Method of Preparing of Natural Graphene Cellulose Blended Spunbond Nonwoven Fabric | Matter42 Literature
Patent
Atlas literature
Patent
US 10,190,242
Method of Preparing of Natural Graphene Cellulose Blended Spunbond Nonwoven Fabric
Wen-Tung CHOU
US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a block diagram showing the manufacturing process of the present invention.
FIG. 2
FIG. 2 is an electron microscope (TEM) image (100 X) of the graphene prepared by the process according to the present invention.
FIG. 3
FIG. 3 shows a chemical structure of N-methylmorpholine N-oxide (referred to as 10 NM M O) solvent, which is used in the present invention.
FIG. 4
FIG. 4 shows a chemical structure of wood pulp cellulose, which is used in the present invention.
FIG. 5
FIG. 5 is a schematic diagram showing the action of spunbonding natural graphene cellulose blended fabric of the present invention. 15
FIG. 6
FIG. 6 is a schematic diagram showing the manufacturing process of the present invention. Detailed Description of the Preferred Embodiments To further …
FIG. 25
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
A method of preparing natural graphene cellulose blended spunbond nonwoven fabric, which comprises the following steps: (a) combining a graphite powder with a solution comprising 1 to 10 wt. % of a first 5 compound selected from the group consisting of sulfuric acid (H 2 S O 4), hydrochloric acid (HCl), perchloric acid (HC l O 4), hydrogen iodide (HI), hydrofluoric acid (HF), and nitric acid (H NO 3), then stirring for 30 minutes in an ice bath environment; (b) adding a solution comprising 1 to 20 wt. % potassium permanganate (KMnO 4) to 10 the product of step (a), stirring for 1 to 2 hours, and adding distilled water, wherein the potassium permanganate solution is continuously added until none of the purple smoke generated by reacting with the potassium permanganate is formed from the distilled water; (c) adding a solution comprising 1 to 10 wt.% hydrogen peroxide (H 2 0 2) to the product 15 of step (b), wherein the hydrogen peroxide solution is added until no bubbles are formed and the mixture becomes dark green, then filtering the dark green solution into a cake; (d) rinsing the cake of step (c) with a solution comprising 5 wt.% hydrochloric acid (HCl) to remove sulfate ions, then washing the cake with distilled water; 20 (e) drying the cake of step (d) in an oven at 40 ° C for 2 hrs to obtain a dried solid graphite oxide; (f) adding distilled water to the dried solid graphite oxide of step (e), wherein the distilled water is added up to 200 m l s per 0.06 to 1.0 g of the dried solid graphite-21-oxide, then treating by ultrasonic vibration for 30 minutes to obtain a graphite oxide solution having a graphite oxide concentration of 0.03 wt. % to 0.5 wt. %; (g) adding a solution comprising 1 to 10 wt. % of a second compound selected from the group consisting of sodium borohydride (NaBH 4), potassium borohydride (KBH 4), 5 lithium aluminum hydride (LiA l H 4), and sodium citrate (C 6 H S Na 3 O 7) to the graphite oxide solution of step (f), then treating by ultrasonic vibration for 30 to 60 minutes, wherein in the resulting solution, the ratio of graphene oxide to the second compound is 1:1 to 1:5 by weight; (h) filtrating the product of step (g), washing the filtrate with water 3 to 5 times to 10 remove the second compound, then back-filtrating to obtain a graphene solution; (i) adding the graphene solution of step (h) to a slurry solution formed by mixing a pulp with N-methylmorpholine N-oxide (NMMO) and a stabilizer in an expansion dissolving tank, then mixing at 60 to 80 ° C, wherein the graphene solution of step (h) is added in a ratio of 0.11 to 5.0 wt. %, the pulp is selected