Oxide Coatings. Kim.Y et al., “Suppression of Cobalt Dissolution from the LiCoO2 Cathodes with Various Metal-Oxide Coatings”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2003, vol. 150, No. 12, pp. A1723-A1725.
Effect of calcination temperature on the electro- chemical behavior of ZnO-coated LiCoO2 cathode. Fang.T et al., “Effect of calcination temperature on the electro- chemical behavior of ZnO-coated LiCoO2 cathode”, Surface & Coatings Technology, Apr. 19, 2006, vol. 201, No. 3-4, pp. 1886-1893, Elsevier.
Novel surface Modification Technique to Improve Electrochemical Performance of LiCoO2 at High Voltage. Park.S et al., “Novel surface Modification Technique to Improve Electrochemical Performance of LiCoO2 at High Voltage”, Elec- trochemical and Solid-State Letters, Apr. 21, 2005, vol. 8, No. 6, pp. A299-A302.
An effective method to reduce residual lithium com- pounds on Ni-rich Li[Ni0.6Co0.2Mn0.2]O2 active material using a phosphoric acid derived Li3PO4 nanolayer. Jo.C et al., “An effective method to reduce residual lithium com- pounds on Ni-rich Li[Ni0.6Co0.2Mn0.2]O2 active material using a phosphoric acid derived Li3PO4 nanolayer”, Nano Research, Dec. 4, 2014, vol. 8, No. 5, pp. 1464-1479, Springer.
Mechanisms of LiCoO2 Cathode Degradation by Reaction with HF and Protection by Thin Oxide Coatings. Tebbe.J et al., “Mechanisms of LiCoO2 Cathode Degradation by Reaction with HF and Protection by Thin Oxide Coatings”, ACS Applied Materials & Interfaces, Oct. 12, 2015, vol. 7, No. 43, pp. 24265-24278.
Review on Synthesis, Characterizations, and Electrochemical Properties of Cathode Materials for Lithium Ion Batteries. Bensalah.N et al., “Review on Synthesis, Characterizations, and Electrochemical Properties of Cathode Materials for Lithium Ion Batteries”, Journal of Material Science & Engineering, 2016, vol. 5, No. 4, pp. 1000258-1-1000258-21.
Recent progress on lithium-ion batteries with high electrochemical performance. Lu.Y et al., “Recent progress on lithium-ion batteries with high electrochemical performance”, Science China Chemistry, Feb. 25, 2019, vol. 62, No. 5, pp. 533-548. Xiao.B, “Surface Modifification of Electrode Materials for Lithium- Ion Batteries”, Graduate Program in Mechanical and Materials Engineering, 2006, pp. 1-235.
Investigation of the surface degradation of LiCoO2 particles in the cathode materials of Li-ion batteries using FIB-TOF-SIMS. Ohnishi.M et al., “Investigation of the surface degradation of LiCoO2 particles in the cathode materials of Li-ion batteries using FIB-TOF-SIMS”, Journal of surface Analysis, 2013, vol. 20, No. 2, pp. 99-110.
Impact of Lithium-Ion Ordering on surface Elec- tronic States of LixCoO2. Iwaya.K et al., “Impact of Lithium-Ion Ordering on surface Elec- tronic States of LixCoO2”, Phys. Rev. Lett. (Physical Review Letters), Sep. 20, 2013, vol. 111, No. 12, pp. 126104-1-126104-5.
Synthesis of High-Voltage (4.5 V) Cycling Doped LiCoO2 for Use in Lithium Rechargeable Cells. Zou.M et al., “Synthesis of High-Voltage (4.5 V) Cycling Doped LiCoO2 for Use in Lithium Rechargeable Cells”, Chem. Mater. (Chemistry of Materials), Dec. 16, 2003, vol. 15, No. 25, pp. 4699-4702.
Study of Cathode Materials for Lithium-Ion Batteries: Recent Progress and New Challenges. Schipper.F et al., “Study of Cathode Materials for Lithium-Ion Batteries: Recent Progress and New Challenges”, Inorganics, Apr. 28, 2017, vol. 5, No. 2, pp. 1-29.
Phase Transitions and High-Voltage Electrochemical Behavior of LiCoO2 Thin Films Grown by Pulsed Laser Deposi- tion. Xia.H et al., “Phase Transitions and High-Voltage Electrochemical Behavior of LiCoO2 Thin Films Grown by Pulsed Laser Deposi- tion”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2007, vol. 154, No. 4, pp. A337-A342.
Role of AlF3 Coating on LiCoO2 Particles during Cycling to Cutoff Voltage above 4.5 V. Sun.Y et al., “Role of AlF3 Coating on LiCoO2 Particles during Cycling to Cutoff Voltage above 4.5 V”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2009, vol. 156, No. 12, pp. A1005-A1010.
Electrochemical properties of LiNi1/3Co1/3Mn1/3O2 cathode material modified by coating withAl2O3 nanoparticles. Araki.K et al., “Electrochemical properties of LiNi1/3Co1/3Mn1/3O2 cathode material modified by coating withAl2O3 nanoparticles”, Journal of Power Sources, 2014, vol. 269, pp. 236-243.
Capacity fading behavior of Ni-rich layered cathode materials in Li-ion full cells. Kim.H et al., “Capacity fading behavior of Ni-rich layered cathode materials in Li-ion full cells”, Journal of Electroanalytical Chem- istry, 2016, vol. 782, pp. 168-173.
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries. Lin.F et al., “Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries”, Nature Communications, Mar. 27, 2014, vol. 5, pp. 3529-1-3529-9.
Surface Structure and High-Voltage Charge/Discharge Characteristics of Al-Oxide Coated LiNi1/3Co1/3Mn1/3O2 Cathodes. Yano.A et al., “Surface Structure and High-Voltage Charge/Discharge Characteristics of Al-Oxide Coated LiNi1/3Co1/3Mn1/3O2 Cathodes”, J. Electrochem. Soc. (Journal of the Electrochemi- cal Society), 2015, vol. 162, No. 2, pp. A3137-A3144.
Surface Structure and High-Voltage Charging/Discharging Performance of Low-Content Zr-Oxide-Coated LiNi1/3Co1/3Mn1/3O2. Yano.A et al., “Surface Structure and High-Voltage Charging/Discharging Performance of Low-Content Zr-Oxide-Coated LiNi1/3Co1/3Mn1/3O2”, J. Electrochem. Soc. (Journal of the Electro- chemical Society), 2016, vol. 163, No. 2, pp. A75-A82. Exhibit 1032 of IPR2023-01016, portions of JP-2015-201432A and Full translation. Exhibit 1028 of IPR2023-01349, Full translation of JP-2015- 201432A. Appendix C of EPR 90/019,447, portions of JP-2015-201432A and Full translation. Exhibit 1041 of EPR 90/019,535, JP-2015-201432A and Full trans- lation. Appendix LL of EPR 90/019,447, portions of JP-2012-074366A and Full translation.
US 5,910,382 A5,910,382 A 6/1999 Goodenough et al.
US 6,085,015 A6,085,015 A 7/2000 Armand et al.
US 6,218,050 B16,218,050 B1 4/2001 Yoon et al.
US 6,346,348 B16,346,348 B1 2/2002 Nakajima et al.
US 6,458,487 B16,458,487 B1 10/2002 Takeuchi et al.
US 6,514,640 B16,514,640 B1 2/2003 Armand et al.
US 6,582,814 B26,582,814 B2 6/2003 Swiler et al.
US 6,680,143 B26,680,143 B2 1/2004 Thackeray et al.
US 6,737,195 B26,737,195 B2 5/2004 Kweon et al.
US 6,753,111 B26,753,111 B2 6/2004 Kweon et al.
US 6,846,592 B26,846,592 B2 1/2005 Kweon et al.
US 6,919,144 B26,919,144 B2 7/2005 Miyazaki et al.
US 6,974,601 B26,974,601 B2 12/2005 Kweon et al.
US 6,984,469 B26,984,469 B2 1/2006 Kweon et al.
US 7,018,741 B27,018,741 B2 3/2006 Suhara et al.
US 7,138,209 B27,138,209 B2 11/2006 Kweon et al.
US 7,294,435 B27,294,435 B2 11/2007 Miyamoto et al.
US 7,303,840 B27,303,840 B2 12/2007 Thackeray et al.
US 7,309,546 B27,309,546 B2 12/2007 Kweon et al.
US 7,368,071 B27,368,071 B2 5/2008 Dahn et al.
US 7,393,476 B27,393,476 B2 7/2008 Shiozaki et al.
US 7,635,536 B27,635,536 B2 12/2009 Johnson et al.
US 7,709,148 B27,709,148 B2 5/2010 Kawasato et al.
US 7,709,151 B27,709,151 B2 5/2010 Inoue et al.
US 7,736,807 B27,736,807 B2 6/2010 Hasegawa et al.
US 7,790,308 B27,790,308 B2 9/2010 Johnson et al.
US 7,892,679 B27,892,679 B2 2/2011 Shimizu et al.
US 7,927,506 B27,927,506 B2 4/2011 Park
US 7,935,270 B27,935,270 B2 5/2011 Park
US 8,003,256 B28,003,256 B2 8/2011 Ohishi
US 8,007,941 B28,007,941 B2 8/2011 Kweon et al.
US 8,034,486 B28,034,486 B2 10/2011 Kweon et al.
US 8,080,340 B28,080,340 B2 12/2011 Thackeray et al.
US 8,236,449 B28,236,449 B2 8/2012 Nakura
US 8,470,477 B28,470,477 B2 6/2013 Miwa et al.
US 8,476,510 B28,476,510 B2 7/2013 Swager et al.
US 8,557,440 B28,557,440 B2 10/2013 Yu et al.
US 8,685,569 B28,685,569 B2 4/2014 Oguni et al.
US 8,685,570 B28,685,570 B2 4/2014 Miwa et al.
US 8,709,654 B28,709,654 B2 4/2014 Takeuchi et al.
US 8,753,532 B28,753,532 B2 6/2014 Levasseur et al.
US 8,808,918 B28,808,918 B2 8/2014 Jung et al.
US 8,877,377 B28,877,377 B2 11/2014 Hosoya
US 8,877,381 B28,877,381 B2 11/2014 Yasuda et al.
US 8,883,351 B28,883,351 B2 11/2014 Todoriki et al.
US 8,906,547 B28,906,547 B2 12/2014 Taniguchi et al.
US 8,927,148 B28,927,148 B2 1/2015 Kawakami
US 8,945,770 B28,945,770 B2 2/2015 Koo et al.
US 8,945,772 B28,945,772 B2 2/2015 Kawakami et al.
US 9,225,003 B29,225,003 B2 12/2015 Yukawa
US 9,227,850 B29,227,850 B2 1/2016 Ooishi
US 9,293,236 B29,293,236 B2 3/2016 Kawakami et al.
US 9,362,557 B29,362,557 B2 6/2016 Watanabe et al.
US 9,391,322 B29,391,322 B2 7/2016 Liu et al.
US 9,478,796 B29,478,796 B2 10/2016 Li et al.
US 9,505,631 B29,505,631 B2 11/2016 Masukuni et al.
US 9,515,313 B29,515,313 B2 12/2016 Umeyama et al.
US 9,601,764 B29,601,764 B2 3/2017 Kawakami et al.
US 9,666,326 B29,666,326 B2 5/2017 Kawakami et al.
US 9,698,420 B29,698,420 B2 7/2017 Ishizaki et al.
US 9,786,903 B29,786,903 B2 10/2017 Ryu et al.
US 9,899,664 B29,899,664 B2 2/2018 Yamaki et al.
US 9,923,244 B29,923,244 B2 3/2018 Takanashi et al.
US 10,128,495 B210,128,495 B2 11/2018 Satow et al.
US 10,243,215 B210,243,215 B2 3/2019 Shitaba et al.
US 10,361,432 B210,361,432 B2 7/2019 Takaichi et al.
US 10,938,035 B210,938,035 B2 3/2021 Yamakaji et al.
US 2001/0010807 A12001/0010807 A1 8/2001 Matsubara
US 2002/0102459 A12002/0102459 A1 8/2002 Hosoya et al.
US 2002/0110736 A12002/0110736 A1 8/2002 Kweon et al.
