METHOD OF PRODUCING LARGE GaAs AND GaP INFRARED WINDOWS | Matter42 Literature
Patent
Atlas literature
Patent
US 12,650,538 B2
METHOD OF PRODUCING LARGE GaAs AND GaP INFRARED WINDOWS
Peter G. Schunemann, Kevin T. Zawilski
BAE Systems Information and Electronic Systems Integration Inc., Nashua, NH (US)·Jun. 9, 2026·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a perspective view showing a substrate wafer placed within an LP-HVPE reactor;
FIG. 2
FIG. 2 is a graph that illustrates the decreased absorption near 1 micron of GaAs grown via LP-HVPE as compared to GaAs from a boule grown from melt;
FIG. 3
apparatus side view
FIG. 3 is a cross-sectional side view illustrating a method of growing GaAs slabs by HVPE on a silicon substrate, whereby layers of GaAsP are applied to the …
FIG. 4
apparatus side view
FIG. 4A is a cross-sectional side view illustrating an embodiment where a sacrificial layer is included between the GaAs or GaP slab and the silicon substrate; …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
1 independent · 7 dependent
1
IndependentGaAsSilarge GaAs infrared window
An infrared window comprising a GaAs slab having a slab largest dimension that is greater than eight inches, said slab being formed from a substrate wafer of single crystal silicon to which at least one layer of GaAs has been applied by Hydride Vapor Phase Epitaxy (“HVPE”), the substrate wafer being removable from the slab.
2
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab largest dimension is greater than 12 inches.
3
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab is substantially round, having a slab diameter of greater than eight inches.
5
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab is at least 2 mm thick.
The infrared window of claim 1, further comprising an electrically conductive layer of doped GaAs or GaP applied to the slab.
7
Dependent← claim 1Silarge GaAs infrared window
The infrared windows of claim 1, wherein the substrate wafer is a wafer of single crystal silicon.
8
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, further comprising an anti-reflective coating applied to the slab. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
large GaAs infrared window
GaAsemi shielding layer (optional)
GaAsir window slab
GaAsPbuffer layer (optional)
Sisubstrate (removable)
Materials
Materials described outside the worked examples.
GaAs
Claimed Ir Window Slab Material
Electrically Conductive Emi Shielding Layer
single crystal silicon
Si
Process steps
Additional fabrication and treatment steps described in the patent.
1
Hvpe Growth
Step 1
Process details
notes:Large-diameter Si substrates commercially available up to 12 inch standard, 18 inch custom, 24 inch demonstrated; thermodynamics and kinetics of HVPE growth process independent of diameter and layer thickness; full-thickness plates can be produced in less than a week for some applications
method:
Characterization
Measurements and analyses referenced in the patent, with their drawing references.
optical absorption
Optical Absorption
FIG. 2 is a graph that illustrates the decreased absorption near 1 micron of GaAs grown via LP-HVPE as compared to GaAs from a boule grown from melt;
METHOD OF PRODUCING LARGE GaAs AND GaP INFRARED WINDOWS
Peter G. Schunemann, Kevin T. Zawilski
BAE Systems Information and Electronic Systems Integration Inc., Nashua, NH (US)·Jun. 9, 2026·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a perspective view showing a substrate wafer placed within an LP-HVPE reactor;
FIG. 2
FIG. 2 is a graph that illustrates the decreased absorption near 1 micron of GaAs grown via LP-HVPE as compared to GaAs from a boule grown from melt;
FIG. 3
apparatus side view
FIG. 3 is a cross-sectional side view illustrating a method of growing GaAs slabs by HVPE on a silicon substrate, whereby layers of GaAsP are applied to the …
FIG. 4
apparatus side view
FIG. 4A is a cross-sectional side view illustrating an embodiment where a sacrificial layer is included between the GaAs or GaP slab and the silicon substrate; …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
1 independent · 7 dependent
1
IndependentGaAsSilarge GaAs infrared window
An infrared window comprising a GaAs slab having a slab largest dimension that is greater than eight inches, said slab being formed from a substrate wafer of single crystal silicon to which at least one layer of GaAs has been applied by Hydride Vapor Phase Epitaxy (“HVPE”), the substrate wafer being removable from the slab.
2
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab largest dimension is greater than 12 inches.
3
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab is substantially round, having a slab diameter of greater than eight inches.
5
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab is at least 2 mm thick.
The infrared window of claim 1, further comprising an electrically conductive layer of doped GaAs or GaP applied to the slab.
7
Dependent← claim 1Silarge GaAs infrared window
The infrared windows of claim 1, wherein the substrate wafer is a wafer of single crystal silicon.