from the group 15 consisting of wood pulp, cotton pulp, bamboo pulp and a mixture of cotton and bamboo pulp, the pulp comprises a-cellulose in an amount of 65 % or more with a polymerization degree of 500 to 1500; and the NMMO has a concentration of 50 % to 78 %; (j) removing water from the product of step (i) using a Thin Film Evaporator (TFE) 20 and heating at 80 to 130 ° C, wherein the water is removed to 5% to 13% within 5 minutes and the cellulose is dissolved to form a spinning dope, and the amount ratio of each component among the components comprised in the dope is: water (H 2 0) 5 % to 15 %, N-methylmorpholine N-oxide (N M MO) 70 % to 90 %, and -22-cellulose 5 % to 15 %; (k) Squeezing the spinning dope of step () from a spinning orifice by using a spunbond process to form a natural graphene cellulose blended filament strand, which comprises pressuring the spinning dope by a metering pump, filtering and 5 degassing by a continuous filter (CPF), transporting the spinning dope into a spinning tank, and stretching the spinning dope outward by air gap cooling through the spinning orifice, to form a natural graphene cellulose blended filament strand; and (1) feeding the natural graphene cellulose blended filament strand of step (k) into a 10 coagulation liquid, solidifying and regenerating the filament strand, stretching the filament strand under high pressure and high speed by an air stream drafting device, stacking the filament strand on a collection web to form a fibrous network structure, and washing, water needle punching, drying, oiling and coiling the fibrous network structure to form a natural graphene cellulose blended spunbond nonwoven fabric, 15 wherein the concentration of the coagulation liquid is between 2. 0% to 10.0 %, and after washing, the amount of residual N MM O solvent is less than 0.1 %.
The method of claim 1, further comprising a recycle process of N-methylmorpholine N-oxide (N M MO) released during the regeneration and washing stages of step (1), 10 which comprises the following recycle steps: A. filtering the NMMO released during the regeneration and washing stages of step (1) using a filter cartridge 1 to 20 m; B. injecting the N M MO obtained after the filtration of step A. into a flocculation tank, processing for about 1 to 2 hours using a f l locutant and other additives in an 15 adding amount of 1.5 to 10.0 mg/L; discharging impurities out through slits of a filter mesh; C. injecting NMMO obtained after the flocculation processing of step B. into an ion exchange system comprising an ion exchange resin having chargeability; D. filtering the product of step C. by using an ultra-filter and a reverse osmosis (RO) 20 filter; E. reducing the water content the product of step D. by distillation through the recirculation operation of a multieffect evaporation device, purifying it step by step until the concentration of the NMMO becomes 50.0 % to 78. 0%, then -24-discharging it to be used as a feed material; and F. filtering the product of step E. using an ultra-filter and reverse osmosis (RO) filter.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
Method of Preparing of Natural Graphene Cellulose Blended Spunbond Nonwoven Fabric
Wen-Tung CHOU
US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a block diagram showing the manufacturing process of the present invention.
FIG. 2
FIG. 2 is an electron microscope (TEM) image (100 X) of the graphene prepared by the process according to the present invention.
FIG. 3
FIG. 3 shows a chemical structure of N-methylmorpholine N-oxide (referred to as 10 NM M O) solvent, which is used in the present invention.
FIG. 4
FIG. 4 shows a chemical structure of wood pulp cellulose, which is used in the present invention.