US 2002/0164156 A12002/0164156 A1 11/2002 Bilbrey
US 2002/0195591 A12002/0195591 A1 12/2002 Ravet et al.
US 2003/0104279 A12003/0104279 A1 6/2003 Miyazaki et al.
US 2003/0134186 A12003/0134186 A1 7/2003 Shizuki
US 2004/0229123 A12004/0229123 A1 11/2004 Takahashi et al.
US 2004/0229124 A12004/0229124 A1 11/2004 Miyamoto et al.
US 2004/0234857 A12004/0234857 A1 11/2004 Shiozaki et al.
US 2005/0019662 A12005/0019662 A1 1/2005 Suhara et al.
US 2006/0051671 A12006/0051671 A1 3/2006 Thackeray et al.
US 2006/0051673 A12006/0051673 A1 3/2006 Johnson et al.
US 2006/0121352 A12006/0121352 A1 6/2006 Kejha et al.
US 2006/0188780 A12006/0188780 A1 8/2006 Fujii et al.
US 2006/0275664 A12006/0275664 A1 12/2006 Ohzuku et al.
US 2006/0286459 A12006/0286459 A1 12/2006 Zhao et al.
US 2007/0026315 A12007/0026315 A1 2/2007 Lampe-Onnerud et al.
US 2007/0099086 A12007/0099086 A1 5/2007 Kang et al.
US 2007/0117014 A12007/0117014 A1 5/2007 Saito et al.
US 2007/0122712 A12007/0122712 A1 5/2007 Kang et al.
US 2007/0148546 A12007/0148546 A1 6/2007 Shimizu et al.
US 2007/0160906 A12007/0160906 A1 7/2007 Tooyama et al.
US 2007/0212609 A12007/0212609 A1 9/2007 Iwami
US 2007/0224506 A12007/0224506 A1 9/2007 Ooyama et al.
US 2008/0131780 A12008/0131780 A1 6/2008 Kawasato et al.
US 2008/0166637 A12008/0166637 A1 7/2008 Inagaki et al.
US 2008/0241693 A12008/0241693 A1 10/2008 Fukuchi et al.
US 2009/0011335 A12009/0011335 A1 1/2009 Takeda et al.
US 2009/0087731 A12009/0087731 A1 4/2009 Fukui et al.
US 2009/0104532 A12009/0104532 A1 4/2009 Hosoya
US 2009/0123813 A12009/0123813 A1 5/2009 Chiang et al.
US 2009/0123842 A12009/0123842 A1 5/2009 Thackeray et al.
US 2009/0220862 A12009/0220862 A1 9/2009 Toyama et al.
US 2010/0019194 A12010/0019194 A1 1/2010 Fujiwara et al.
US 2010/0035147 A12010/0035147 A1 2/2010 Kotato et al.
US 2010/0129714 A12010/0129714 A1 5/2010 Toyama et al.
US 2010/0129715 A12010/0129715 A1 5/2010 Saito et al.
US 2010/0143784 A12010/0143784 A1 6/2010 Johnson et al.
US 2010/0143799 A12010/0143799 A1 6/2010 Park
US 2010/0159330 A12010/0159330 A1 6/2010 Sugiura et al.
US 2010/0178464 A12010/0178464 A1 * 7/2010 Choi...................... B82Y 30/00examiner
US 2010/0216024 A12010/0216024 A1 8/2010 Kanno et al.
US 2010/0233542 A12010/0233542 A1 9/2010 Endo et al.
US 2010/0247986 A12010/0247986 A1 9/2010 Toyama et al.
US 2010/0248033 A12010/0248033 A1 9/2010 Kumar et al.
US 2011/0033749 A12011/0033749 A1 2/2011 Uchida et al.
US 2011/0059367 A12011/0059367 A1 3/2011 Morita et al.
US 2011/0076564 A12011/0076564 A1 3/2011 Yu et al.
US 2011/0200879 A12011/0200879 A1 8/2011 Saito et al.
US 2011/0229757 A12011/0229757 A1 9/2011 Kawakami et al.
US 2011/0256437 A12011/0256437 A1 10/2011 Katsuki. et al.
US 2011/0269023 A12011/0269023 A1 11/2011 Kawakami et al.
US 2011/0297876 A12011/0297876 A1 12/2011 Masukuni et al.
US 2011/0300441 A12011/0300441 A1 12/2011 Kawakami
US 2012/0034516 A12012/0034516 A1 2/2012 Koo et al.
US 2012/0045692 A12012/0045692 A1 2/2012 Takemura et al.
US 2012/0064406 A12012/0064406 A1 3/2012 Sato et al.
US 2012/0064409 A12012/0064409 A1 3/2012 Zhamu et al.
US 2012/0088151 A12012/0088151 A1 4/2012 Yamazaki et al.
US 2012/0088156 A12012/0088156 A1 4/2012 Nomoto et al.
US 2012/0118149 A12012/0118149 A1 5/2012 Dabrowski et al.
US 2012/0177974 A12012/0177974 A1 7/2012 Nakajima et al.
US 2012/0244430 A12012/0244430 A1 9/2012 Yamazaki et al.
US 2012/0256337 A12012/0256337 A1 10/2012 Yokoyama et al.
US 2012/0258358 A12012/0258358 A1 10/2012 Yura et al.
US 2012/0258365 A12012/0258365 A1 10/2012 Yokoyama et al.
US 2012/0258369 A12012/0258369 A1 10/2012 Yokoyama et al.
US 2012/0261622 A12012/0261622 A1 10/2012 Honma
US 2012/0295163 A12012/0295163 A1 11/2012 Yanagita et al.
US 2012/0308891 A12012/0308891 A1 12/2012 Todoriki et al.
US 2012/0315544 A12012/0315544 A1 12/2012 Yasuda et al.
US 2012/0328951 A12012/0328951 A1 12/2012 Hirohashi et al.
US 2012/0328956 A12012/0328956 A1 12/2012 Oguni et al.
US 2012/0330044 A12012/0330044 A1 * 12/2012 Hou....................... B82Y 30/00examiner
US 2013/0017435 A12013/0017435 A1 1/2013 Sato et al.
US 2013/0040193 A12013/0040193 A1 2/2013 Tsuchida et al.
US 2013/0045418 A12013/0045418 A1 2/2013 Oguni et al.
US 2013/0052547 A12013/0052547 A1 2/2013 Ogino et al.
US 2013/0065120 A12013/0065120 A1 3/2013 Miwa et al.
US 2013/0078516 A12013/0078516 A1 3/2013 Taniguchi et al.
US 2013/0084384 A12013/0084384 A1 4/2013 Yamakaji
US 2013/0130103 A12013/0130103 A1 5/2013 Kim et al.
US 2013/0134051 A12013/0134051 A1 5/2013 Takahashi et al.
US 2013/0156683 A12013/0156683 A1 6/2013 Holzapfel et al.
US 2013/0156942 A12013/0156942 A1 6/2013 Yamakaji et al.
US 2013/0157034 A12013/0157034 A1 6/2013 Choi et al.
US 2013/0164619 A12013/0164619 A1 6/2013 Yamakaji et al.
US 2013/0177806 A12013/0177806 A1 7/2013 Caldwell et al.
US 2013/0183579 A12013/0183579 A1 7/2013 Kim et al.
US 2013/0189585 A12013/0189585 A1 7/2013 Kang et al.
US 2013/0190449 A12013/0190449 A1 7/2013 Kinloch et al.
US 2013/0202953 A12013/0202953 A1 8/2013 Sharma et al.
US 2013/0212879 A12013/0212879 A1 8/2013 Ogino
US 2013/0266858 A12013/0266858 A1 10/2013 Inoue et al.
US 2013/0266859 A12013/0266859 A1 10/2013 Todoriki et al.
US 2013/0313471 A12013/0313471 A1 11/2013 Endo et al.
US 2013/0316237 A12013/0316237 A1 11/2013 Miki
US 2013/0337320 A12013/0337320 A1 12/2013 Yukawa
US 2014/0004412 A12014/0004412 A1 1/2014 Ogino
US 2014/0023920 A12014/0023920 A1 1/2014 Yamazaki et al.
US 2014/0079995 A12014/0079995 A1 3/2014 Wakada
US 2014/0099554 A12014/0099554 A1 4/2014 Inoue et al.
US 2014/0127567 A12014/0127567 A1 5/2014 Kuriki et al.
US 2014/0127568 A12014/0127568 A1 * 5/2014 Kawakami.......... H01M 4/1393examiner
US 2014/0131633 A12014/0131633 A1 5/2014 Ito et al.
US 2014/0162132 A12014/0162132 A1 6/2014 Ishii et al.
US 2014/0166946 A12014/0166946 A1 6/2014 Miwa et al.
US 2014/0184172 A12014/0184172 A1 7/2014 Momo et al.
US 2014/0234700 A12014/0234700 A1 8/2014 Moriwaka et al.
US 2014/0275323 A12014/0275323 A1 9/2014 Thibodeau et al.
US 2014/0295068 A12014/0295068 A1 10/2014 Nanba et al.
US 2014/0315083 A12014/0315083 A1 * 10/2014 Liu....................... H01M 4/622examiner
US 2014/0332715 A12014/0332715 A1 11/2014 Kawakami et al.
US 2014/0370184 A12014/0370184 A1 12/2014 Takemura. et al.
US 2015/0014581 A12015/0014581 A1 1/2015 Kawakami et al.
US 2015/0014605 A12015/0014605 A1 1/2015 Kawakami et al.
US 2015/0064565 A12015/0064565 A1 3/2015 Todoriki et al.
US 2015/0093648 A12015/0093648 A1 4/2015 Son et al.
US 2015/0099178 A12015/0099178 A1 4/2015 Kawakami et al.
US 2015/0099179 A12015/0099179 A1 4/2015 Ikenuma et al.
US 2015/0123050 A12015/0123050 A1 5/2015 Yamazaki et al.
US 2015/0155556 A12015/0155556 A1 6/2015 Kawakami et al.
US 2015/0166348 A12015/0166348 A1 6/2015 Ikenuma et al.
US 2015/0262762 A12015/0262762 A1 9/2015 Ikenuma et al.
US 2015/0325855 A12015/0325855 A1 11/2015 Kawakami et al.
US 2015/0333320 A12015/0333320 A1 11/2015 Tamaki et al.
US 2015/0333324 A12015/0333324 A1 11/2015 Umeyama et al.
US 2015/0357641 A12015/0357641 A1 12/2015 Sugie et al.
US 2015/0380737 A12015/0380737 A1 12/2015 Kawasato et al.
US 2016/0006032 A12016/0006032 A1 1/2016 Paulsen et al.
US 2016/0028080 A12016/0028080 A1 1/2016 Sugiura
US 2016/0046771 A12016/0046771 A1 2/2016 Thibodeau et al.
US 2016/0064726 A12016/0064726 A1 3/2016 Ikenuma et al.
US 2016/0087315 A12016/0087315 A1 3/2016 Oyama
US 2016/0118646 A12016/0118646 A1 4/2016 Ikenuma
US 2016/0118658 A12016/0118658 A1 4/2016 Kawakami et al.
US 2016/0156030 A12016/0156030 A1 6/2016 Sun et al.
US 2016/0164089 A12016/0164089 A1 6/2016 Kawakami et al.
US 2016/0276658 A12016/0276658 A1 9/2016 Choi et al.
US 2016/0285102 A12016/0285102 A1 9/2016 Shitaba et al.
US 2016/0329533 A12016/0329533 A1 11/2016 Tajima
US 2016/0349905 A12016/0349905 A1 12/2016 Momma et al.
US 2016/0380271 A12016/0380271 A1 12/2016 Ochiai et al.
US 2017/0005364 A12017/0005364 A1 1/2017 Yamazaki et al.
US 2017/0040594 A12017/0040594 A1 2/2017 Yamaki et al.
US 2017/0062819 A12017/0062819 A1 3/2017 Ikenuma
US 2017/0069907 A12017/0069907 A1 3/2017 Zhu et al.
US 2017/0117589 A12017/0117589 A1 4/2017 Tajima et al.
US 2017/0187035 A12017/0187035 A1 6/2017 Yanagihara et al.
