Patent
US 10,347,916dopa
noradrenalin
3,4-dihydroxybenzoic acid
3,4-dihydroxyphenylacetic acid
caffeic acid
4-methylcatechol
4-tert-butylpyrocatechol
compound with modified 1,2-benzendiol structure (3- to 6-position modified)
graphene powder with catechol-group compound |
N/C element ratio by XPS-Example 1 graphene powder after reduction | 0.006 atomic ratio | graphene powder with catechol-group compound |
weight ratio of dopamine hydrochloride to graphene-Example 1 | 6 wt% | graphene powder with catechol-group compound |
electrical conductivity of graphene powder after reduction-Comparative Example 2 (dopamine, 100°C, 24h) | 681 S/m | graphene powder with catechol-group compound |
O/C element ratio by XPS-Comparative Example 2 graphene powder | 0.23 atomic ratio | graphene powder with catechol-group compound |
N/C element ratio by XPS-Comparative Example 2 graphene powder | 0.013 atomic ratio | graphene powder with catechol-group compound |
weight ratio of dopamine hydrochloride to graphene-Comparative Example 2 | 17 wt% | graphene powder with catechol-group compound |
discharge capacity of LIB electrode-Comparative Example 2 | 129 mAh/g | graphene powder with catechol-group compound |
O/C element ratio by XPS-Comparative Example 3 graphene powder (catechol, 40°C, 30 min) | 0.42 atomic ratio | graphene powder with catechol-group compound |
weight ratio of catechol in graphene powder-Comparative Example 3 | 13 wt% | graphene powder with catechol-group compound |
dopa
noradrenalin
3,4-dihydroxybenzoic acid
3,4-dihydroxyphenylacetic acid
caffeic acid
4-methylcatechol
4-tert-butylpyrocatechol
compound with modified 1,2-benzendiol structure (3- to 6-position modified)
graphene powder with catechol-group compound |
N/C element ratio by XPS-Example 1 graphene powder after reduction | 0.006 atomic ratio | graphene powder with catechol-group compound |
weight ratio of dopamine hydrochloride to graphene-Example 1 | 6 wt% | graphene powder with catechol-group compound |
electrical conductivity of graphene powder after reduction-Comparative Example 2 (dopamine, 100°C, 24h) | 681 S/m | graphene powder with catechol-group compound |
O/C element ratio by XPS-Comparative Example 2 graphene powder | 0.23 atomic ratio | graphene powder with catechol-group compound |
N/C element ratio by XPS-Comparative Example 2 graphene powder | 0.013 atomic ratio | graphene powder with catechol-group compound |
weight ratio of dopamine hydrochloride to graphene-Comparative Example 2 | 17 wt% | graphene powder with catechol-group compound |
discharge capacity of LIB electrode-Comparative Example 2 | 129 mAh/g | graphene powder with catechol-group compound |
O/C element ratio by XPS-Comparative Example 3 graphene powder (catechol, 40°C, 30 min) | 0.42 atomic ratio | graphene powder with catechol-group compound |
weight ratio of catechol in graphene powder-Comparative Example 3 | 13 wt% | graphene powder with catechol-group compound |
dopa
noradrenalin
3,4-dihydroxybenzoic acid
3,4-dihydroxyphenylacetic acid
caffeic acid
4-methylcatechol
4-tert-butylpyrocatechol
compound with modified 1,2-benzendiol structure (3- to 6-position modified)
graphene powder with catechol-group compound |
N/C element ratio by XPS-Example 1 graphene powder after reduction | 0.006 atomic ratio | graphene powder with catechol-group compound |
weight ratio of dopamine hydrochloride to graphene-Example 1 | 6 wt% | graphene powder with catechol-group compound |
electrical conductivity of graphene powder after reduction-Comparative Example 2 (dopamine, 100°C, 24h) | 681 S/m | graphene powder with catechol-group compound |
O/C element ratio by XPS-Comparative Example 2 graphene powder | 0.23 atomic ratio | graphene powder with catechol-group compound |
N/C element ratio by XPS-Comparative Example 2 graphene powder | 0.013 atomic ratio | graphene powder with catechol-group compound |
weight ratio of dopamine hydrochloride to graphene-Comparative Example 2 | 17 wt% | graphene powder with catechol-group compound |
discharge capacity of LIB electrode-Comparative Example 2 | 129 mAh/g | graphene powder with catechol-group compound |
O/C element ratio by XPS-Comparative Example 3 graphene powder (catechol, 40°C, 30 min) | 0.42 atomic ratio | graphene powder with catechol-group compound |
weight ratio of catechol in graphene powder-Comparative Example 3 | 13 wt% | graphene powder with catechol-group compound |
dopa
noradrenalin
3,4-dihydroxybenzoic acid
3,4-dihydroxyphenylacetic acid
caffeic acid
4-methylcatechol
4-tert-butylpyrocatechol
compound with modified 1,2-benzendiol structure (3- to 6-position modified)
graphene powder with catechol-group compound |
N/C element ratio by XPS-Example 1 graphene powder after reduction | 0.006 atomic ratio | graphene powder with catechol-group compound |
weight ratio of dopamine hydrochloride to graphene-Example 1 | 6 wt% | graphene powder with catechol-group compound |
electrical conductivity of graphene powder after reduction-Comparative Example 2 (dopamine, 100°C, 24h) | 681 S/m | graphene powder with catechol-group compound |
O/C element ratio by XPS-Comparative Example 2 graphene powder | 0.23 atomic ratio | graphene powder with catechol-group compound |
N/C element ratio by XPS-Comparative Example 2 graphene powder | 0.013 atomic ratio | graphene powder with catechol-group compound |
weight ratio of dopamine hydrochloride to graphene-Comparative Example 2 | 17 wt% | graphene powder with catechol-group compound |
discharge capacity of LIB electrode-Comparative Example 2 | 129 mAh/g | graphene powder with catechol-group compound |
O/C element ratio by XPS-Comparative Example 3 graphene powder (catechol, 40°C, 30 min) | 0.42 atomic ratio | graphene powder with catechol-group compound |
weight ratio of catechol in graphene powder-Comparative Example 3 | 13 wt% | graphene powder with catechol-group compound |