FIG. 5
FIG. 5 is a schematic diagram showing the action of spunbonding natural graphene cellulose blended fabric of the present invention. 15
FIG. 6
FIG. 6 is a schematic diagram showing the manufacturing process of the present invention. Detailed Description of the Preferred Embodiments To further …
FIG. 25
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
A method of preparing natural graphene cellulose blended spunbond nonwoven fabric, which comprises the following steps: (a) combining a graphite powder with a solution comprising 1 to 10 wt. % of a first 5 compound selected from the group consisting of sulfuric acid (H 2 S O 4), hydrochloric acid (HCl), perchloric acid (HC l O 4), hydrogen iodide (HI), hydrofluoric acid (HF), and nitric acid (H NO 3), then stirring for 30 minutes in an ice bath environment; (b) adding a solution comprising 1 to 20 wt. % potassium permanganate (KMnO 4) to 10 the product of step (a), stirring for 1 to 2 hours, and adding distilled water, wherein the potassium permanganate solution is continuously added until none of the purple smoke generated by reacting with the potassium permanganate is formed from the distilled water; (c) adding a solution comprising 1 to 10 wt.% hydrogen peroxide (H 2 0 2) to the product 15 of step (b), wherein the hydrogen peroxide solution is added until no bubbles are formed and the mixture becomes dark green, then filtering the dark green solution into a cake; (d) rinsing the cake of step (c) with a solution comprising 5 wt.% hydrochloric acid (HCl) to remove sulfate ions, then washing the cake with distilled water; 20 (e) drying the cake of step (d) in an oven at 40 ° C for 2 hrs to obtain a dried solid graphite oxide; (f) adding distilled water to the dried solid graphite oxide of step (e), wherein the distilled water is added up to 200 m l s per 0.06 to 1.0 g of the dried solid graphite-21-oxide, then treating by ultrasonic vibration for 30 minutes to obtain a graphite oxide solution having a graphite oxide concentration of 0.03 wt. % to 0.5 wt. %; (g) adding a solution comprising 1 to 10 wt. % of a second compound selected from the group consisting of sodium borohydride (NaBH 4), potassium borohydride (KBH 4), 5 lithium aluminum hydride (LiA l H 4), and sodium citrate (C 6 H S Na 3 O 7) to the graphite oxide solution of step (f), then treating by ultrasonic vibration for 30 to 60 minutes, wherein in the resulting solution, the ratio of graphene oxide to the second compound is 1:1 to 1:5 by weight; (h) filtrating the product of step (g), washing the filtrate with water 3 to 5 times to 10 remove the second compound, then back-filtrating to obtain a graphene solution; (i) adding the graphene solution of step (h) to a slurry solution formed by mixing a pulp with N-methylmorpholine N-oxide (NMMO) and a stabilizer in an expansion dissolving tank, then mixing at 60 to 80 ° C, wherein the graphene solution of step (h) is added in a ratio of 0.11 to 5.0 wt. %, the pulp is selected from the group 15 consisting of wood pulp, cotton pulp, bamboo pulp and a mixture of cotton and bamboo pulp, the pulp comprises a-cellulose in an amount of 65 % or more with a polymerization degree of 500 to 1500; and the NMMO has a concentration of 50 % to 78 %; (j) removing water from the product of step (i) using a Thin Film Evaporator (TFE) 20 and heating at 80 to 130 ° C, wherein the water is removed to 5% to 13% within 5 minutes and the cellulose is dissolved to form a spinning dope, and the amount ratio of each component among the components comprised in the dope is: water (H 2 0) 5 % to 15 %, N-methylmorpholine N-oxide (N M MO) 70 % to 90 %, and -22-cellulose 5 % to 15 %; (k) Squeezing the spinning dope of step () from a spinning orifice by using a spunbond process to form a natural graphene cellulose blended filament strand, which comprises pressuring the spinning dope by a metering pump, filtering and 5 degassing by a continuous filter (CPF), transporting the spinning dope into a spinning tank, and stretching the spinning dope outward by air gap cooling through the spinning orifice, to form a natural graphene cellulose blended filament strand; and (1) feeding the natural graphene cellulose blended filament strand of step (k) into a 10 coagulation liquid, solidifying and regenerating the filament strand, stretching the filament strand under high pressure and high speed by an air stream drafting device, stacking the filament strand on a collection web to form a fibrous network structure, and washing, water needle punching, drying, oiling and coiling the fibrous network structure to form a natural graphene cellulose blended spunbond nonwoven fabric, 15 wherein the concentration of the coagulation liquid is between 2. 0% to 10.0 %, and after washing, the amount of residual N MM O solvent is less than 0.1 %.