US 2017/0207444 A12017/0207444 A1 7/2017 Yanagihara et al.
US 2017/0256817 A12017/0256817 A1 9/2017 Kadoma et al.
US 2017/0309910 A12017/0309910 A1 10/2017 Jo et al.
US 2018/0013130 A12018/0013130 A1 1/2018 Ochiai et al.
US 2018/0019462 A12018/0019462 A1 1/2018 Kadoma et al.
US 2018/0040888 A12018/0040888 A1 2/2018 Park et al.
US 2018/0040897 A12018/0040897 A1 2/2018 Park et al.
US 2018/0102536 A12018/0102536 A1 4/2018 Kawakami et al.
US 2018/0108944 A12018/0108944 A1 4/2018 Yamakaji
US 2018/0145317 A12018/0145317 A1 5/2018 Momma et al.
US 2018/0145368 A12018/0145368 A1 5/2018 Ochiai et al.
US 2018/0254477 A12018/0254477 A1 9/2018 Horikawa et al.
US 2018/0331365 A12018/0331365 A1 * 11/2018 Joo..................... H01M 4/0404examiner
US 2018/0366729 A12018/0366729 A1 12/2018 Yanagita et al.
US 2020/0144601 A12020/0144601 A1 5/2020 Takahashi et al.
US 2020/0152961 A12020/0152961 A1 5/2020 Momma et al.
US 2020/0176770 A12020/0176770 A1 6/2020 Takahashi et al.
US 2021/0175507 A12021/0175507 A1 6/2021 Yamakaji et al.
CN 102694201 ACN 102694201 A 9/2012
CN 102569775 BCN 102569775 B 1/2017
Cited non-patent literature · 74
Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Bat- teries. Joshi.T et al., “Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Bat- teries”, J. Electrochem. SOC. (Journal of the Electrochemical Society), 2014, vol. 161, No. 12, pp. A1915-A1921.
High-energy cathode material for long-life and safe lithium batteries. Sun.Y et al., “High-energy cathode material for long-life and safe lithium batteries”, Nature Materials, Mar. 22, 2009, vol. 8, pp. 320-324.
Li2MnO3-stabilized LiMO2(M=Mn, Ni, Co) electrodes for lithium-ion batteries. Thackeray.M et al., “Li2MnO3-stabilized LiMO2(M=Mn, Ni, Co) electrodes for lithium-ion batteries”, J. Mater. Chem. (Journal of Materials Chemistry), 2007, vol. 17, pp. 3112-3125.
Magnetic properties of the chemically delithiated LixMn2O4 with 0.07 ≤x≤1. Mukalk et al., “Magnetic properties of the chemically delithiated LixMn2O4 with 0.07 ≤x≤1”, Journal of Solid State Chemistry, May 1, 2011, vol. 184, No. 5, pp. 1096-1104.
Antiferromagnetic ordering in Li2MnO3 single crys- tals with a two-dimensional honeycomb lattice. Lee.S et al., “Antiferromagnetic ordering in Li2MnO3 single crys- tals with a two-dimensional honeycomb lattice”, Journal of Physics: Condensed Matter, Nov. 14, 2012, vol. 24, No. 45, pp. 456004-1- 456004-9.
The Chemistry of Graphene Oxide. Dreyer.D et al., “The Chemistry of Graphene Oxide”, Chemical Society Reviews, Nov. 3, 2009, vol. 39, No. 1, pp. 228-240.
EELS analysis of cation valence states and oxygen vacancies in magnetic oxides. Wang.Z et al., “EELS analysis of cation valence states and oxygen vacancies in magnetic oxides”, Micron, Oct. 1, 2000, vol. 31, No. 5, pp. 571-580, Elsevier.
Oxidation state and chemical shift investigation in transition metal oxides by EELS. Tan.H et al., “Oxidation state and chemical shift investigation in transition metal oxides by EELS”, Ultramicroscopy, May 1, 2012, vol. 116, pp. 24-33, Elsevier.
Thermogravimetry and X-Ray Diffraction Study of the Thermal Decomposition Processes in xLi2CO3—MnCO3 Mixtures. Berbenni.V et al., “Thermogravimetry and X-Ray Diffraction Study of the Thermal Decomposition Processes in xLi2CO3—MnCO3 Mixtures”, Journal of Analytical and Applied Pyrolysis, 2002, vol. 62, pp. 45-62.
Lithium-manganese oxide electrodes with layered- spinel composite structures xLi2MnO3 v (1-x)Li1+yMn2- yO4(0<x<1,0≤y≤0.33) for lithium batteries. Johnson.C et al., “Lithium-manganese oxide electrodes with layered- spinel composite structures xLi2MnO3 v (1-x)Li1+yMn2- yO4(0<x<1,0≤y≤0.33) for lithium batteries”, Electrochemistry Com- munications, May 1, 2005, vol. 7, No. 5, pp. 528-536, Elsevier.
Growth modes in two-dimensional heteroepitaxy on an elasticsubstrate. Katsuno.H et al., “Growth modes in two-dimensional heteroepitaxy on an elasticsubstrate”, J. Cryst. Growth (Journal of Crystal Growth), Feb. 15, 2005, vol. 275, No. 1-2, pp. e263-e288, Elsevier.
Characterization of MgO-coated-LiCoO2 par- ticles by analytical transmission electron microscopy. Taguchi.N et al., “Characterization of MgO-coated-LiCoO2 par- ticles by analytical transmission electron microscopy”, Journal of Power Sources, 2016, vol. 328, pp. 161-166, Elsevier.
Structural Studies on the Effects of ZrO2 Coating on LiCoO2 during Cycling Using In Situ X-Ray Diffraction Tech- nique. Chung.K et al., “Structural Studies on the Effects of ZrO2 Coating on LiCoO2 during Cycling Using In Situ X-Ray Diffraction Tech- nique”, J. Electrochem. Soc. (Journal of the Electrochemical Soci- ety), 2006, vol. 153, No. 11, pp. A2152-A2157.
Electrochemical and In Situ Synchrotron XRD Studies on Al2O3-Coated LiCoO2 Cathode Material. Liu.L et al., “Electrochemical and In Situ Synchrotron XRD Studies on Al2O3-Coated LiCoO2 Cathode Material”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2004, vol. 151, No. 9, pp. A1344-A1351.
LICoO2 Degradation Behavior in the High-Voltage Phase Transition Region and Improved Reversibility with surface Coating. Yano.A et al., “LICoO2 Degradation Behavior in the High-Voltage Phase Transition Region and Improved Reversibility with surface Coating”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2017, vol. 164, No. 1, pp. A6116-A6122.
Staging PhaseTransitions in LixCoO2. Chen.Z et al., “Staging PhaseTransitions in LixCoO2”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2002, vol. 149, No. 12, pp. A1604-A1609.
The spinel and cubic rocksalt solid-solutions in the Li—Mn—Ni oxide pseudo-ternary system. McCalla.E et al., “The spinel and cubic rocksalt solid-solutions in the Li—Mn—Ni oxide pseudo-ternary system”, Solid State Ionics, May 2, 2013, vol. 242, pp. 1-9, Elsevier.
Characterization of Spinel LixCo204-Coated LiCo02 Prepared with Post-Thermal Treatment as a Cathode Material for Lithium ion Batteries. Shim.J et al., “Characterization of Spinel LixCo204-Coated LiCo02 Prepared with Post-Thermal Treatment as a Cathode Material for Lithium ion Batteries”, Chem. Mater. (Chemistry of Materials), Apr. 10, 2015, vol. 27, No. 9, pp. 3273-3279.
Correlation of lithium ion distribution and X-ray absorption near-edge structure in O3- and O2-lithium cobalt oxides from first-principle calculation. Okumura.T et al., “Correlation of lithium ion distribution and X-ray absorption near-edge structure in O3- and O2-lithium cobalt oxides from first-principle calculation”, Journal of Materials Chemistry, 2012, vol. 22, pp. 17340-17348.
Electronic phase diagram of the layered cobalt oxide system LixCoO2 (0.0≤x≤1.0). Motohashi.T et al., “Electronic phase diagram of the layered cobalt oxide system LixCoO2 (0.0≤x≤1.0)”, Phys. Rev. B (Physical Review. B), Oct. 9, 2009, vol. 80, No. 16, pp. 165114-1-155114-9.
Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide TEM Investigation. Gabrisch.H et al., “Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide TEM Investigation”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2004, vol. 151, No. 6, pp. A891-A897.
Khedr.A et al., “Synthesis, Structure, and Electrochemistry of Sm-Modified LiMn2O4 Cathode Materials for Lithium-Ion Batter-
ies”, J. Electron. Mater.(Journal of Electronic Materials), Apr. 23, 2013, vol. 42, No. 6, pp. 1275-1281.
Fluoride Model Systems: II, The Binary Systems CaF2—BeF2, MgF2—BeF2, and LiF—MgF2. Counts.W et al., “Fluoride Model Systems: II, The Binary Systems CaF2—BeF2, MgF2—BeF2, and LiF—MgF2”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), 1953, vol. 36, No. 1, pp. 12-17.
Synthesis of Mg and Mn Doped LiCoO2 and Effects on High Voltage Cycling. Liu.A et al., “Synthesis of Mg and Mn Doped LiCoO2 and Effects on High Voltage Cycling”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Jun. 2, 2017, vol. 164, No. 7, pp. A1655- A1664.
Electronic Conductivity of LICoO2 and Its Enhancement by Magnesium Doping. Tukamoto.H et al., “Electronic Conductivity of LICoO2 and Its Enhancement by Magnesium Doping”, J. Electrochem. Soc. (Jour- nal of the Electrochemical Society), Sep. 1, 1997, vol. 144, No. 9, pp. 3164-3168.
Solid-State Redox Reactions of LiCoO2 (R-3m) for 4 Volt Secondary Lithium Cells. Ohzuku.T et al., “Solid-State Redox Reactions of LiCoO2 (R-3m) for 4 Volt Secondary Lithium Cells”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Nov. 1, 1994, vol. 141, No. 11, pp. 2972-2977.
CoO2, The End Member of the LixCoO2 Solid Solution. Amatucci.G et al., “CoO2, The End Member of the LixCoO2 Solid Solution”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Mar. 1, 1996, vol. 143, No. 3, pp. 1114-1123.
Structural and electrochemical characterizations of surface-modified LiCoO2 cathode materials for Li-ion batteries. Wang.Z et al., “Structural and electrochemical characterizations of surface-modified LiCoO2 cathode materials for Li-ion batteries”, Solid State Ionics, Jun. 2, 2002, vol. 148, No. 3-4, pp. 335-342, Elsevier.
Synthesis and Electrochemical Performance of High Voltage Cycling LiM0.05Co0.95O2 as Cathode Material for Lithium Rechargeable Cells. Zou.M et al., “Synthesis and Electrochemical Performance of High Voltage Cycling LiM0.05Co0.95O2 as Cathode Material for Lithium Rechargeable Cells”, Electrochemical and Solid-State Letters, 2004, vol. 7, No. 7, pp. A176-A179.
Improving the cycling stability of LiCoO2 at 4.5 V through co-modification by Mg doping and zirconium oxyfluoride coating. Wang.Z et al., “Improving the cycling stability of LiCoO2 at 4.5 V through co-modification by Mg doping and zirconium oxyfluoride coating”, Ceramics Internationa, 2015, vol. 41, No. 1, pp. 469-474.
High Performance LiCoO2 Cathode Materials at 60° C. for Lithium Secondary Batteries Prepared by the Facile Nanoscale Dry-Coating Method. Cho.Y et al., “High Performance LiCoO2 Cathode Materials at 60° C. for Lithium Secondary Batteries Prepared by the Facile Nanoscale Dry-Coating Method”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), 2010, vol. 157, No. 5, pp. A617-A624.
Mg doping and zirconium oxyfluoride coating co-modification to enhance the high-voltage performance of LiCoO2 for lithium ion battery. Wang.Z et al., “Mg doping and zirconium oxyfluoride coating co-modification to enhance the high-voltage performance of LiCoO2 for lithium ion battery”, Journal of Alloys and Compounds, Feb. 5, 2015, vol. 621, pp. 212-219.
