METHOD FOR PRODUCING GAN LAYERED SUBSTRATE | Matter42 Literature
Patent
Atlas literature
Patent
US 11,967,530 B2
METHOD FOR PRODUCING GAN LAYERED SUBSTRATE
Sumio Sekiyama, Yoshihiro Kubota
SHIN-ETSU CHEMICAL CO., LTD., Tokyo (JP)·Apr. 23, 2024·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a diagram showing a production process in an embodiment of a method for producing a GaN layered substrate according to the present invention, where …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
A method for producing a GaN layered substrate, comprising the steps of: subjecting a C-plane sapphire substrate having an off-angle of 0.5 to 5 degrees to a high-temperature nitriding treatment at 800° C. to 1,000° C. and/or a treatment for deposition of crystalline AlN on the C-plane sapphire substrate to carry out a surface treatment of the C-plane sapphire substrate; carrying out epitaxial growth of GaN on the surface of the surface-treated C-plane sapphire substrate, so that a GaN film is formed on the surface of the surface-treated C-plane sapphire substrate, whereby a GaN film carrier having a surface of an N polar face is produced; forming an ion implantation region by carrying out ion implantation on the GaN film of the GaN film carrier; Evaluation result of GaN transfer Silicon oxide Support thin film film surface substrate surface Polishing Polishing rough- Substrate rough-by Depo- by ness configu- ness Crystal-CMP sition CMP Ra ration Ra linity* None Done Done 0.3 nm Si 8 nm 300 substrate arcsec (Thermal oxide formation) Done None None 0.2 nm Si 0.3 nm 250 substrate arcsec (Thermal oxide formation) None Done Done 0.2 nm Si 60 nm 600 substrate arcsec (Thermal oxide formation) None Done Done 0.3 nm Si 80 nm 800 substrate arcsec (Thermal oxide formation) plane laminating and bonding a support substrate with a surface of the GaN film of the GaN film carrier, to which the ion implantation has been carried out; and performing delamination at the ion-implanted region in the GaN film to transfer a GaN thin film onto the support substrate, to obtain a GaN layered substrate having, on the support substrate, the GaN thin film whose surface is a Ga polar face.
2
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein the GaN epitaxial growth is carried out at a higher temperature than the high-temperature nitriding treatment.
3
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein the GaN epitaxial growth is carried out by a MOCVD method.
4
Dependent← claim 1GaNGaN
The method for producing a GaN layered substrate according to claim 1, wherein after the surface treatment of the C-plane sapphire substrate is carried out, a GaN buffer layer is formed at 700° C. or lower, and the GaN epitaxial growth is then carried out on the GaN buffer layer.
6
Dependent← claim 1GaNSiO₂
The method for producing a GaN layered substrate according to claim 1, wherein after the GaN film is formed by the epitaxial growth, a silicon oxide film is further formed on the GaN film to obtain the GaN film carrier.
7
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein before the ion implantation, the surface of the GaN film is smoothed to an arithmetic mean roughness Ra of 0.3 nm or less.
8
Dependent← claim 1
The method for producing a GaN layered substrate according to claim 1, wherein the ion implantation is a treatment using hydrogen ions (H+) and/or hydrogen-mol-ecule ions (H₂ +) at an implantation energy of 100 keV to 160 keV and a dose of 1.0×1017 atom/cm2 to 3.0×1017 atom/cm2.
9
Dependent← claim 1support substrate
The method for producing a GaN layered substrate according to claim 1, wherein the support substrate is made of Si, Al₂O3, SiC, AlN or SiO2.
11
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein thickness of the GaN thin film is 500 nm or greater and less than thickness of the GaN film. ∗ ∗ ∗ ∗ ∗
Worked examples
Embodiments described in the patent, grouped by the materials and process steps they use.
Example (Table in Claim 1/Examples section)
example section example
3 materials1 process step
GaN transfer experiments comparing configurations with/without CMP polishing of GaN film surface and deposition of silicon oxide film, using Si support substrates with thermal oxide. Results tabulated: (1) No CMP/oxide deposition/CMP on support: GaN surface Ra 0.3 nm, support Ra 8 nm, crystallinity 300 arcsec; (2) CMP/no oxide deposition/no support CMP: GaN surface Ra 0.2 nm, support Ra 0.3 nm, crystallinity 250 arcsec; (3) No CMP/oxide deposition/CMP: GaN surface Ra 0.2 nm, support Ra 60 nm, crystallinity 600 arcsec; (4) No CMP/oxide deposition/CMP: GaN surface Ra 0.3 nm, support Ra 80 nm, crystallinity 800 arcsec.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
GaN layered substrate
GaNGaN thin film Ga polar face surface
SiO₂bonding interlayer silicon oxide
support substratesupport substrate
Materials
Materials described outside the worked examples.