8
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, further comprising an anti-reflective coating applied to the slab. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
large GaAs infrared window
GaAsemi shielding layer (optional)
GaAsir window slab
GaAsPbuffer layer (optional)
Sisubstrate (removable)
Materials
Materials described outside the worked examples.
GaAs
Claimed Ir Window Slab Material
Electrically Conductive Emi Shielding Layer
single crystal silicon
Si
Process steps
Additional fabrication and treatment steps described in the patent.
1
Hvpe Growth
Step 1
Process details
notes:Large-diameter Si substrates commercially available up to 12 inch standard, 18 inch custom, 24 inch demonstrated; thermodynamics and kinetics of HVPE growth process independent of diameter and layer thickness; full-thickness plates can be produced in less than a week for some applications
method:
Characterization
Measurements and analyses referenced in the patent, with their drawing references.
optical absorption
Optical Absorption
FIG. 2 is a graph that illustrates the decreased absorption near 1 micron of GaAs grown via LP-HVPE as compared to GaAs from a boule grown from melt;
METHOD OF PRODUCING LARGE GaAs AND GaP INFRARED WINDOWS
Peter G. Schunemann, Kevin T. Zawilski
BAE Systems Information and Electronic Systems Integration Inc., Nashua, NH (US)·Jun. 9, 2026·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a perspective view showing a substrate wafer placed within an LP-HVPE reactor;
FIG. 2
FIG. 2 is a graph that illustrates the decreased absorption near 1 micron of GaAs grown via LP-HVPE as compared to GaAs from a boule grown from melt;
FIG. 3
apparatus side view
FIG. 3 is a cross-sectional side view illustrating a method of growing GaAs slabs by HVPE on a silicon substrate, whereby layers of GaAsP are applied to the …
FIG. 4
apparatus side view
FIG. 4A is a cross-sectional side view illustrating an embodiment where a sacrificial layer is included between the GaAs or GaP slab and the silicon substrate; …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
1 independent · 7 dependent
1
IndependentGaAsSilarge GaAs infrared window
An infrared window comprising a GaAs slab having a slab largest dimension that is greater than eight inches, said slab being formed from a substrate wafer of single crystal silicon to which at least one layer of GaAs has been applied by Hydride Vapor Phase Epitaxy (“HVPE”), the substrate wafer being removable from the slab.
2
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab largest dimension is greater than 12 inches.
3
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab is substantially round, having a slab diameter of greater than eight inches.
5
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab is at least 2 mm thick.
The infrared window of claim 1, further comprising an electrically conductive layer of doped GaAs or GaP applied to the slab.
7
Dependent← claim 1Silarge GaAs infrared window
The infrared windows of claim 1, wherein the substrate wafer is a wafer of single crystal silicon.
8
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, further comprising an anti-reflective coating applied to the slab. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
large GaAs infrared window
GaAsemi shielding layer (optional)
GaAsir window slab
GaAsPbuffer layer (optional)
Sisubstrate (removable)
Materials
Materials described outside the worked examples.
GaAs
Claimed Ir Window Slab Material
Electrically Conductive Emi Shielding Layer
single crystal silicon
Si
Process steps
Additional fabrication and treatment steps described in the patent.
1
Hvpe Growth
Step 1
Process details
notes:Large-diameter Si substrates commercially available up to 12 inch standard, 18 inch custom, 24 inch demonstrated; thermodynamics and kinetics of HVPE growth process independent of diameter and layer thickness; full-thickness plates can be produced in less than a week for some applications
method:
Characterization
Measurements and analyses referenced in the patent, with their drawing references.
optical absorption
Optical Absorption
FIG. 2 is a graph that illustrates the decreased absorption near 1 micron of GaAs grown via LP-HVPE as compared to GaAs from a boule grown from melt;
METHOD OF PRODUCING LARGE GaAs AND GaP INFRARED WINDOWS
Peter G. Schunemann, Kevin T. Zawilski
BAE Systems Information and Electronic Systems Integration Inc., Nashua, NH (US)·Jun. 9, 2026·US
Drawings
Patent drawings and their descriptions. Click a drawing to enlarge it.