Effect of Mg doping and MgO-surface modi- fication on the cycling stability of LiCoO2 electrodes.. Mladenov.M et al., “Effect of Mg doping and MgO-surface modi- fication on the cycling stability of LiCoO2 electrodes.”, Electro- chemistry Communications, Aug. 1, 2001, vol. 3, No. 8, pp. 410-416.
Effects of metal oxide coatings on the thermal stability and electrical performance of LiCoCO2 in a Li-ion cell. Kweon.H et al., “Effects of metal oxide coatings on the thermal stability and electrical performance of LiCoCO2 in a Li-ion cell”, Journal of Power Sources, Feb. 16, 2004, vol. 126, pp. 156-162, Elsevier.
Effects of MgO Coating on the Structural and Electrochemical Characteristics of LiCoO2 as Cathode Materials for Lithium Ion Battery. Shim.J et al., “Effects of MgO Coating on the Structural and Electrochemical Characteristics of LiCoO2 as Cathode Materials for Lithium Ion Battery”, Chem. Mater. (Chemistry of Materials), Mar. 24, 2014, vol. 26, No. 8, pp. 2537-2543.
Improvement of electrochemical stability of LiCoO2 cathode by a nano-crystalline coating. Zhao.H et al., “Improvement of electrochemical stability of LiCoO2 cathode by a nano-crystalline coating”, Journal of Power Sources, May 20, 2004, vol. 132, pp. 195-200, Elsevier.
Effects of surface modification by MgO on interfacial reactions of lithium cobalt oxide thin film electrode. Iriyama.Y et al., “Effects of surface modification by MgO on interfacial reactions of lithium cobalt oxide thin film electrode”, Journal of Power Sources, Oct. 5, 2004, vol. 137, pp. 111-116, Elsevier.
Origin of surface Coating Effect for MgO on LiCoO2 to Improve the Interfacial Reaction between Electrode and Electrolyte. Orikasa.Y et al., “Origin of surface Coating Effect for MgO on LiCoO2 to Improve the Interfacial Reaction between Electrode and Electrolyte”, Adv. Mater.Interfaces (Advanced Materials Inter- faces), Aug. 28, 2014, vol. 1, No. 9, pp. 1400195-1-1400195-8.
Stabilization of the Electronic Structure at the Cathode/Electrolyte Interface via MgO Ultra-thin Layer during Lithium-ions Insertion/Extraction. Yamamoto.K et al., “Stabilization of the Electronic Structure at the Cathode/Electrolyte Interface via MgO Ultra-thin Layer during Lithium-ions Insertion/Extraction”, Electrochemistry, Oct. 5, 2014, vol. 82, No. 10, pp. 891-896.
Synergistic effects of coating and doping for lithium ion battery cathode materials: synthesis and characterization of lithium titanate-coated LiCoO2 with Mg doping. Shim.J et al., “Synergistic effects of coating and doping for lithium ion battery cathode materials: synthesis and characterization of lithium titanate-coated LiCoO2 with Mg doping”, Electrochimica Acta, Dec. 20, 2015, vol. 186, pp. 201-208, Elesevier.
in situ Total-Reflection Fluorescence X-Ray Absorption Spectroscopic Study on Stability at LiFePO4/Electro- lyte Interface. Yamamoto.K et al., “in situ Total-Reflection Fluorescence X-Ray Absorption Spectroscopic Study on Stability at LiFePO4/Electro- lyte Interface”, 224th ECS Meeting Abstract, Oct. 27, 2013, p. 923.
Electrochemical Evaluation and Structural Charac- terization of Commercial LiCoO2 Surfaces Modified with MgO for Lithium-Ion Batteries. Wang.Z et al., “Electrochemical Evaluation and Structural Charac- terization of Commercial LiCoO2 Surfaces Modified with MgO for Lithium-Ion Batteries”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), Mar. 4, 2002, vol. 149, No. 4, pp. A466-A471.
Phase Transition of Bare and Coated LixCoO2 (x=0.4 and 0.24) at 300° C.. Lee.Y et al., “Phase Transition of Bare and Coated LixCoO2 (x=0.4 and 0.24) at 300° C.”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), Jul. 28, 2005, vol. 152, No. 9, pp. A1824- A1827.
Impact of active material surface area on thermal stability of LiCoO2 cathode. Geder.J et al., “Impact of active material surface area on thermal stability of LiCoO2 cathode”, Journal of Power Sources, Jul. 1, 2014, vol. 257, pp. 286-292, Elsevier.
Effect of LiF on Hot-Pressing of MgO. Benecke.M et al., “Effect of LiF on Hot-Pressing of MgO”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), Jul. 1, 1967, vol. 50, No. 7, pp. 365-368.
Densification Mechanisms in Hot-Pressing of Mag- nesia with a Fugitive Liquid. Hart.P et al., “Densification Mechanisms in Hot-Pressing of Mag- nesia with a Fugitive Liquid”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), Feb. 1, 1970, vol. 53, No. 2, pp. 83-86.
New developments in the Inorganic Crystal Struc- ture Database (ICSD): Accessibility in support of materials research and design.. Belsky.A et al., “New developments in the Inorganic Crystal Struc- ture Database (ICSD): Accessibility in support of materials research and design.”, Acta. Cryst (Acta Crystallographica Section B), Jun. 1, 2002, vol. B58, No. 3, pp. 364-369.
SPES, 6Li MAS NMR, and Ni3+ EPR evidence for the formation of Co2+-containing spinel phases in LiCoO2 cycled electrode materials. Alcantara.R et al., “SPES, 6Li MAS NMR, and Ni3+ EPR evidence for the formation of Co2+-containing spinel phases in LiCoO2 cycled electrode materials”, Journal of Electroanalytical Chemistry, Aug. 28, 1998, vol. 454, No. 1-2, pp. 173-181.
Enhanced cycling stability of Li[Li 0.2Mn0.54Ni0. 13Co0.13]O2 by surface modification of MgO with melting impreg- nation method. Shi.S et al., “Enhanced cycling stability of Li[Li 0.2Mn0.54Ni0. 13Co0.13]O2 by surface modification of MgO with melting impreg- nation method”, Electrochimica Acta, Nov. 1, 2012, vol. 88, pp. 671-679.
Preparation and Characterization of LiCoO2 Thin Films by Laser Ablation Deposition. Antaya.M et al., “Preparation and Characterization of LiCoO2 Thin Films by Laser Ablation Deposition”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Mar. 1, 1993, vol. 140, No. 3, pp. 575-578. Koyama. Y et al., “Co K-edge XANES of LiCoO2 and CoO2 with a variety of structures by supercell density functional calculations with a core hole”, Phys. Rev. B (Physical Review. B), Feb. 27, 2012, vol. 85, No. 7, pp. 075129-1-075129-7.
XPS Investigation of the Electrolyte Induced Stabilization of LiCoO2 and “AlPO4. Quinlan.R et al., “XPS Investigation of the Electrolyte Induced Stabilization of LiCoO2 and “AlPO4”-Coated LiCoO2 Composite Electrodes”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Dec. 3, 2015, vol. 163, No. 2, pp. A300-A308.
Comparison of Al2O3- and AlPO4-coated LiCoO2 cathode materials for a Li-ion cell. Cho.J et al., “Comparison of Al2O3- and AlPO4-coated LiCoO2 cathode materials for a Li-ion cell”, Journal of Power Sources, 2005, vol. 146, pp. 58-64, Elsevier.
Electrochemical Characterizations of Commercial LiCoO2 Powders with surface Modified by Li3PO4 Nanoparticles. Jin.Y et al., “Electrochemical Characterizations of Commercial LiCoO2 Powders with surface Modified by Li3PO4 Nanoparticles”, Electrochemical and Solid-State Letters, Apr. 3, 2006, vol. 9, No. 6, pp. A273-A276.
Modification of LiCoO2 by surface Coating with MgO/TiO2/SiO2 for High-Performance Lithium-Ion Battery. Hong.W et al., “Modification of LiCoO2 by surface Coating with MgO/TiO2/SiO2 for High-Performance Lithium-Ion Battery”, Elec- trochemical and Solid-State Letters, Dec. 20, 2005, vol. 9, No. 2, pp. A82-A85.
M3(PO4)2-Nanoparticle-Coated LiCoO2 vs LiCo0. 96M0.04O2(M=Mg and Zn) on Electrochemical and Storage Char- acteristics. Eom.J et al., “M3(PO4)2-Nanoparticle-Coated LiCoO2 vs LiCo0. 96M0.04O2(M=Mg and Zn) on Electrochemical and Storage Char- acteristics”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Jan. 8, 2008, vol. 155, No. 3, pp. A201-A205.
Suppression of Cobalt Dissolution from the LiCoO2 Cathodes with Various Metal-Oxide Coatings. Kim.Y et al., “Suppression of Cobalt Dissolution from the LiCoO2 Cathodes with Various Metal-Oxide Coatings”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2003, vol. 150, No. 12, pp. A1723-A1725.
Effect of calcination temperature on the electro- chemical behavior of ZnO-coated LiCoO2 cathode. Fang.T et al., “Effect of calcination temperature on the electro- chemical behavior of ZnO-coated LiCoO2 cathode”, Surface & Coatings Technology, Apr. 19, 2006, vol. 201, No. 3-4, pp. 1886-1893, Elsevier.
Novel surface Modification Technique to Improve Electrochemical Performance of LiCoO2 at High Voltage. Park.S et al., “Novel surface Modification Technique to Improve Electrochemical Performance of LiCoO2 at High Voltage”, Elec- trochemical and Solid-State Letters, Apr. 21, 2005, vol. 8, No. 6, pp. A299-A302.
An effective method to reduce residual lithium com- pounds on Ni-rich Li[Ni0.6Co0.2Mn0.2]O2 active material using a phosphoric acid derived Li3PO4 nanolayer. Jo.C et al., “An effective method to reduce residual lithium com- pounds on Ni-rich Li[Ni0.6Co0.2Mn0.2]O2 active material using a phosphoric acid derived Li3PO4 nanolayer”, Nano Research, Dec. 4, 2014, vol. 8, No. 5, pp. 1464-1479, Springer.
Mechanisms of LiCoO2 Cathode Degradation by Reaction with HF and Protection by Thin Oxide Coatings. Tebbe.J et al., “Mechanisms of LiCoO2 Cathode Degradation by Reaction with HF and Protection by Thin Oxide Coatings”, ACS Applied Materials & Interfaces, Oct. 12, 2015, vol. 7, No. 43, pp. 24265-24278.
Review on Synthesis, Characterizations, and Electrochemical Properties of Cathode Materials for Lithium Ion Batteries. Bensalah.N et al., “Review on Synthesis, Characterizations, and Electrochemical Properties of Cathode Materials for Lithium Ion Batteries”, Journal of Material Science & Engineering, 2016, vol. 5, No. 4, pp. 1000258-1-1000258-21.
Recent progress on lithium-ion batteries with high electrochemical performance. Lu.Y et al., “Recent progress on lithium-ion batteries with high electrochemical performance”, Science China Chemistry, Feb. 25, 2019, vol. 62, No. 5, pp. 533-548. Xiao.B, “Surface Modifification of Electrode Materials for Lithium- Ion Batteries”, Graduate Program in Mechanical and Materials Engineering, 2006, pp. 1-235.
Investigation of the surface degradation of LiCoO2 particles in the cathode materials of Li-ion batteries using FIB-TOF-SIMS. Ohnishi.M et al., “Investigation of the surface degradation of LiCoO2 particles in the cathode materials of Li-ion batteries using FIB-TOF-SIMS”, Journal of surface Analysis, 2013, vol. 20, No. 2, pp. 99-110.
Impact of Lithium-Ion Ordering on surface Elec- tronic States of LixCoO2. Iwaya.K et al., “Impact of Lithium-Ion Ordering on surface Elec- tronic States of LixCoO2”, Phys. Rev. Lett. (Physical Review Letters), Sep. 20, 2013, vol. 111, No. 12, pp. 126104-1-126104-5.
Synthesis of High-Voltage (4.5 V) Cycling Doped LiCoO2 for Use in Lithium Rechargeable Cells. Zou.M et al., “Synthesis of High-Voltage (4.5 V) Cycling Doped LiCoO2 for Use in Lithium Rechargeable Cells”, Chem. Mater. (Chemistry of Materials), Dec. 16, 2003, vol. 15, No. 25, pp. 4699-4702.