C-plane sapphire substrate
Al₂O₃
Donor Substrate
crystalline AlN
AlN
Surface Treatment Deposit
Process steps
Additional fabrication and treatment steps described in the patent.
1
Ion Implantation And Transfer
Step 1
Process details
energy keV:100 to 160
ion species:H+ and/or H₂+
dose atom per cm2:
Reported properties
Performance values and ranges asserted in the specification or claims.
Property
Value
Material
GaN film surface Ra before ion implantation (claimed upper limit)
0.3 nm
GaN
GaN buffer layer thickness (claimed range)
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 11
US 2008/0111144 A12008/0111144 A1 5/2008 Fichtenbaum et al.
US 2009/0221131 A12009/0221131 A1 * 9/2009 Kubota................... C30B 29/40examiner
US 2012/0223329 A12012/0223329 A1 * 9/2012 Kinoshita............. C30B 25/186examiner
US 2013/0115753 A12013/0115753 A1 5/2013 Eo et al.
US 2014/0065360 A12014/0065360 A1 * 3/2014 D’Evelyn............... C30B 25/18
Why these are connected
Related documents with shared materials, methods, properties, or citations.
SHIN-ETSU CHEMICAL CO., LTD., Tokyo (JP)·Apr. 23, 2024·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a diagram showing a production process in an embodiment of a method for producing a GaN layered substrate according to the present invention, where …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
A method for producing a GaN layered substrate, comprising the steps of: subjecting a C-plane sapphire substrate having an off-angle of 0.5 to 5 degrees to a high-temperature nitriding treatment at 800° C. to 1,000° C. and/or a treatment for deposition of crystalline AlN on the C-plane sapphire substrate to carry out a surface treatment of the C-plane sapphire substrate; carrying out epitaxial growth of GaN on the surface of the surface-treated C-plane sapphire substrate, so that a GaN film is formed on the surface of the surface-treated C-plane sapphire substrate, whereby a GaN film carrier having a surface of an N polar face is produced; forming an ion implantation region by carrying out ion implantation on the GaN film of the GaN film carrier; Evaluation result of GaN transfer Silicon oxide Support thin film film surface substrate surface Polishing Polishing rough- Substrate rough-by Depo- by ness configu- ness Crystal-CMP sition CMP Ra ration Ra linity* None Done Done 0.3 nm Si 8 nm 300 substrate arcsec (Thermal oxide formation) Done None None 0.2 nm Si 0.3 nm 250 substrate arcsec (Thermal oxide formation) None Done Done 0.2 nm Si 60 nm 600 substrate arcsec (Thermal oxide formation) None Done Done 0.3 nm Si 80 nm 800 substrate arcsec (Thermal oxide formation) plane laminating and bonding a support substrate with a surface of the GaN film of the GaN film carrier, to which the ion implantation has been carried out; and performing delamination at the ion-implanted region in the GaN film to transfer a GaN thin film onto the support substrate, to obtain a GaN layered substrate having, on the support substrate, the GaN thin film whose surface is a Ga polar face.
2
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein the GaN epitaxial growth is carried out at a higher temperature than the high-temperature nitriding treatment.
3
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein the GaN epitaxial growth is carried out by a MOCVD method.
4
Dependent← claim 1GaNGaN
The method for producing a GaN layered substrate according to claim 1, wherein after the surface treatment of the C-plane sapphire substrate is carried out, a GaN buffer layer is formed at 700° C. or lower, and the GaN epitaxial growth is then carried out on the GaN buffer layer.
6
Dependent← claim 1GaNSiO₂
The method for producing a GaN layered substrate according to claim 1, wherein after the GaN film is formed by the epitaxial growth, a silicon oxide film is further formed on the GaN film to obtain the GaN film carrier.
7
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein before the ion implantation, the surface of the GaN film is smoothed to an arithmetic mean roughness Ra of 0.3 nm or less.
8
Dependent← claim 1
The method for producing a GaN layered substrate according to claim 1, wherein the ion implantation is a treatment using hydrogen ions (H+) and/or hydrogen-mol-ecule ions (H₂ +) at an implantation energy of 100 keV to 160 keV and a dose of 1.0×1017 atom/cm2 to 3.0×1017 atom/cm2.
9
Dependent← claim 1support substrate
The method for producing a GaN layered substrate according to claim 1, wherein the support substrate is made of Si, Al₂O3, SiC, AlN or SiO2.