FIG. 1
FIG. 1 is a perspective view showing a substrate wafer placed within an LP-HVPE reactor;
FIG. 2
FIG. 2 is a graph that illustrates the decreased absorption near 1 micron of GaAs grown via LP-HVPE as compared to GaAs from a boule grown from melt;
FIG. 3
apparatus side view
FIG. 3 is a cross-sectional side view illustrating a method of growing GaAs slabs by HVPE on a silicon substrate, whereby layers of GaAsP are applied to the …
FIG. 4
apparatus side view
FIG. 4A is a cross-sectional side view illustrating an embodiment where a sacrificial layer is included between the GaAs or GaP slab and the silicon substrate; …
Claims
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
1 independent · 7 dependent
1
IndependentGaAsSilarge GaAs infrared window
An infrared window comprising a GaAs slab having a slab largest dimension that is greater than eight inches, said slab being formed from a substrate wafer of single crystal silicon to which at least one layer of GaAs has been applied by Hydride Vapor Phase Epitaxy (“HVPE”), the substrate wafer being removable from the slab.
2
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab largest dimension is greater than 12 inches.
3
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab is substantially round, having a slab diameter of greater than eight inches.
5
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, wherein the slab is at least 2 mm thick.
The infrared window of claim 1, further comprising an electrically conductive layer of doped GaAs or GaP applied to the slab.
7
Dependent← claim 1Silarge GaAs infrared window
The infrared windows of claim 1, wherein the substrate wafer is a wafer of single crystal silicon.
8
Dependent← claim 1GaAslarge GaAs infrared window
The infrared window of claim 1, further comprising an anti-reflective coating applied to the slab. ∗ ∗ ∗ ∗ ∗
Device structures
Layer stacks claimed or described, ordered top of device to substrate.
large GaAs infrared window
GaAsemi shielding layer (optional)
GaAsir window slab
GaAsPbuffer layer (optional)
Sisubstrate (removable)
Materials
Materials described outside the worked examples.
GaAs
Claimed Ir Window Slab Material
Electrically Conductive Emi Shielding Layer
single crystal silicon
Si
Process steps
Additional fabrication and treatment steps described in the patent.
1
Hvpe Growth
Step 1
Process details
notes:Large-diameter Si substrates commercially available up to 12 inch standard, 18 inch custom, 24 inch demonstrated; thermodynamics and kinetics of HVPE growth process independent of diameter and layer thickness; full-thickness plates can be produced in less than a week for some applications
method:
Characterization
Measurements and analyses referenced in the patent, with their drawing references.
optical absorption
Optical Absorption
FIG. 2 is a graph that illustrates the decreased absorption near 1 micron of GaAs grown via LP-HVPE as compared to GaAs from a boule grown from melt;
buffer layer:GaAsP layers varying from 0% to 100% As composition for GaAs on Si
Materials:GaAsGaP
GaAs
GaAs
GaP transparency range
—
GaP
Thickness
≥ 2 mm
—
US 5,824,418 A5,824,418 A 10/1998 Tully
US 6,287,478 B16,287,478 B1 * 9/2001 Klocek................... C30B 29/64examiner
US 10,156,023 B210,156,023 B2 12/2018 Schunemann
US 12,084,791 B212,084,791 B2 * 9/2024 Schunemann.......... C30B 29/42examiner
US 12,203,192 B212,203,192 B2 * 1/2025 Reeves................ H05K 9/0005examiner
US 12,302,542 B212,302,542 B2 * 5/2025 Schunemann........ C23C 16/306examiner
US 2003/0172870 A12003/0172870 A1 9/2003 Liu
US 2010/0219509 A12010/0219509 A1 9/2010 He
US 2011/0256693 A12011/0256693 A1 10/2011 D’Evelyn
US 2012/0031324 A12012/0031324 A1 2/2012 Hiromura
US 2012/0097092 A12012/0097092 A1 4/2012 Zhu
US 2012/0255484 A12012/0255484 A1 10/2012 Zhu
US 2014/0162441 A12014/0162441 A1 6/2014 Preble
US 2017/0362739 A12017/0362739 A1 12/2017 Kajimoto
US 2024/0183065 A12024/0183065 A1 * 6/2024 Schunemann.......... C30B 29/42examiner
Cited non-patent literature · 2
Jeremy B. Reeves et. al., Method of Optimizing the EMI Shielding and Infrared Transparency of GaAs IR Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/072,931.