Study of Cathode Materials for Lithium-Ion Batteries: Recent Progress and New Challenges. Schipper.F et al., “Study of Cathode Materials for Lithium-Ion Batteries: Recent Progress and New Challenges”, Inorganics, Apr. 28, 2017, vol. 5, No. 2, pp. 1-29.
Phase Transitions and High-Voltage Electrochemical Behavior of LiCoO2 Thin Films Grown by Pulsed Laser Deposi- tion. Xia.H et al., “Phase Transitions and High-Voltage Electrochemical Behavior of LiCoO2 Thin Films Grown by Pulsed Laser Deposi- tion”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2007, vol. 154, No. 4, pp. A337-A342.
Role of AlF3 Coating on LiCoO2 Particles during Cycling to Cutoff Voltage above 4.5 V. Sun.Y et al., “Role of AlF3 Coating on LiCoO2 Particles during Cycling to Cutoff Voltage above 4.5 V”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2009, vol. 156, No. 12, pp. A1005-A1010.
Electrochemical properties of LiNi1/3Co1/3Mn1/3O2 cathode material modified by coating withAl2O3 nanoparticles. Araki.K et al., “Electrochemical properties of LiNi1/3Co1/3Mn1/3O2 cathode material modified by coating withAl2O3 nanoparticles”, Journal of Power Sources, 2014, vol. 269, pp. 236-243.
Capacity fading behavior of Ni-rich layered cathode materials in Li-ion full cells. Kim.H et al., “Capacity fading behavior of Ni-rich layered cathode materials in Li-ion full cells”, Journal of Electroanalytical Chem- istry, 2016, vol. 782, pp. 168-173.
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries. Lin.F et al., “Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries”, Nature Communications, Mar. 27, 2014, vol. 5, pp. 3529-1-3529-9.
Surface Structure and High-Voltage Charge/Discharge Characteristics of Al-Oxide Coated LiNi1/3Co1/3Mn1/3O2 Cathodes. Yano.A et al., “Surface Structure and High-Voltage Charge/Discharge Characteristics of Al-Oxide Coated LiNi1/3Co1/3Mn1/3O2 Cathodes”, J. Electrochem. Soc. (Journal of the Electrochemi- cal Society), 2015, vol. 162, No. 2, pp. A3137-A3144.
Surface Structure and High-Voltage Charging/Discharging Performance of Low-Content Zr-Oxide-Coated LiNi1/3Co1/3Mn1/3O2. Yano.A et al., “Surface Structure and High-Voltage Charging/Discharging Performance of Low-Content Zr-Oxide-Coated LiNi1/3Co1/3Mn1/3O2”, J. Electrochem. Soc. (Journal of the Electro- chemical Society), 2016, vol. 163, No. 2, pp. A75-A82. Exhibit 1032 of IPR2023-01016, portions of JP-2015-201432A and Full translation. Exhibit 1028 of IPR2023-01349, Full translation of JP-2015- 201432A. Appendix C of EPR 90/019,447, portions of JP-2015-201432A and Full translation. Exhibit 1041 of EPR 90/019,535, JP-2015-201432A and Full trans- lation. Appendix LL of EPR 90/019,447, portions of JP-2012-074366A and Full translation.
US 5,910,382 A5,910,382 A 6/1999 Goodenough et al.
US 6,085,015 A6,085,015 A 7/2000 Armand et al.
US 6,218,050 B16,218,050 B1 4/2001 Yoon et al.
US 6,346,348 B16,346,348 B1 2/2002 Nakajima et al.
US 6,458,487 B16,458,487 B1 10/2002 Takeuchi et al.
US 6,514,640 B16,514,640 B1 2/2003 Armand et al.
US 6,582,814 B26,582,814 B2 6/2003 Swiler et al.
US 6,680,143 B26,680,143 B2 1/2004 Thackeray et al.
US 6,737,195 B26,737,195 B2 5/2004 Kweon et al.
US 6,753,111 B26,753,111 B2 6/2004 Kweon et al.
US 6,846,592 B26,846,592 B2 1/2005 Kweon et al.
US 6,919,144 B26,919,144 B2 7/2005 Miyazaki et al.
US 6,974,601 B26,974,601 B2 12/2005 Kweon et al.
US 6,984,469 B26,984,469 B2 1/2006 Kweon et al.
US 7,018,741 B27,018,741 B2 3/2006 Suhara et al.
US 7,138,209 B27,138,209 B2 11/2006 Kweon et al.
US 7,294,435 B27,294,435 B2 11/2007 Miyamoto et al.
US 7,303,840 B27,303,840 B2 12/2007 Thackeray et al.
US 7,309,546 B27,309,546 B2 12/2007 Kweon et al.
US 7,368,071 B27,368,071 B2 5/2008 Dahn et al.
US 7,393,476 B27,393,476 B2 7/2008 Shiozaki et al.
US 7,635,536 B27,635,536 B2 12/2009 Johnson et al.
US 7,709,148 B27,709,148 B2 5/2010 Kawasato et al.
US 7,709,151 B27,709,151 B2 5/2010 Inoue et al.
US 7,736,807 B27,736,807 B2 6/2010 Hasegawa et al.
US 7,790,308 B27,790,308 B2 9/2010 Johnson et al.
US 7,892,679 B27,892,679 B2 2/2011 Shimizu et al.
US 7,927,506 B27,927,506 B2 4/2011 Park
US 7,935,270 B27,935,270 B2 5/2011 Park
US 8,003,256 B28,003,256 B2 8/2011 Ohishi
US 8,007,941 B28,007,941 B2 8/2011 Kweon et al.
US 8,034,486 B28,034,486 B2 10/2011 Kweon et al.
US 8,080,340 B28,080,340 B2 12/2011 Thackeray et al.
US 8,236,449 B28,236,449 B2 8/2012 Nakura
US 8,470,477 B28,470,477 B2 6/2013 Miwa et al.
US 8,476,510 B28,476,510 B2 7/2013 Swager et al.
US 8,557,440 B28,557,440 B2 10/2013 Yu et al.
US 8,685,569 B28,685,569 B2 4/2014 Oguni et al.
US 8,685,570 B28,685,570 B2 4/2014 Miwa et al.
US 8,709,654 B28,709,654 B2 4/2014 Takeuchi et al.
US 8,753,532 B28,753,532 B2 6/2014 Levasseur et al.
US 8,808,918 B28,808,918 B2 8/2014 Jung et al.
US 8,877,377 B28,877,377 B2 11/2014 Hosoya
US 8,877,381 B28,877,381 B2 11/2014 Yasuda et al.
US 8,883,351 B28,883,351 B2 11/2014 Todoriki et al.
US 8,906,547 B28,906,547 B2 12/2014 Taniguchi et al.
US 8,927,148 B28,927,148 B2 1/2015 Kawakami
US 8,945,770 B28,945,770 B2 2/2015 Koo et al.
US 8,945,772 B28,945,772 B2 2/2015 Kawakami et al.
US 9,225,003 B29,225,003 B2 12/2015 Yukawa
US 9,227,850 B29,227,850 B2 1/2016 Ooishi
US 9,293,236 B29,293,236 B2 3/2016 Kawakami et al.
US 9,362,557 B29,362,557 B2 6/2016 Watanabe et al.
US 9,391,322 B29,391,322 B2 7/2016 Liu et al.
US 9,478,796 B29,478,796 B2 10/2016 Li et al.
US 9,505,631 B29,505,631 B2 11/2016 Masukuni et al.
US 9,515,313 B29,515,313 B2 12/2016 Umeyama et al.
US 9,601,764 B29,601,764 B2 3/2017 Kawakami et al.
US 9,666,326 B29,666,326 B2 5/2017 Kawakami et al.
US 9,698,420 B29,698,420 B2 7/2017 Ishizaki et al.
US 9,786,903 B29,786,903 B2 10/2017 Ryu et al.
US 9,899,664 B29,899,664 B2 2/2018 Yamaki et al.
US 9,923,244 B29,923,244 B2 3/2018 Takanashi et al.
US 10,128,495 B210,128,495 B2 11/2018 Satow et al.
US 10,243,215 B210,243,215 B2 3/2019 Shitaba et al.
US 10,361,432 B210,361,432 B2 7/2019 Takaichi et al.
US 10,938,035 B210,938,035 B2 3/2021 Yamakaji et al.
US 2001/0010807 A12001/0010807 A1 8/2001 Matsubara
US 2002/0102459 A12002/0102459 A1 8/2002 Hosoya et al.
US 2002/0110736 A12002/0110736 A1 8/2002 Kweon et al.
US 2002/0164156 A12002/0164156 A1 11/2002 Bilbrey
US 2002/0195591 A12002/0195591 A1 12/2002 Ravet et al.
US 2003/0104279 A12003/0104279 A1 6/2003 Miyazaki et al.
US 2003/0134186 A12003/0134186 A1 7/2003 Shizuki
US 2004/0229123 A12004/0229123 A1 11/2004 Takahashi et al.
US 2004/0229124 A12004/0229124 A1 11/2004 Miyamoto et al.
US 2004/0234857 A12004/0234857 A1 11/2004 Shiozaki et al.
US 2005/0019662 A12005/0019662 A1 1/2005 Suhara et al.
US 2006/0051671 A12006/0051671 A1 3/2006 Thackeray et al.
US 2006/0051673 A12006/0051673 A1 3/2006 Johnson et al.
US 2006/0121352 A12006/0121352 A1 6/2006 Kejha et al.
US 2006/0188780 A12006/0188780 A1 8/2006 Fujii et al.
US 2006/0275664 A12006/0275664 A1 12/2006 Ohzuku et al.
US 2006/0286459 A12006/0286459 A1 12/2006 Zhao et al.
US 2007/0026315 A12007/0026315 A1 2/2007 Lampe-Onnerud et al.
US 2007/0099086 A12007/0099086 A1 5/2007 Kang et al.
US 2007/0117014 A12007/0117014 A1 5/2007 Saito et al.
US 2007/0122712 A12007/0122712 A1 5/2007 Kang et al.
US 2007/0148546 A12007/0148546 A1 6/2007 Shimizu et al.
US 2007/0160906 A12007/0160906 A1 7/2007 Tooyama et al.
US 2007/0212609 A12007/0212609 A1 9/2007 Iwami
US 2007/0224506 A12007/0224506 A1 9/2007 Ooyama et al.
US 2008/0131780 A12008/0131780 A1 6/2008 Kawasato et al.
US 2008/0166637 A12008/0166637 A1 7/2008 Inagaki et al.
US 2008/0241693 A12008/0241693 A1 10/2008 Fukuchi et al.
US 2009/0011335 A12009/0011335 A1 1/2009 Takeda et al.
US 2009/0087731 A12009/0087731 A1 4/2009 Fukui et al.
US 2009/0104532 A12009/0104532 A1 4/2009 Hosoya
US 2009/0123813 A12009/0123813 A1 5/2009 Chiang et al.
US 2009/0123842 A12009/0123842 A1 5/2009 Thackeray et al.
US 2009/0220862 A12009/0220862 A1 9/2009 Toyama et al.
US 2010/0019194 A12010/0019194 A1 1/2010 Fujiwara et al.
US 2010/0035147 A12010/0035147 A1 2/2010 Kotato et al.
US 2010/0129714 A12010/0129714 A1 5/2010 Toyama et al.
US 2010/0129715 A12010/0129715 A1 5/2010 Saito et al.
US 2010/0143784 A12010/0143784 A1 6/2010 Johnson et al.
US 2010/0143799 A12010/0143799 A1 6/2010 Park
US 2010/0159330 A12010/0159330 A1 6/2010 Sugiura et al.
US 2010/0178464 A12010/0178464 A1 * 7/2010 Choi...................... B82Y 30/00examiner
US 2010/0216024 A12010/0216024 A1 8/2010 Kanno et al.
US 2010/0233542 A12010/0233542 A1 9/2010 Endo et al.
US 2010/0247986 A12010/0247986 A1 9/2010 Toyama et al.
US 2010/0248033 A12010/0248033 A1 9/2010 Kumar et al.