11
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein thickness of the GaN thin film is 500 nm or greater and less than thickness of the GaN film. ∗ ∗ ∗ ∗ ∗
Worked examples
Embodiments described in the patent, grouped by the materials and process steps they use.
Example (Table in Claim 1/Examples section)
example section example
3 materials1 process step
GaN transfer experiments comparing configurations with/without CMP polishing of GaN film surface and deposition of silicon oxide film, using Si support substrates with thermal oxide. Results tabulated: (1) No CMP/oxide deposition/CMP on support: GaN surface Ra 0.3 nm, support Ra 8 nm, crystallinity 300 arcsec; (2) CMP/no oxide deposition/no support CMP: GaN surface Ra 0.2 nm, support Ra 0.3 nm, crystallinity 250 arcsec; (3) No CMP/oxide deposition/CMP: GaN surface Ra 0.2 nm, support Ra 60 nm, crystallinity 600 arcsec; (4) No CMP/oxide deposition/CMP: GaN surface Ra 0.3 nm, support Ra 80 nm, crystallinity 800 arcsec.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
GaN layered substrate
GaNGaN thin film Ga polar face surface
SiO₂bonding interlayer silicon oxide
support substratesupport substrate
Materials
Materials described outside the worked examples.
C-plane sapphire substrate
Al₂O₃
Donor Substrate
crystalline AlN
AlN
Surface Treatment Deposit
Process steps
Additional fabrication and treatment steps described in the patent.
1
Ion Implantation And Transfer
Step 1
Process details
energy keV:100 to 160
ion species:H+ and/or H₂+
dose atom per cm2:
Reported properties
Performance values and ranges asserted in the specification or claims.
Property
Value
Material
GaN film surface Ra before ion implantation (claimed upper limit)
0.3 nm
GaN
GaN buffer layer thickness (claimed range)
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 11
US 2008/0111144 A12008/0111144 A1 5/2008 Fichtenbaum et al.
US 2009/0221131 A12009/0221131 A1 * 9/2009 Kubota................... C30B 29/40examiner
US 2012/0223329 A12012/0223329 A1 * 9/2012 Kinoshita............. C30B 25/186examiner
US 2013/0115753 A12013/0115753 A1 5/2013 Eo et al.
US 2014/0065360 A12014/0065360 A1 * 3/2014 D’Evelyn............... C30B 25/18
Why these are connected
Related documents with shared materials, methods, properties, or citations.
SHIN-ETSU CHEMICAL CO., LTD., Tokyo (JP)·Apr. 23, 2024·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a diagram showing a production process in an embodiment of a method for producing a GaN layered substrate according to the present invention, where …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
A method for producing a GaN layered substrate, comprising the steps of: subjecting a C-plane sapphire substrate having an off-angle of 0.5 to 5 degrees to a high-temperature nitriding treatment at 800° C. to 1,000° C. and/or a treatment for deposition of crystalline AlN on the C-plane sapphire substrate to carry out a surface treatment of the C-plane sapphire substrate; carrying out epitaxial growth of GaN on the surface of the surface-treated C-plane sapphire substrate, so that a GaN film is formed on the surface of the surface-treated C-plane sapphire substrate, whereby a GaN film carrier having a surface of an N polar face is produced; forming an ion implantation region by carrying out ion implantation on the GaN film of the GaN film carrier; Evaluation result of GaN transfer Silicon oxide Support thin film film surface substrate surface Polishing Polishing rough- Substrate rough-by Depo- by ness configu- ness Crystal-CMP sition CMP Ra ration Ra linity* None Done Done 0.3 nm Si 8 nm 300 substrate arcsec (Thermal oxide formation) Done None None 0.2 nm Si 0.3 nm 250 substrate arcsec (Thermal oxide formation) None Done Done 0.2 nm Si 60 nm 600 substrate arcsec (Thermal oxide formation) None Done Done 0.3 nm Si 80 nm 800 substrate arcsec (Thermal oxide formation) plane laminating and bonding a support substrate with a surface of the GaN film of the GaN film carrier, to which the ion implantation has been carried out; and performing delamination at the ion-implanted region in the GaN film to transfer a GaN thin film onto the support substrate, to obtain a GaN layered substrate having, on the support substrate, the GaN thin film whose surface is a Ga polar face.
2
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein the GaN epitaxial growth is carried out at a higher temperature than the high-temperature nitriding treatment.
3
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein the GaN epitaxial growth is carried out by a MOCVD method.
4
Dependent← claim 1GaNGaN
The method for producing a GaN layered substrate according to claim 1, wherein after the surface treatment of the C-plane sapphire substrate is carried out, a GaN buffer layer is formed at 700° C. or lower, and the GaN epitaxial growth is then carried out on the GaN buffer layer.