Empirical low-field mobility model for III-V compounds applicable in device simulation codes.. Peter G. Schunemann et. al., Method of Producing Large EMI Shielded GaAs Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,179. Peter G. Schunemann et. al., Method of Producing Large EMI Shielded GaAs and GaP Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,183. Peter G. Schunemann et. al., Method of Producing Large GaAs and GaP Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,228. Sotoodeh, M., A. H. Khalid, and A. A. Rezazadeh. “Empirical low-field mobility model for III-V compounds applicable in device simulation codes.” Journal of applied physics 87.6 dated Mar. 15, 2000): 2890-2900. Stromberg, A., Bhargava, P., Xu, Z., Lourdudoss, S. and Sun, Y. (2021), Direct Heteroepitaxy and Selective Area Growth of GaP and GaAs on Si by Hydride Vapor Phase Epitaxy. Phys. Status Solidi A, dated Oct. 17, 2020 218.3. Office Action for U.S. Appl. No. 18/073,179 mail date Sep. 10, 2024, 16 pages. Notice of Allowance for U.S. Appl. No. 18/073,228 mail date 240930, 15 pages (Sep. 30, 2024).
buffer layer:GaAsP layers varying from 0% to 100% As composition for GaAs on Si
Materials:GaAsGaP
GaAs
GaAs
GaP transparency range
—
GaP
Thickness
≥ 2 mm
—
US 5,824,418 A5,824,418 A 10/1998 Tully
US 6,287,478 B16,287,478 B1 * 9/2001 Klocek................... C30B 29/64examiner
US 10,156,023 B210,156,023 B2 12/2018 Schunemann
US 12,084,791 B212,084,791 B2 * 9/2024 Schunemann.......... C30B 29/42examiner
US 12,203,192 B212,203,192 B2 * 1/2025 Reeves................ H05K 9/0005examiner
US 12,302,542 B212,302,542 B2 * 5/2025 Schunemann........ C23C 16/306examiner
US 2003/0172870 A12003/0172870 A1 9/2003 Liu
US 2010/0219509 A12010/0219509 A1 9/2010 He
US 2011/0256693 A12011/0256693 A1 10/2011 D’Evelyn
US 2012/0031324 A12012/0031324 A1 2/2012 Hiromura
US 2012/0097092 A12012/0097092 A1 4/2012 Zhu
US 2012/0255484 A12012/0255484 A1 10/2012 Zhu
US 2014/0162441 A12014/0162441 A1 6/2014 Preble
US 2017/0362739 A12017/0362739 A1 12/2017 Kajimoto
US 2024/0183065 A12024/0183065 A1 * 6/2024 Schunemann.......... C30B 29/42examiner
Cited non-patent literature · 2
Jeremy B. Reeves et. al., Method of Optimizing the EMI Shielding and Infrared Transparency of GaAs IR Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/072,931.
Empirical low-field mobility model for III-V compounds applicable in device simulation codes.. Peter G. Schunemann et. al., Method of Producing Large EMI Shielded GaAs Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,179. Peter G. Schunemann et. al., Method of Producing Large EMI Shielded GaAs and GaP Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,183. Peter G. Schunemann et. al., Method of Producing Large GaAs and GaP Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,228. Sotoodeh, M., A. H. Khalid, and A. A. Rezazadeh. “Empirical low-field mobility model for III-V compounds applicable in device simulation codes.” Journal of applied physics 87.6 dated Mar. 15, 2000): 2890-2900. Stromberg, A., Bhargava, P., Xu, Z., Lourdudoss, S. and Sun, Y. (2021), Direct Heteroepitaxy and Selective Area Growth of GaP and GaAs on Si by Hydride Vapor Phase Epitaxy. Phys. Status Solidi A, dated Oct. 17, 2020 218.3. Office Action for U.S. Appl. No. 18/073,179 mail date Sep. 10, 2024, 16 pages. Notice of Allowance for U.S. Appl. No. 18/073,228 mail date 240930, 15 pages (Sep. 30, 2024).
buffer layer:GaAsP layers varying from 0% to 100% As composition for GaAs on Si
Materials:GaAsGaP
GaAs
GaAs
GaP transparency range
—
GaP
Thickness
≥ 2 mm
—
US 5,824,418 A5,824,418 A 10/1998 Tully
US 6,287,478 B16,287,478 B1 * 9/2001 Klocek................... C30B 29/64examiner
US 10,156,023 B210,156,023 B2 12/2018 Schunemann
US 12,084,791 B212,084,791 B2 * 9/2024 Schunemann.......... C30B 29/42examiner
US 12,203,192 B212,203,192 B2 * 1/2025 Reeves................ H05K 9/0005examiner
US 12,302,542 B212,302,542 B2 * 5/2025 Schunemann........ C23C 16/306examiner
US 2003/0172870 A12003/0172870 A1 9/2003 Liu
US 2010/0219509 A12010/0219509 A1 9/2010 He
US 2011/0256693 A12011/0256693 A1 10/2011 D’Evelyn
US 2012/0031324 A12012/0031324 A1 2/2012 Hiromura
US 2012/0097092 A12012/0097092 A1 4/2012 Zhu
US 2012/0255484 A12012/0255484 A1 10/2012 Zhu
US 2014/0162441 A12014/0162441 A1 6/2014 Preble
US 2017/0362739 A12017/0362739 A1 12/2017 Kajimoto
US 2024/0183065 A12024/0183065 A1 * 6/2024 Schunemann.......... C30B 29/42examiner
Cited non-patent literature · 2
Jeremy B. Reeves et. al., Method of Optimizing the EMI Shielding and Infrared Transparency of GaAs IR Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/072,931.