US 2011/0033749 A12011/0033749 A1 2/2011 Uchida et al.
US 2011/0059367 A12011/0059367 A1 3/2011 Morita et al.
US 2011/0076564 A12011/0076564 A1 3/2011 Yu et al.
US 2011/0200879 A12011/0200879 A1 8/2011 Saito et al.
US 2011/0229757 A12011/0229757 A1 9/2011 Kawakami et al.
US 2011/0256437 A12011/0256437 A1 10/2011 Katsuki. et al.
US 2011/0269023 A12011/0269023 A1 11/2011 Kawakami et al.
US 2011/0297876 A12011/0297876 A1 12/2011 Masukuni et al.
US 2011/0300441 A12011/0300441 A1 12/2011 Kawakami
US 2012/0034516 A12012/0034516 A1 2/2012 Koo et al.
US 2012/0045692 A12012/0045692 A1 2/2012 Takemura et al.
US 2012/0064406 A12012/0064406 A1 3/2012 Sato et al.
US 2012/0064409 A12012/0064409 A1 3/2012 Zhamu et al.
US 2012/0088151 A12012/0088151 A1 4/2012 Yamazaki et al.
US 2012/0088156 A12012/0088156 A1 4/2012 Nomoto et al.
US 2012/0118149 A12012/0118149 A1 5/2012 Dabrowski et al.
US 2012/0177974 A12012/0177974 A1 7/2012 Nakajima et al.
US 2012/0244430 A12012/0244430 A1 9/2012 Yamazaki et al.
US 2012/0256337 A12012/0256337 A1 10/2012 Yokoyama et al.
US 2012/0258358 A12012/0258358 A1 10/2012 Yura et al.
US 2012/0258365 A12012/0258365 A1 10/2012 Yokoyama et al.
US 2012/0258369 A12012/0258369 A1 10/2012 Yokoyama et al.
US 2012/0261622 A12012/0261622 A1 10/2012 Honma
US 2012/0295163 A12012/0295163 A1 11/2012 Yanagita et al.
US 2012/0308891 A12012/0308891 A1 12/2012 Todoriki et al.
US 2012/0315544 A12012/0315544 A1 12/2012 Yasuda et al.
US 2012/0328951 A12012/0328951 A1 12/2012 Hirohashi et al.
US 2012/0328956 A12012/0328956 A1 12/2012 Oguni et al.
US 2012/0330044 A12012/0330044 A1 * 12/2012 Hou....................... B82Y 30/00examiner
US 2013/0017435 A12013/0017435 A1 1/2013 Sato et al.
US 2013/0040193 A12013/0040193 A1 2/2013 Tsuchida et al.
US 2013/0045418 A12013/0045418 A1 2/2013 Oguni et al.
US 2013/0052547 A12013/0052547 A1 2/2013 Ogino et al.
US 2013/0065120 A12013/0065120 A1 3/2013 Miwa et al.
US 2013/0078516 A12013/0078516 A1 3/2013 Taniguchi et al.
US 2013/0084384 A12013/0084384 A1 4/2013 Yamakaji
US 2013/0130103 A12013/0130103 A1 5/2013 Kim et al.
US 2013/0134051 A12013/0134051 A1 5/2013 Takahashi et al.
US 2013/0156683 A12013/0156683 A1 6/2013 Holzapfel et al.
US 2013/0156942 A12013/0156942 A1 6/2013 Yamakaji et al.
US 2013/0157034 A12013/0157034 A1 6/2013 Choi et al.
US 2013/0164619 A12013/0164619 A1 6/2013 Yamakaji et al.
US 2013/0177806 A12013/0177806 A1 7/2013 Caldwell et al.
US 2013/0183579 A12013/0183579 A1 7/2013 Kim et al.
US 2013/0189585 A12013/0189585 A1 7/2013 Kang et al.
US 2013/0190449 A12013/0190449 A1 7/2013 Kinloch et al.
US 2013/0202953 A12013/0202953 A1 8/2013 Sharma et al.
US 2013/0212879 A12013/0212879 A1 8/2013 Ogino
US 2013/0266858 A12013/0266858 A1 10/2013 Inoue et al.
US 2013/0266859 A12013/0266859 A1 10/2013 Todoriki et al.
US 2013/0313471 A12013/0313471 A1 11/2013 Endo et al.
US 2013/0316237 A12013/0316237 A1 11/2013 Miki
US 2013/0337320 A12013/0337320 A1 12/2013 Yukawa
US 2014/0004412 A12014/0004412 A1 1/2014 Ogino
US 2014/0023920 A12014/0023920 A1 1/2014 Yamazaki et al.
US 2014/0079995 A12014/0079995 A1 3/2014 Wakada
US 2014/0099554 A12014/0099554 A1 4/2014 Inoue et al.
US 2014/0127567 A12014/0127567 A1 5/2014 Kuriki et al.
US 2014/0127568 A12014/0127568 A1 * 5/2014 Kawakami.......... H01M 4/1393examiner
US 2014/0131633 A12014/0131633 A1 5/2014 Ito et al.
US 2014/0162132 A12014/0162132 A1 6/2014 Ishii et al.
US 2014/0166946 A12014/0166946 A1 6/2014 Miwa et al.
US 2014/0184172 A12014/0184172 A1 7/2014 Momo et al.
US 2014/0234700 A12014/0234700 A1 8/2014 Moriwaka et al.
US 2014/0275323 A12014/0275323 A1 9/2014 Thibodeau et al.
US 2014/0295068 A12014/0295068 A1 10/2014 Nanba et al.
US 2014/0315083 A12014/0315083 A1 * 10/2014 Liu....................... H01M 4/622examiner
US 2014/0332715 A12014/0332715 A1 11/2014 Kawakami et al.
US 2014/0370184 A12014/0370184 A1 12/2014 Takemura. et al.
US 2015/0014581 A12015/0014581 A1 1/2015 Kawakami et al.
US 2015/0014605 A12015/0014605 A1 1/2015 Kawakami et al.
US 2015/0064565 A12015/0064565 A1 3/2015 Todoriki et al.
US 2015/0093648 A12015/0093648 A1 4/2015 Son et al.
US 2015/0099178 A12015/0099178 A1 4/2015 Kawakami et al.
US 2015/0099179 A12015/0099179 A1 4/2015 Ikenuma et al.
US 2015/0123050 A12015/0123050 A1 5/2015 Yamazaki et al.
US 2015/0155556 A12015/0155556 A1 6/2015 Kawakami et al.
US 2015/0166348 A12015/0166348 A1 6/2015 Ikenuma et al.
US 2015/0262762 A12015/0262762 A1 9/2015 Ikenuma et al.
US 2015/0325855 A12015/0325855 A1 11/2015 Kawakami et al.
US 2015/0333320 A12015/0333320 A1 11/2015 Tamaki et al.
US 2015/0333324 A12015/0333324 A1 11/2015 Umeyama et al.
US 2015/0357641 A12015/0357641 A1 12/2015 Sugie et al.
US 2015/0380737 A12015/0380737 A1 12/2015 Kawasato et al.
US 2016/0006032 A12016/0006032 A1 1/2016 Paulsen et al.
US 2016/0028080 A12016/0028080 A1 1/2016 Sugiura
US 2016/0046771 A12016/0046771 A1 2/2016 Thibodeau et al.
US 2016/0064726 A12016/0064726 A1 3/2016 Ikenuma et al.
US 2016/0087315 A12016/0087315 A1 3/2016 Oyama
US 2016/0118646 A12016/0118646 A1 4/2016 Ikenuma
US 2016/0118658 A12016/0118658 A1 4/2016 Kawakami et al.
US 2016/0156030 A12016/0156030 A1 6/2016 Sun et al.
US 2016/0164089 A12016/0164089 A1 6/2016 Kawakami et al.
US 2016/0276658 A12016/0276658 A1 9/2016 Choi et al.
US 2016/0285102 A12016/0285102 A1 9/2016 Shitaba et al.
US 2016/0329533 A12016/0329533 A1 11/2016 Tajima
US 2016/0349905 A12016/0349905 A1 12/2016 Momma et al.
US 2016/0380271 A12016/0380271 A1 12/2016 Ochiai et al.
US 2017/0005364 A12017/0005364 A1 1/2017 Yamazaki et al.
US 2017/0040594 A12017/0040594 A1 2/2017 Yamaki et al.
US 2017/0062819 A12017/0062819 A1 3/2017 Ikenuma
US 2017/0069907 A12017/0069907 A1 3/2017 Zhu et al.
US 2017/0117589 A12017/0117589 A1 4/2017 Tajima et al.
US 2017/0187035 A12017/0187035 A1 6/2017 Yanagihara et al.
US 2017/0207444 A12017/0207444 A1 7/2017 Yanagihara et al.
US 2017/0256817 A12017/0256817 A1 9/2017 Kadoma et al.
US 2017/0309910 A12017/0309910 A1 10/2017 Jo et al.
US 2018/0013130 A12018/0013130 A1 1/2018 Ochiai et al.
US 2018/0019462 A12018/0019462 A1 1/2018 Kadoma et al.
US 2018/0040888 A12018/0040888 A1 2/2018 Park et al.
US 2018/0040897 A12018/0040897 A1 2/2018 Park et al.
US 2018/0102536 A12018/0102536 A1 4/2018 Kawakami et al.
US 2018/0108944 A12018/0108944 A1 4/2018 Yamakaji
US 2018/0145317 A12018/0145317 A1 5/2018 Momma et al.
US 2018/0145368 A12018/0145368 A1 5/2018 Ochiai et al.
US 2018/0254477 A12018/0254477 A1 9/2018 Horikawa et al.
US 2018/0331365 A12018/0331365 A1 * 11/2018 Joo..................... H01M 4/0404examiner
US 2018/0366729 A12018/0366729 A1 12/2018 Yanagita et al.
US 2020/0144601 A12020/0144601 A1 5/2020 Takahashi et al.
US 2020/0152961 A12020/0152961 A1 5/2020 Momma et al.
US 2020/0176770 A12020/0176770 A1 6/2020 Takahashi et al.
US 2021/0175507 A12021/0175507 A1 6/2021 Yamakaji et al.
CN 102694201 ACN 102694201 A 9/2012
CN 102569775 BCN 102569775 B 1/2017
Cited non-patent literature · 74
Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Bat- teries. Joshi.T et al., “Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Bat- teries”, J. Electrochem. SOC. (Journal of the Electrochemical Society), 2014, vol. 161, No. 12, pp. A1915-A1921.
High-energy cathode material for long-life and safe lithium batteries. Sun.Y et al., “High-energy cathode material for long-life and safe lithium batteries”, Nature Materials, Mar. 22, 2009, vol. 8, pp. 320-324.
Li2MnO3-stabilized LiMO2(M=Mn, Ni, Co) electrodes for lithium-ion batteries. Thackeray.M et al., “Li2MnO3-stabilized LiMO2(M=Mn, Ni, Co) electrodes for lithium-ion batteries”, J. Mater. Chem. (Journal of Materials Chemistry), 2007, vol. 17, pp. 3112-3125.
Magnetic properties of the chemically delithiated LixMn2O4 with 0.07 ≤x≤1. Mukalk et al., “Magnetic properties of the chemically delithiated LixMn2O4 with 0.07 ≤x≤1”, Journal of Solid State Chemistry, May 1, 2011, vol. 184, No. 5, pp. 1096-1104.
Antiferromagnetic ordering in Li2MnO3 single crys- tals with a two-dimensional honeycomb lattice. Lee.S et al., “Antiferromagnetic ordering in Li2MnO3 single crys- tals with a two-dimensional honeycomb lattice”, Journal of Physics: Condensed Matter, Nov. 14, 2012, vol. 24, No. 45, pp. 456004-1- 456004-9.
The Chemistry of Graphene Oxide. Dreyer.D et al., “The Chemistry of Graphene Oxide”, Chemical Society Reviews, Nov. 3, 2009, vol. 39, No. 1, pp. 228-240.
EELS analysis of cation valence states and oxygen vacancies in magnetic oxides. Wang.Z et al., “EELS analysis of cation valence states and oxygen vacancies in magnetic oxides”, Micron, Oct. 1, 2000, vol. 31, No. 5, pp. 571-580, Elsevier.