6
Dependent← claim 1GaNSiO₂
The method for producing a GaN layered substrate according to claim 1, wherein after the GaN film is formed by the epitaxial growth, a silicon oxide film is further formed on the GaN film to obtain the GaN film carrier.
7
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein before the ion implantation, the surface of the GaN film is smoothed to an arithmetic mean roughness Ra of 0.3 nm or less.
8
Dependent← claim 1
The method for producing a GaN layered substrate according to claim 1, wherein the ion implantation is a treatment using hydrogen ions (H+) and/or hydrogen-mol-ecule ions (H₂ +) at an implantation energy of 100 keV to 160 keV and a dose of 1.0×1017 atom/cm2 to 3.0×1017 atom/cm2.
9
Dependent← claim 1support substrate
The method for producing a GaN layered substrate according to claim 1, wherein the support substrate is made of Si, Al₂O3, SiC, AlN or SiO2.
11
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein thickness of the GaN thin film is 500 nm or greater and less than thickness of the GaN film. ∗ ∗ ∗ ∗ ∗
Worked examples
Embodiments described in the patent, grouped by the materials and process steps they use.
Example (Table in Claim 1/Examples section)
example section example
3 materials1 process step
GaN transfer experiments comparing configurations with/without CMP polishing of GaN film surface and deposition of silicon oxide film, using Si support substrates with thermal oxide. Results tabulated: (1) No CMP/oxide deposition/CMP on support: GaN surface Ra 0.3 nm, support Ra 8 nm, crystallinity 300 arcsec; (2) CMP/no oxide deposition/no support CMP: GaN surface Ra 0.2 nm, support Ra 0.3 nm, crystallinity 250 arcsec; (3) No CMP/oxide deposition/CMP: GaN surface Ra 0.2 nm, support Ra 60 nm, crystallinity 600 arcsec; (4) No CMP/oxide deposition/CMP: GaN surface Ra 0.3 nm, support Ra 80 nm, crystallinity 800 arcsec.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
GaN layered substrate
GaNGaN thin film Ga polar face surface
SiO₂bonding interlayer silicon oxide
support substratesupport substrate
Materials
Materials described outside the worked examples.
C-plane sapphire substrate
Al₂O₃
Donor Substrate
crystalline AlN
AlN
Surface Treatment Deposit
Process steps
Additional fabrication and treatment steps described in the patent.
1
Ion Implantation And Transfer
Step 1
Process details
energy keV:100 to 160
ion species:H+ and/or H₂+
dose atom per cm2:
Reported properties
Performance values and ranges asserted in the specification or claims.
Property
Value
Material
GaN film surface Ra before ion implantation (claimed upper limit)
0.3 nm
GaN
GaN buffer layer thickness (claimed range)
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 11
US 2008/0111144 A12008/0111144 A1 5/2008 Fichtenbaum et al.
US 2009/0221131 A12009/0221131 A1 * 9/2009 Kubota................... C30B 29/40examiner
US 2012/0223329 A12012/0223329 A1 * 9/2012 Kinoshita............. C30B 25/186examiner
US 2013/0115753 A12013/0115753 A1 5/2013 Eo et al.
US 2014/0065360 A12014/0065360 A1 * 3/2014 D’Evelyn............... C30B 25/18
Why these are connected
Related documents with shared materials, methods, properties, or citations.
SHIN-ETSU CHEMICAL CO., LTD., Tokyo (JP)·Apr. 23, 2024·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a diagram showing a production process in an embodiment of a method for producing a GaN layered substrate according to the present invention, where …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
A method for producing a GaN layered substrate, comprising the steps of: subjecting a C-plane sapphire substrate having an off-angle of 0.5 to 5 degrees to a high-temperature nitriding treatment at 800° C. to 1,000° C. and/or a treatment for deposition of crystalline AlN on the C-plane sapphire substrate to carry out a surface treatment of the C-plane sapphire substrate; carrying out epitaxial growth of GaN on the surface of the surface-treated C-plane sapphire substrate, so that a GaN film is formed on the surface of the surface-treated C-plane sapphire substrate, whereby a GaN film carrier having a surface of an N polar face is produced; forming an ion implantation region by carrying out ion implantation on the GaN film of the GaN film carrier; Evaluation result of GaN transfer Silicon oxide Support thin film film surface substrate surface Polishing Polishing rough- Substrate rough-by Depo- by ness configu- ness Crystal-CMP sition CMP Ra ration Ra linity* None Done Done 0.3 nm Si 8 nm 300 substrate arcsec (Thermal oxide formation) Done None None 0.2 nm Si 0.3 nm 250 substrate arcsec (Thermal oxide formation) None Done Done 0.2 nm Si 60 nm 600 substrate arcsec (Thermal oxide formation) None Done Done 0.3 nm Si 80 nm 800 substrate arcsec (Thermal oxide formation) plane laminating and bonding a support substrate with a surface of the GaN film of the GaN film carrier, to which the ion implantation has been carried out; and performing delamination at the ion-implanted region in the GaN film to transfer a GaN thin film onto the support substrate, to obtain a GaN layered substrate having, on the support substrate, the GaN thin film whose surface is a Ga polar face.