Empirical low-field mobility model for III-V compounds applicable in device simulation codes.. Peter G. Schunemann et. al., Method of Producing Large EMI Shielded GaAs Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,179. Peter G. Schunemann et. al., Method of Producing Large EMI Shielded GaAs and GaP Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,183. Peter G. Schunemann et. al., Method of Producing Large GaAs and GaP Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,228. Sotoodeh, M., A. H. Khalid, and A. A. Rezazadeh. “Empirical low-field mobility model for III-V compounds applicable in device simulation codes.” Journal of applied physics 87.6 dated Mar. 15, 2000): 2890-2900. Stromberg, A., Bhargava, P., Xu, Z., Lourdudoss, S. and Sun, Y. (2021), Direct Heteroepitaxy and Selective Area Growth of GaP and GaAs on Si by Hydride Vapor Phase Epitaxy. Phys. Status Solidi A, dated Oct. 17, 2020 218.3. Office Action for U.S. Appl. No. 18/073,179 mail date Sep. 10, 2024, 16 pages. Notice of Allowance for U.S. Appl. No. 18/073,228 mail date 240930, 15 pages (Sep. 30, 2024).
buffer layer:GaAsP layers varying from 0% to 100% As composition for GaAs on Si
Materials:GaAsGaP
GaAs
GaAs
GaP transparency range
—
GaP
Thickness
≥ 2 mm
—
US 5,824,418 A5,824,418 A 10/1998 Tully
US 6,287,478 B16,287,478 B1 * 9/2001 Klocek................... C30B 29/64examiner
US 10,156,023 B210,156,023 B2 12/2018 Schunemann
US 12,084,791 B212,084,791 B2 * 9/2024 Schunemann.......... C30B 29/42examiner
US 12,203,192 B212,203,192 B2 * 1/2025 Reeves................ H05K 9/0005examiner
US 12,302,542 B212,302,542 B2 * 5/2025 Schunemann........ C23C 16/306examiner
US 2003/0172870 A12003/0172870 A1 9/2003 Liu
US 2010/0219509 A12010/0219509 A1 9/2010 He
US 2011/0256693 A12011/0256693 A1 10/2011 D’Evelyn
US 2012/0031324 A12012/0031324 A1 2/2012 Hiromura
US 2012/0097092 A12012/0097092 A1 4/2012 Zhu
US 2012/0255484 A12012/0255484 A1 10/2012 Zhu
US 2014/0162441 A12014/0162441 A1 6/2014 Preble
US 2017/0362739 A12017/0362739 A1 12/2017 Kajimoto
US 2024/0183065 A12024/0183065 A1 * 6/2024 Schunemann.......... C30B 29/42examiner
Cited non-patent literature · 2
Jeremy B. Reeves et. al., Method of Optimizing the EMI Shielding and Infrared Transparency of GaAs IR Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/072,931.
Empirical low-field mobility model for III-V compounds applicable in device simulation codes.. Peter G. Schunemann et. al., Method of Producing Large EMI Shielded GaAs Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,179. Peter G. Schunemann et. al., Method of Producing Large EMI Shielded GaAs and GaP Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,183. Peter G. Schunemann et. al., Method of Producing Large GaAs and GaP Infrared Windows, patent application, filed Dec. 1, 2022, U.S. Appl. No. 18/073,228. Sotoodeh, M., A. H. Khalid, and A. A. Rezazadeh. “Empirical low-field mobility model for III-V compounds applicable in device simulation codes.” Journal of applied physics 87.6 dated Mar. 15, 2000): 2890-2900. Stromberg, A., Bhargava, P., Xu, Z., Lourdudoss, S. and Sun, Y. (2021), Direct Heteroepitaxy and Selective Area Growth of GaP and GaAs on Si by Hydride Vapor Phase Epitaxy. Phys. Status Solidi A, dated Oct. 17, 2020 218.3. Office Action for U.S. Appl. No. 18/073,179 mail date Sep. 10, 2024, 16 pages. Notice of Allowance for U.S. Appl. No. 18/073,228 mail date 240930, 15 pages (Sep. 30, 2024).