The method of claim 1, further comprising a recycle process of N-methylmorpholine N-oxide (N M MO) released during the regeneration and washing stages of step (1), 10 which comprises the following recycle steps: A. filtering the NMMO released during the regeneration and washing stages of step (1) using a filter cartridge 1 to 20 m; B. injecting the N M MO obtained after the filtration of step A. into a flocculation tank, processing for about 1 to 2 hours using a f l locutant and other additives in an 15 adding amount of 1.5 to 10.0 mg/L; discharging impurities out through slits of a filter mesh; C. injecting NMMO obtained after the flocculation processing of step B. into an ion exchange system comprising an ion exchange resin having chargeability; D. filtering the product of step C. by using an ultra-filter and a reverse osmosis (RO) 20 filter; E. reducing the water content the product of step D. by distillation through the recirculation operation of a multieffect evaporation device, purifying it step by step until the concentration of the NMMO becomes 50.0 % to 78. 0%, then -24-discharging it to be used as a feed material; and F. filtering the product of step E. using an ultra-filter and reverse osmosis (RO) filter.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
Method of Preparing of Natural Graphene Cellulose Blended Spunbond Nonwoven Fabric
Wen-Tung CHOU
US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a block diagram showing the manufacturing process of the present invention.
FIG. 2
FIG. 2 is an electron microscope (TEM) image (100 X) of the graphene prepared by the process according to the present invention.
FIG. 3
FIG. 3 shows a chemical structure of N-methylmorpholine N-oxide (referred to as 10 NM M O) solvent, which is used in the present invention.
FIG. 4
FIG. 4 shows a chemical structure of wood pulp cellulose, which is used in the present invention.
FIG. 5
FIG. 5 is a schematic diagram showing the action of spunbonding natural graphene cellulose blended fabric of the present invention. 15
FIG. 6
FIG. 6 is a schematic diagram showing the manufacturing process of the present invention. Detailed Description of the Preferred Embodiments To further …
FIG. 25
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
A method of preparing natural graphene cellulose blended spunbond nonwoven fabric, which comprises the following steps: (a) combining a graphite powder with a solution comprising 1 to 10 wt. % of a first 5 compound selected from the group consisting of sulfuric acid (H 2 S O 4), hydrochloric acid (HCl), perchloric acid (HC l O 4), hydrogen iodide (HI), hydrofluoric acid (HF), and nitric acid (H NO 3), then stirring for 30 minutes in an ice bath environment; (b) adding a solution comprising 1 to 20 wt. % potassium permanganate (KMnO 4) to 10 the product of step (a), stirring for 1 to 2 hours, and adding distilled water, wherein the potassium permanganate solution is continuously added until none of the purple smoke generated by reacting with the potassium permanganate is formed from the distilled water; (c) adding a solution comprising 1 to 10 wt.% hydrogen peroxide (H 2 0 2) to the product 15 of step (b), wherein the hydrogen peroxide solution is added until no bubbles are formed and the mixture becomes dark green, then filtering the dark green solution into a cake; (d) rinsing the cake of step (c) with a solution comprising 5 wt.% hydrochloric acid (HCl) to remove sulfate ions, then washing the cake with distilled water; 20 (e) drying the cake of step (d) in an oven at 40 ° C for 2 hrs to obtain a dried solid graphite oxide; (f) adding distilled water to the dried solid graphite oxide of step (e), wherein the distilled water is added up to 200 m l s per 0.06 to 1.0 g of the dried solid graphite-21-oxide, then treating by ultrasonic vibration for 30 minutes to obtain a graphite oxide solution having a graphite oxide concentration of 0.03 wt. % to 0.5 wt. %; (g) adding a solution comprising 1 to 10 wt. % of a second compound selected from the group consisting of sodium borohydride (NaBH 4), potassium borohydride (KBH 4), 5 lithium aluminum hydride (LiA l H 4), and sodium citrate (C 6 H S Na 3 O 7) to the graphite oxide solution of step (f), then treating by ultrasonic vibration for 30 to 60 minutes, wherein in the resulting