Oxidation state and chemical shift investigation in transition metal oxides by EELS. Tan.H et al., “Oxidation state and chemical shift investigation in transition metal oxides by EELS”, Ultramicroscopy, May 1, 2012, vol. 116, pp. 24-33, Elsevier.
Thermogravimetry and X-Ray Diffraction Study of the Thermal Decomposition Processes in xLi2CO3—MnCO3 Mixtures. Berbenni.V et al., “Thermogravimetry and X-Ray Diffraction Study of the Thermal Decomposition Processes in xLi2CO3—MnCO3 Mixtures”, Journal of Analytical and Applied Pyrolysis, 2002, vol. 62, pp. 45-62.
Lithium-manganese oxide electrodes with layered- spinel composite structures xLi2MnO3 v (1-x)Li1+yMn2- yO4(0<x<1,0≤y≤0.33) for lithium batteries. Johnson.C et al., “Lithium-manganese oxide electrodes with layered- spinel composite structures xLi2MnO3 v (1-x)Li1+yMn2- yO4(0<x<1,0≤y≤0.33) for lithium batteries”, Electrochemistry Com- munications, May 1, 2005, vol. 7, No. 5, pp. 528-536, Elsevier.
Growth modes in two-dimensional heteroepitaxy on an elasticsubstrate. Katsuno.H et al., “Growth modes in two-dimensional heteroepitaxy on an elasticsubstrate”, J. Cryst. Growth (Journal of Crystal Growth), Feb. 15, 2005, vol. 275, No. 1-2, pp. e263-e288, Elsevier.
Characterization of MgO-coated-LiCoO2 par- ticles by analytical transmission electron microscopy. Taguchi.N et al., “Characterization of MgO-coated-LiCoO2 par- ticles by analytical transmission electron microscopy”, Journal of Power Sources, 2016, vol. 328, pp. 161-166, Elsevier.
Structural Studies on the Effects of ZrO2 Coating on LiCoO2 during Cycling Using In Situ X-Ray Diffraction Tech- nique. Chung.K et al., “Structural Studies on the Effects of ZrO2 Coating on LiCoO2 during Cycling Using In Situ X-Ray Diffraction Tech- nique”, J. Electrochem. Soc. (Journal of the Electrochemical Soci- ety), 2006, vol. 153, No. 11, pp. A2152-A2157.
Electrochemical and In Situ Synchrotron XRD Studies on Al2O3-Coated LiCoO2 Cathode Material. Liu.L et al., “Electrochemical and In Situ Synchrotron XRD Studies on Al2O3-Coated LiCoO2 Cathode Material”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2004, vol. 151, No. 9, pp. A1344-A1351.
LICoO2 Degradation Behavior in the High-Voltage Phase Transition Region and Improved Reversibility with surface Coating. Yano.A et al., “LICoO2 Degradation Behavior in the High-Voltage Phase Transition Region and Improved Reversibility with surface Coating”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2017, vol. 164, No. 1, pp. A6116-A6122.
Staging PhaseTransitions in LixCoO2. Chen.Z et al., “Staging PhaseTransitions in LixCoO2”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2002, vol. 149, No. 12, pp. A1604-A1609.
The spinel and cubic rocksalt solid-solutions in the Li—Mn—Ni oxide pseudo-ternary system. McCalla.E et al., “The spinel and cubic rocksalt solid-solutions in the Li—Mn—Ni oxide pseudo-ternary system”, Solid State Ionics, May 2, 2013, vol. 242, pp. 1-9, Elsevier.
Characterization of Spinel LixCo204-Coated LiCo02 Prepared with Post-Thermal Treatment as a Cathode Material for Lithium ion Batteries. Shim.J et al., “Characterization of Spinel LixCo204-Coated LiCo02 Prepared with Post-Thermal Treatment as a Cathode Material for Lithium ion Batteries”, Chem. Mater. (Chemistry of Materials), Apr. 10, 2015, vol. 27, No. 9, pp. 3273-3279.
Correlation of lithium ion distribution and X-ray absorption near-edge structure in O3- and O2-lithium cobalt oxides from first-principle calculation. Okumura.T et al., “Correlation of lithium ion distribution and X-ray absorption near-edge structure in O3- and O2-lithium cobalt oxides from first-principle calculation”, Journal of Materials Chemistry, 2012, vol. 22, pp. 17340-17348.
Electronic phase diagram of the layered cobalt oxide system LixCoO2 (0.0≤x≤1.0). Motohashi.T et al., “Electronic phase diagram of the layered cobalt oxide system LixCoO2 (0.0≤x≤1.0)”, Phys. Rev. B (Physical Review. B), Oct. 9, 2009, vol. 80, No. 16, pp. 165114-1-155114-9.
Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide TEM Investigation. Gabrisch.H et al., “Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide TEM Investigation”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2004, vol. 151, No. 6, pp. A891-A897.
Khedr.A et al., “Synthesis, Structure, and Electrochemistry of Sm-Modified LiMn2O4 Cathode Materials for Lithium-Ion Batter-
ies”, J. Electron. Mater.(Journal of Electronic Materials), Apr. 23, 2013, vol. 42, No. 6, pp. 1275-1281.
Fluoride Model Systems: II, The Binary Systems CaF2—BeF2, MgF2—BeF2, and LiF—MgF2. Counts.W et al., “Fluoride Model Systems: II, The Binary Systems CaF2—BeF2, MgF2—BeF2, and LiF—MgF2”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), 1953, vol. 36, No. 1, pp. 12-17.
Synthesis of Mg and Mn Doped LiCoO2 and Effects on High Voltage Cycling. Liu.A et al., “Synthesis of Mg and Mn Doped LiCoO2 and Effects on High Voltage Cycling”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Jun. 2, 2017, vol. 164, No. 7, pp. A1655- A1664.
Electronic Conductivity of LICoO2 and Its Enhancement by Magnesium Doping. Tukamoto.H et al., “Electronic Conductivity of LICoO2 and Its Enhancement by Magnesium Doping”, J. Electrochem. Soc. (Jour- nal of the Electrochemical Society), Sep. 1, 1997, vol. 144, No. 9, pp. 3164-3168.
Solid-State Redox Reactions of LiCoO2 (R-3m) for 4 Volt Secondary Lithium Cells. Ohzuku.T et al., “Solid-State Redox Reactions of LiCoO2 (R-3m) for 4 Volt Secondary Lithium Cells”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Nov. 1, 1994, vol. 141, No. 11, pp. 2972-2977.
CoO2, The End Member of the LixCoO2 Solid Solution. Amatucci.G et al., “CoO2, The End Member of the LixCoO2 Solid Solution”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Mar. 1, 1996, vol. 143, No. 3, pp. 1114-1123.
Structural and electrochemical characterizations of surface-modified LiCoO2 cathode materials for Li-ion batteries. Wang.Z et al., “Structural and electrochemical characterizations of surface-modified LiCoO2 cathode materials for Li-ion batteries”, Solid State Ionics, Jun. 2, 2002, vol. 148, No. 3-4, pp. 335-342, Elsevier.
Synthesis and Electrochemical Performance of High Voltage Cycling LiM0.05Co0.95O2 as Cathode Material for Lithium Rechargeable Cells. Zou.M et al., “Synthesis and Electrochemical Performance of High Voltage Cycling LiM0.05Co0.95O2 as Cathode Material for Lithium Rechargeable Cells”, Electrochemical and Solid-State Letters, 2004, vol. 7, No. 7, pp. A176-A179.
Improving the cycling stability of LiCoO2 at 4.5 V through co-modification by Mg doping and zirconium oxyfluoride coating. Wang.Z et al., “Improving the cycling stability of LiCoO2 at 4.5 V through co-modification by Mg doping and zirconium oxyfluoride coating”, Ceramics Internationa, 2015, vol. 41, No. 1, pp. 469-474.
High Performance LiCoO2 Cathode Materials at 60° C. for Lithium Secondary Batteries Prepared by the Facile Nanoscale Dry-Coating Method. Cho.Y et al., “High Performance LiCoO2 Cathode Materials at 60° C. for Lithium Secondary Batteries Prepared by the Facile Nanoscale Dry-Coating Method”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), 2010, vol. 157, No. 5, pp. A617-A624.
Mg doping and zirconium oxyfluoride coating co-modification to enhance the high-voltage performance of LiCoO2 for lithium ion battery. Wang.Z et al., “Mg doping and zirconium oxyfluoride coating co-modification to enhance the high-voltage performance of LiCoO2 for lithium ion battery”, Journal of Alloys and Compounds, Feb. 5, 2015, vol. 621, pp. 212-219.
Effect of Mg doping and MgO-surface modi- fication on the cycling stability of LiCoO2 electrodes.. Mladenov.M et al., “Effect of Mg doping and MgO-surface modi- fication on the cycling stability of LiCoO2 electrodes.”, Electro- chemistry Communications, Aug. 1, 2001, vol. 3, No. 8, pp. 410-416.
Effects of metal oxide coatings on the thermal stability and electrical performance of LiCoCO2 in a Li-ion cell. Kweon.H et al., “Effects of metal oxide coatings on the thermal stability and electrical performance of LiCoCO2 in a Li-ion cell”, Journal of Power Sources, Feb. 16, 2004, vol. 126, pp. 156-162, Elsevier.
Effects of MgO Coating on the Structural and Electrochemical Characteristics of LiCoO2 as Cathode Materials for Lithium Ion Battery. Shim.J et al., “Effects of MgO Coating on the Structural and Electrochemical Characteristics of LiCoO2 as Cathode Materials for Lithium Ion Battery”, Chem. Mater. (Chemistry of Materials), Mar. 24, 2014, vol. 26, No. 8, pp. 2537-2543.
Improvement of electrochemical stability of LiCoO2 cathode by a nano-crystalline coating. Zhao.H et al., “Improvement of electrochemical stability of LiCoO2 cathode by a nano-crystalline coating”, Journal of Power Sources, May 20, 2004, vol. 132, pp. 195-200, Elsevier.
Effects of surface modification by MgO on interfacial reactions of lithium cobalt oxide thin film electrode. Iriyama.Y et al., “Effects of surface modification by MgO on interfacial reactions of lithium cobalt oxide thin film electrode”, Journal of Power Sources, Oct. 5, 2004, vol. 137, pp. 111-116, Elsevier.
Origin of surface Coating Effect for MgO on LiCoO2 to Improve the Interfacial Reaction between Electrode and Electrolyte. Orikasa.Y et al., “Origin of surface Coating Effect for MgO on LiCoO2 to Improve the Interfacial Reaction between Electrode and Electrolyte”, Adv. Mater.Interfaces (Advanced Materials Inter- faces), Aug. 28, 2014, vol. 1, No. 9, pp. 1400195-1-1400195-8.
Stabilization of the Electronic Structure at the Cathode/Electrolyte Interface via MgO Ultra-thin Layer during Lithium-ions Insertion/Extraction. Yamamoto.K et al., “Stabilization of the Electronic Structure at the Cathode/Electrolyte Interface via MgO Ultra-thin Layer during Lithium-ions Insertion/Extraction”, Electrochemistry, Oct. 5, 2014, vol. 82, No. 10, pp. 891-896.
Synergistic effects of coating and doping for lithium ion battery cathode materials: synthesis and characterization of lithium titanate-coated LiCoO2 with Mg doping. Shim.J et al., “Synergistic effects of coating and doping for lithium ion battery cathode materials: synthesis and characterization of lithium titanate-coated LiCoO2 with Mg doping”, Electrochimica Acta, Dec. 20, 2015, vol. 186, pp. 201-208, Elesevier.
in situ Total-Reflection Fluorescence X-Ray Absorption Spectroscopic Study on Stability at LiFePO4/Electro- lyte Interface. Yamamoto.K et al., “in situ Total-Reflection Fluorescence X-Ray Absorption Spectroscopic Study on Stability at LiFePO4/Electro- lyte Interface”, 224th ECS Meeting Abstract, Oct. 27, 2013, p. 923.