2
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein the GaN epitaxial growth is carried out at a higher temperature than the high-temperature nitriding treatment.
3
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein the GaN epitaxial growth is carried out by a MOCVD method.
4
Dependent← claim 1GaNGaN
The method for producing a GaN layered substrate according to claim 1, wherein after the surface treatment of the C-plane sapphire substrate is carried out, a GaN buffer layer is formed at 700° C. or lower, and the GaN epitaxial growth is then carried out on the GaN buffer layer.
6
Dependent← claim 1GaNSiO₂
The method for producing a GaN layered substrate according to claim 1, wherein after the GaN film is formed by the epitaxial growth, a silicon oxide film is further formed on the GaN film to obtain the GaN film carrier.
7
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein before the ion implantation, the surface of the GaN film is smoothed to an arithmetic mean roughness Ra of 0.3 nm or less.
8
Dependent← claim 1
The method for producing a GaN layered substrate according to claim 1, wherein the ion implantation is a treatment using hydrogen ions (H+) and/or hydrogen-mol-ecule ions (H₂ +) at an implantation energy of 100 keV to 160 keV and a dose of 1.0×1017 atom/cm2 to 3.0×1017 atom/cm2.
9
Dependent← claim 1support substrate
The method for producing a GaN layered substrate according to claim 1, wherein the support substrate is made of Si, Al₂O3, SiC, AlN or SiO2.
11
Dependent← claim 1GaN
The method for producing a GaN layered substrate according to claim 1, wherein thickness of the GaN thin film is 500 nm or greater and less than thickness of the GaN film. ∗ ∗ ∗ ∗ ∗
Worked examples
Embodiments described in the patent, grouped by the materials and process steps they use.
Example (Table in Claim 1/Examples section)
example section example
3 materials1 process step
GaN transfer experiments comparing configurations with/without CMP polishing of GaN film surface and deposition of silicon oxide film, using Si support substrates with thermal oxide. Results tabulated: (1) No CMP/oxide deposition/CMP on support: GaN surface Ra 0.3 nm, support Ra 8 nm, crystallinity 300 arcsec; (2) CMP/no oxide deposition/no support CMP: GaN surface Ra 0.2 nm, support Ra 0.3 nm, crystallinity 250 arcsec; (3) No CMP/oxide deposition/CMP: GaN surface Ra 0.2 nm, support Ra 60 nm, crystallinity 600 arcsec; (4) No CMP/oxide deposition/CMP: GaN surface Ra 0.3 nm, support Ra 80 nm, crystallinity 800 arcsec.
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
GaN layered substrate
GaNGaN thin film Ga polar face surface
SiO₂bonding interlayer silicon oxide
support substratesupport substrate
Materials
Materials described outside the worked examples.
C-plane sapphire substrate
Al₂O₃
Donor Substrate
crystalline AlN
AlN
Surface Treatment Deposit
Process steps
Additional fabrication and treatment steps described in the patent.
1
Ion Implantation And Transfer
Step 1
Process details
energy keV:100 to 160
ion species:H+ and/or H₂+
dose atom per cm2:
Reported properties
Performance values and ranges asserted in the specification or claims.
Property
Value
Material
GaN film surface Ra before ion implantation (claimed upper limit)
0.3 nm
GaN
GaN buffer layer thickness (claimed range)
Cited prior art
Patents and literature cited by this patent (applicant and examiner references).
Cited patents · 11
US 2008/0111144 A12008/0111144 A1 5/2008 Fichtenbaum et al.
US 2009/0221131 A12009/0221131 A1 * 9/2009 Kubota................... C30B 29/40examiner
US 2012/0223329 A12012/0223329 A1 * 9/2012 Kinoshita............. C30B 25/186examiner
US 2013/0115753 A12013/0115753 A1 5/2013 Eo et al.
US 2014/0065360 A12014/0065360 A1 * 3/2014 D’Evelyn............... C30B 25/18
Why these are connected
Related documents with shared materials, methods, properties, or citations.