solution, the ratio of graphene oxide to the second compound is 1:1 to 1:5 by weight; (h) filtrating the product of step (g), washing the filtrate with water 3 to 5 times to 10 remove the second compound, then back-filtrating to obtain a graphene solution; (i) adding the graphene solution of step (h) to a slurry solution formed by mixing a pulp with N-methylmorpholine N-oxide (NMMO) and a stabilizer in an expansion dissolving tank, then mixing at 60 to 80 ° C, wherein the graphene solution of step (h) is added in a ratio of 0.11 to 5.0 wt. %, the pulp is selected from the group 15 consisting of wood pulp, cotton pulp, bamboo pulp and a mixture of cotton and bamboo pulp, the pulp comprises a-cellulose in an amount of 65 % or more with a polymerization degree of 500 to 1500; and the NMMO has a concentration of 50 % to 78 %; (j) removing water from the product of step (i) using a Thin Film Evaporator (TFE) 20 and heating at 80 to 130 ° C, wherein the water is removed to 5% to 13% within 5 minutes and the cellulose is dissolved to form a spinning dope, and the amount ratio of each component among the components comprised in the dope is: water (H 2 0) 5 % to 15 %, N-methylmorpholine N-oxide (N M MO) 70 % to 90 %, and -22-cellulose 5 % to 15 %; (k) Squeezing the spinning dope of step () from a spinning orifice by using a spunbond process to form a natural graphene cellulose blended filament strand, which comprises pressuring the spinning dope by a metering pump, filtering and 5 degassing by a continuous filter (CPF), transporting the spinning dope into a spinning tank, and stretching the spinning dope outward by air gap cooling through the spinning orifice, to form a natural graphene cellulose blended filament strand; and (1) feeding the natural graphene cellulose blended filament strand of step (k) into a 10 coagulation liquid, solidifying and regenerating the filament strand, stretching the filament strand under high pressure and high speed by an air stream drafting device, stacking the filament strand on a collection web to form a fibrous network structure, and washing, water needle punching, drying, oiling and coiling the fibrous network structure to form a natural graphene cellulose blended spunbond nonwoven fabric, 15 wherein the concentration of the coagulation liquid is between 2. 0% to 10.0 %, and after washing, the amount of residual N MM O solvent is less than 0.1 %.
The method of claim 1, further comprising a recycle process of N-methylmorpholine N-oxide (N M MO) released during the regeneration and washing stages of step (1), 10 which comprises the following recycle steps: A. filtering the NMMO released during the regeneration and washing stages of step (1) using a filter cartridge 1 to 20 m; B. injecting the N M MO obtained after the filtration of step A. into a flocculation tank, processing for about 1 to 2 hours using a f l locutant and other additives in an 15 adding amount of 1.5 to 10.0 mg/L; discharging impurities out through slits of a filter mesh; C. injecting NMMO obtained after the flocculation processing of step B. into an ion exchange system comprising an ion exchange resin having chargeability; D. filtering the product of step C. by using an ultra-filter and a reverse osmosis (RO) 20 filter; E. reducing the water content the product of step D. by distillation through the recirculation operation of a multieffect evaporation device, purifying it step by step until the concentration of the NMMO becomes 50.0 % to 78. 0%, then -24-discharging it to be used as a feed material; and F. filtering the product of step E. using an ultra-filter and reverse osmosis (RO) filter.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
Method of Preparing of Natural Graphene Cellulose Blended Spunbond Nonwoven Fabric
Wen-Tung CHOU
US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a block diagram showing the manufacturing process of the present invention.
FIG. 2
FIG. 2 is an electron microscope (TEM) image (100 X) of the graphene prepared by the process according to the present invention.
FIG. 3
FIG. 3 shows a chemical structure of N-methylmorpholine N-oxide (referred to as 10 NM M O) solvent, which is used in the present invention.
FIG. 4
FIG. 4 shows a chemical structure of wood pulp cellulose, which is used in the present invention.