Electrochemical Evaluation and Structural Charac- terization of Commercial LiCoO2 Surfaces Modified with MgO for Lithium-Ion Batteries. Wang.Z et al., “Electrochemical Evaluation and Structural Charac- terization of Commercial LiCoO2 Surfaces Modified with MgO for Lithium-Ion Batteries”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), Mar. 4, 2002, vol. 149, No. 4, pp. A466-A471.
Phase Transition of Bare and Coated LixCoO2 (x=0.4 and 0.24) at 300° C.. Lee.Y et al., “Phase Transition of Bare and Coated LixCoO2 (x=0.4 and 0.24) at 300° C.”, J. Electrochem. Soc. (Journal of the Elec- trochemical Society), Jul. 28, 2005, vol. 152, No. 9, pp. A1824- A1827.
Impact of active material surface area on thermal stability of LiCoO2 cathode. Geder.J et al., “Impact of active material surface area on thermal stability of LiCoO2 cathode”, Journal of Power Sources, Jul. 1, 2014, vol. 257, pp. 286-292, Elsevier.
Effect of LiF on Hot-Pressing of MgO. Benecke.M et al., “Effect of LiF on Hot-Pressing of MgO”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), Jul. 1, 1967, vol. 50, No. 7, pp. 365-368.
Densification Mechanisms in Hot-Pressing of Mag- nesia with a Fugitive Liquid. Hart.P et al., “Densification Mechanisms in Hot-Pressing of Mag- nesia with a Fugitive Liquid”, J. Am. Ceram. Soc. (Journal of the American Ceramic Society), Feb. 1, 1970, vol. 53, No. 2, pp. 83-86.
New developments in the Inorganic Crystal Struc- ture Database (ICSD): Accessibility in support of materials research and design.. Belsky.A et al., “New developments in the Inorganic Crystal Struc- ture Database (ICSD): Accessibility in support of materials research and design.”, Acta. Cryst (Acta Crystallographica Section B), Jun. 1, 2002, vol. B58, No. 3, pp. 364-369.
SPES, 6Li MAS NMR, and Ni3+ EPR evidence for the formation of Co2+-containing spinel phases in LiCoO2 cycled electrode materials. Alcantara.R et al., “SPES, 6Li MAS NMR, and Ni3+ EPR evidence for the formation of Co2+-containing spinel phases in LiCoO2 cycled electrode materials”, Journal of Electroanalytical Chemistry, Aug. 28, 1998, vol. 454, No. 1-2, pp. 173-181.
Enhanced cycling stability of Li[Li 0.2Mn0.54Ni0. 13Co0.13]O2 by surface modification of MgO with melting impreg- nation method. Shi.S et al., “Enhanced cycling stability of Li[Li 0.2Mn0.54Ni0. 13Co0.13]O2 by surface modification of MgO with melting impreg- nation method”, Electrochimica Acta, Nov. 1, 2012, vol. 88, pp. 671-679.
Preparation and Characterization of LiCoO2 Thin Films by Laser Ablation Deposition. Antaya.M et al., “Preparation and Characterization of LiCoO2 Thin Films by Laser Ablation Deposition”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Mar. 1, 1993, vol. 140, No. 3, pp. 575-578. Koyama. Y et al., “Co K-edge XANES of LiCoO2 and CoO2 with a variety of structures by supercell density functional calculations with a core hole”, Phys. Rev. B (Physical Review. B), Feb. 27, 2012, vol. 85, No. 7, pp. 075129-1-075129-7.
XPS Investigation of the Electrolyte Induced Stabilization of LiCoO2 and “AlPO4. Quinlan.R et al., “XPS Investigation of the Electrolyte Induced Stabilization of LiCoO2 and “AlPO4”-Coated LiCoO2 Composite Electrodes”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Dec. 3, 2015, vol. 163, No. 2, pp. A300-A308.
Comparison of Al2O3- and AlPO4-coated LiCoO2 cathode materials for a Li-ion cell. Cho.J et al., “Comparison of Al2O3- and AlPO4-coated LiCoO2 cathode materials for a Li-ion cell”, Journal of Power Sources, 2005, vol. 146, pp. 58-64, Elsevier.
Electrochemical Characterizations of Commercial LiCoO2 Powders with surface Modified by Li3PO4 Nanoparticles. Jin.Y et al., “Electrochemical Characterizations of Commercial LiCoO2 Powders with surface Modified by Li3PO4 Nanoparticles”, Electrochemical and Solid-State Letters, Apr. 3, 2006, vol. 9, No. 6, pp. A273-A276.
Modification of LiCoO2 by surface Coating with MgO/TiO2/SiO2 for High-Performance Lithium-Ion Battery. Hong.W et al., “Modification of LiCoO2 by surface Coating with MgO/TiO2/SiO2 for High-Performance Lithium-Ion Battery”, Elec- trochemical and Solid-State Letters, Dec. 20, 2005, vol. 9, No. 2, pp. A82-A85.
M3(PO4)2-Nanoparticle-Coated LiCoO2 vs LiCo0. 96M0.04O2(M=Mg and Zn) on Electrochemical and Storage Char- acteristics. Eom.J et al., “M3(PO4)2-Nanoparticle-Coated LiCoO2 vs LiCo0. 96M0.04O2(M=Mg and Zn) on Electrochemical and Storage Char- acteristics”, J. Electrochem. Soc. (Journal of the Electrochemical Society), Jan. 8, 2008, vol. 155, No. 3, pp. A201-A205.
Suppression of Cobalt Dissolution from the LiCoO2 Cathodes with Various Metal-Oxide Coatings. Kim.Y et al., “Suppression of Cobalt Dissolution from the LiCoO2 Cathodes with Various Metal-Oxide Coatings”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2003, vol. 150, No. 12, pp. A1723-A1725.
Effect of calcination temperature on the electro- chemical behavior of ZnO-coated LiCoO2 cathode. Fang.T et al., “Effect of calcination temperature on the electro- chemical behavior of ZnO-coated LiCoO2 cathode”, Surface & Coatings Technology, Apr. 19, 2006, vol. 201, No. 3-4, pp. 1886-1893, Elsevier.
Novel surface Modification Technique to Improve Electrochemical Performance of LiCoO2 at High Voltage. Park.S et al., “Novel surface Modification Technique to Improve Electrochemical Performance of LiCoO2 at High Voltage”, Elec- trochemical and Solid-State Letters, Apr. 21, 2005, vol. 8, No. 6, pp. A299-A302.
An effective method to reduce residual lithium com- pounds on Ni-rich Li[Ni0.6Co0.2Mn0.2]O2 active material using a phosphoric acid derived Li3PO4 nanolayer. Jo.C et al., “An effective method to reduce residual lithium com- pounds on Ni-rich Li[Ni0.6Co0.2Mn0.2]O2 active material using a phosphoric acid derived Li3PO4 nanolayer”, Nano Research, Dec. 4, 2014, vol. 8, No. 5, pp. 1464-1479, Springer.
Mechanisms of LiCoO2 Cathode Degradation by Reaction with HF and Protection by Thin Oxide Coatings. Tebbe.J et al., “Mechanisms of LiCoO2 Cathode Degradation by Reaction with HF and Protection by Thin Oxide Coatings”, ACS Applied Materials & Interfaces, Oct. 12, 2015, vol. 7, No. 43, pp. 24265-24278.
Review on Synthesis, Characterizations, and Electrochemical Properties of Cathode Materials for Lithium Ion Batteries. Bensalah.N et al., “Review on Synthesis, Characterizations, and Electrochemical Properties of Cathode Materials for Lithium Ion Batteries”, Journal of Material Science & Engineering, 2016, vol. 5, No. 4, pp. 1000258-1-1000258-21.
Recent progress on lithium-ion batteries with high electrochemical performance. Lu.Y et al., “Recent progress on lithium-ion batteries with high electrochemical performance”, Science China Chemistry, Feb. 25, 2019, vol. 62, No. 5, pp. 533-548. Xiao.B, “Surface Modifification of Electrode Materials for Lithium- Ion Batteries”, Graduate Program in Mechanical and Materials Engineering, 2006, pp. 1-235.
Investigation of the surface degradation of LiCoO2 particles in the cathode materials of Li-ion batteries using FIB-TOF-SIMS. Ohnishi.M et al., “Investigation of the surface degradation of LiCoO2 particles in the cathode materials of Li-ion batteries using FIB-TOF-SIMS”, Journal of surface Analysis, 2013, vol. 20, No. 2, pp. 99-110.
Impact of Lithium-Ion Ordering on surface Elec- tronic States of LixCoO2. Iwaya.K et al., “Impact of Lithium-Ion Ordering on surface Elec- tronic States of LixCoO2”, Phys. Rev. Lett. (Physical Review Letters), Sep. 20, 2013, vol. 111, No. 12, pp. 126104-1-126104-5.
Synthesis of High-Voltage (4.5 V) Cycling Doped LiCoO2 for Use in Lithium Rechargeable Cells. Zou.M et al., “Synthesis of High-Voltage (4.5 V) Cycling Doped LiCoO2 for Use in Lithium Rechargeable Cells”, Chem. Mater. (Chemistry of Materials), Dec. 16, 2003, vol. 15, No. 25, pp. 4699-4702.
Study of Cathode Materials for Lithium-Ion Batteries: Recent Progress and New Challenges. Schipper.F et al., “Study of Cathode Materials for Lithium-Ion Batteries: Recent Progress and New Challenges”, Inorganics, Apr. 28, 2017, vol. 5, No. 2, pp. 1-29.
Phase Transitions and High-Voltage Electrochemical Behavior of LiCoO2 Thin Films Grown by Pulsed Laser Deposi- tion. Xia.H et al., “Phase Transitions and High-Voltage Electrochemical Behavior of LiCoO2 Thin Films Grown by Pulsed Laser Deposi- tion”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2007, vol. 154, No. 4, pp. A337-A342.
Role of AlF3 Coating on LiCoO2 Particles during Cycling to Cutoff Voltage above 4.5 V. Sun.Y et al., “Role of AlF3 Coating on LiCoO2 Particles during Cycling to Cutoff Voltage above 4.5 V”, J. Electrochem. Soc. (Journal of the Electrochemical Society), 2009, vol. 156, No. 12, pp. A1005-A1010.
Electrochemical properties of LiNi1/3Co1/3Mn1/3O2 cathode material modified by coating withAl2O3 nanoparticles. Araki.K et al., “Electrochemical properties of LiNi1/3Co1/3Mn1/3O2 cathode material modified by coating withAl2O3 nanoparticles”, Journal of Power Sources, 2014, vol. 269, pp. 236-243.
Capacity fading behavior of Ni-rich layered cathode materials in Li-ion full cells. Kim.H et al., “Capacity fading behavior of Ni-rich layered cathode materials in Li-ion full cells”, Journal of Electroanalytical Chem- istry, 2016, vol. 782, pp. 168-173.
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries. Lin.F et al., “Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries”, Nature Communications, Mar. 27, 2014, vol. 5, pp. 3529-1-3529-9.
Surface Structure and High-Voltage Charge/Discharge Characteristics of Al-Oxide Coated LiNi1/3Co1/3Mn1/3O2 Cathodes. Yano.A et al., “Surface Structure and High-Voltage Charge/Discharge Characteristics of Al-Oxide Coated LiNi1/3Co1/3Mn1/3O2 Cathodes”, J. Electrochem. Soc. (Journal of the Electrochemi- cal Society), 2015, vol. 162, No. 2, pp. A3137-A3144.
Surface Structure and High-Voltage Charging/Discharging Performance of Low-Content Zr-Oxide-Coated LiNi1/3Co1/3Mn1/3O2. Yano.A et al., “Surface Structure and High-Voltage Charging/Discharging Performance of Low-Content Zr-Oxide-Coated LiNi1/3Co1/3Mn1/3O2”, J. Electrochem. Soc. (Journal of the Electro- chemical Society), 2016, vol. 163, No. 2, pp. A75-A82. Exhibit 1032 of IPR2023-01016, portions of JP-2015-201432A and Full translation. Exhibit 1028 of IPR2023-01349, Full translation of JP-2015- 201432A. Appendix C of EPR 90/019,447, portions of JP-2015-201432A and Full translation. Exhibit 1041 of EPR 90/019,535, JP-2015-201432A and Full trans- lation. Appendix LL of EPR 90/019,447, portions of JP-2012-074366A and Full translation.