FIG. 5
FIG. 5 is a schematic diagram showing the action of spunbonding natural graphene cellulose blended fabric of the present invention. 15
FIG. 6
FIG. 6 is a schematic diagram showing the manufacturing process of the present invention. Detailed Description of the Preferred Embodiments To further …
FIG. 25
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
A method of preparing natural graphene cellulose blended spunbond nonwoven fabric, which comprises the following steps: (a) combining a graphite powder with a solution comprising 1 to 10 wt. % of a first 5 compound selected from the group consisting of sulfuric acid (H 2 S O 4), hydrochloric acid (HCl), perchloric acid (HC l O 4), hydrogen iodide (HI), hydrofluoric acid (HF), and nitric acid (H NO 3), then stirring for 30 minutes in an ice bath environment; (b) adding a solution comprising 1 to 20 wt. % potassium permanganate (KMnO 4) to 10 the product of step (a), stirring for 1 to 2 hours, and adding distilled water, wherein the potassium permanganate solution is continuously added until none of the purple smoke generated by reacting with the potassium permanganate is formed from the distilled water; (c) adding a solution comprising 1 to 10 wt.% hydrogen peroxide (H 2 0 2) to the product 15 of step (b), wherein the hydrogen peroxide solution is added until no bubbles are formed and the mixture becomes dark green, then filtering the dark green solution into a cake; (d) rinsing the cake of step (c) with a solution comprising 5 wt.% hydrochloric acid (HCl) to remove sulfate ions, then washing the cake with distilled water; 20 (e) drying the cake of step (d) in an oven at 40 ° C for 2 hrs to obtain a dried solid graphite oxide; (f) adding distilled water to the dried solid graphite oxide of step (e), wherein the distilled water is added up to 200 m l s per 0.06 to 1.0 g of the dried solid graphite-21-oxide, then treating by ultrasonic vibration for 30 minutes to obtain a graphite oxide solution having a graphite oxide concentration of 0.03 wt. % to 0.5 wt. %; (g) adding a solution comprising 1 to 10 wt. % of a second compound selected from the group consisting of sodium borohydride (NaBH 4), potassium borohydride (KBH 4), 5 lithium aluminum hydride (LiA l H 4), and sodium citrate (C 6 H S Na 3 O 7) to the graphite oxide solution of step (f), then treating by ultrasonic vibration for 30 to 60 minutes, wherein in the resulting solution, the ratio of graphene oxide to the second compound is 1:1 to 1:5 by weight; (h) filtrating the product of step (g), washing the filtrate with water 3 to 5 times to 10 remove the second compound, then back-filtrating to obtain a graphene solution; (i) adding the graphene solution of step (h) to a slurry solution formed by mixing a pulp with N-methylmorpholine N-oxide (NMMO) and a stabilizer in an expansion dissolving tank, then mixing at 60 to 80 ° C, wherein the graphene solution of step (h) is added in a ratio of 0.11 to 5.0 wt. %, the pulp is selected from the group 15 consisting of wood pulp, cotton pulp, bamboo pulp and a mixture of cotton and bamboo pulp, the pulp comprises a-cellulose in an amount of 65 % or more with a polymerization degree of 500 to 1500; and the NMMO has a concentration of 50 % to 78 %; (j) removing water from the product of step (i) using a Thin Film Evaporator (TFE) 20 and heating at 80 to 130 ° C, wherein the water is removed to 5% to 13% within 5 minutes and the cellulose is dissolved to form a spinning dope, and the amount ratio of each component among the components comprised in the dope is: water (H 2 0) 5 % to 15 %, N-methylmorpholine N-oxide (N M MO) 70 % to 90 %, and -22-cellulose 5 % to 15 %; (k) Squeezing the spinning dope of step () from a spinning orifice by using a spunbond process to form a natural graphene cellulose blended filament strand, which comprises pressuring the spinning dope by a metering pump, filtering and 5 degassing by a continuous filter (CPF), transporting the spinning dope into a spinning tank, and stretching the spinning dope outward by air gap cooling through the spinning orifice, to form a natural graphene cellulose blended filament strand; and (1) feeding the natural graphene cellulose blended filament strand of step (k) into a 10 coagulation liquid, solidifying and regenerating the filament strand, stretching the filament strand under high pressure and high speed by an air stream drafting device, stacking the filament strand on a collection web to form a fibrous network structure, and washing, water needle punching, drying, oiling and coiling the fibrous network structure to form a natural graphene cellulose blended spunbond nonwoven fabric, 15 wherein the concentration of the coagulation liquid is between 2. 0% to 10.0 %, and after washing, the amount of residual N MM O solvent is less than 0.1 %.
The method of claim 1, further comprising a recycle process of N-methylmorpholine N-oxide (N M MO) released during the regeneration and washing stages of step (1), 10 which comprises the following recycle steps: A. filtering the NMMO released during the regeneration and washing stages of step (1) using a filter cartridge 1 to 20 m; B. injecting the N M MO obtained after the filtration of step A. into a flocculation tank, processing for about 1 to 2 hours using a f l locutant and other additives in an 15 adding amount of 1.5 to 10.0 mg/L; discharging impurities out through slits of a filter mesh; C. injecting NMMO obtained after the flocculation processing of step B. into an ion exchange system comprising an ion exchange resin having chargeability; D. filtering the product of step C. by using an ultra-filter and a reverse osmosis (RO) 20 filter; E. reducing the water content the product of step D. by distillation through the recirculation operation of a multieffect evaporation device, purifying it step by step until the concentration of the NMMO becomes 50.0 % to 78. 0%, then -24-discharging it to be used as a feed material; and F. filtering the product of step E. using an ultra-filter and reverse osmosis (RO) filter.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
Materials:N-methylmorpholine N-oxide (NMMO)pulp (wood pulp, cotton pulp, bamboo pulp, or mixture of cotton and bamboo pulp)graphene
6
Spunbond Spinning
Step 6
Process details
step k:squeeze spinning dope from spinning orifice by spunbond process; pressure by metering pump, filter and degas by continuous filter (CPF), transport to spinning tank, stretch outward by air gap cooling through spinning orifice
step l:feed filament strand into coagulation liquid, solidify and regenerate, stretch under high pressure and high speed by air stream drafting device, stack on collection web, wash, water needle punch, dry, oil, and coil to form nonwoven fabric
Materials:N-methylmorpholine N-oxide (NMMO)pulp (wood pulp, cotton pulp, bamboo pulp, or mixture of cotton and bamboo pulp)graphene
6
Spunbond Spinning
Step 6
Process details
step k:squeeze spinning dope from spinning orifice by spunbond process; pressure by metering pump, filter and degas by continuous filter (CPF), transport to spinning tank, stretch outward by air gap cooling through spinning orifice
step l:feed filament strand into coagulation liquid, solidify and regenerate, stretch under high pressure and high speed by air stream drafting device, stack on collection web, wash, water needle punch, dry, oil, and coil to form nonwoven fabric
Materials:N-methylmorpholine N-oxide (NMMO)pulp (wood pulp, cotton pulp, bamboo pulp, or mixture of cotton and bamboo pulp)graphene
6
Spunbond Spinning
Step 6
Process details
step k:squeeze spinning dope from spinning orifice by spunbond process; pressure by metering pump, filter and degas by continuous filter (CPF), transport to spinning tank, stretch outward by air gap cooling through spinning orifice
step l:feed filament strand into coagulation liquid, solidify and regenerate, stretch under high pressure and high speed by air stream drafting device, stack on collection web, wash, water needle punch, dry, oil, and coil to form nonwoven fabric
Materials:N-methylmorpholine N-oxide (NMMO)pulp (wood pulp, cotton pulp, bamboo pulp, or mixture of cotton and bamboo pulp)graphene
6
Spunbond Spinning
Step 6
Process details
step k:squeeze spinning dope from spinning orifice by spunbond process; pressure by metering pump, filter and degas by continuous filter (CPF), transport to spinning tank, stretch outward by air gap cooling through spinning orifice
step l:feed filament strand into coagulation liquid, solidify and regenerate, stretch under high pressure and high speed by air stream drafting device, stack on collection web, wash, water needle punch, dry, oil, and coil to form nonwoven fabric