Abstract

Pyroelectric energy conversion offers a route for harvesting time-dependent thermal fluctuations that are abundant in natural and technological environments. Two-dimensional ferroelectrics are particularly attractive for this purpose because reduced dimensionality enables ultrathin, mechanically compliant device architectures. Here, we demonstrate direct nanoscale pyroelectric characterization of an out-of-plane van der Waals nanogenerator based on CuInP₂S₆ (CIPS) encapsulated between few-layer graphene electrodes. A scanning thermal microscopy (SThM) probe is employed as a localized nanoscale heat source while the electrically generated response is measured in situ through the device electrodes. Harmonic detection isolates the pyroelectric signal from parasitic first-harmonic electromechanical contributions, while finite-element thermal modeling combined with probe calibration enables direct determination of the local pyroelectric coefficient from the measured electrical response. Beyond quantitative characterization, the spatially resolved measurements directly identify electrically inactive regions associated with device defects, revealing local performance-limiting features that remain hidden in conventional spatially averaged pyroelectric measurements. The presented approach establishes a versatile platform for quantitative nanoscale pyroelectric characterization and the optimization of van der Waals pyroelectric devices.

Abstract

Pyroelectric energy conversion offers a route for harvesting time-dependent thermal fluctuations that are abundant in natural and technological environments. Two-dimensional ferroelectrics are particularly attractive for this purpose because reduced dimensionality enables ultrathin, mechanically compliant device architectures. Here, we demonstrate direct nanoscale pyroelectric characterization of an out-of-plane van der Waals nanogenerator based on CuInP₂S₆ (CIPS) encapsulated between few-layer graphene electrodes. A scanning thermal microscopy (SThM) probe is employed as a localized nanoscale heat source while the electrically generated response is measured in situ through the device electrodes. Harmonic detection isolates the pyroelectric signal from parasitic first-harmonic electromechanical contributions, while finite-element thermal modeling combined with probe calibration enables direct determination of the local pyroelectric coefficient from the measured electrical response. Beyond quantitative characterization, the spatially resolved measurements directly identify electrically inactive regions associated with device defects, revealing local performance-limiting features that remain hidden in conventional spatially averaged pyroelectric measurements. The presented approach establishes a versatile platform for quantitative nanoscale pyroelectric characterization and the optimization of van der Waals pyroelectric devices.

Abstract

Pyroelectric energy conversion offers a route for harvesting time-dependent thermal fluctuations that are abundant in natural and technological environments. Two-dimensional ferroelectrics are particularly attractive for this purpose because reduced dimensionality enables ultrathin, mechanically compliant device architectures. Here, we demonstrate direct nanoscale pyroelectric characterization of an out-of-plane van der Waals nanogenerator based on CuInP₂S₆ (CIPS) encapsulated between few-layer graphene electrodes. A scanning thermal microscopy (SThM) probe is employed as a localized nanoscale heat source while the electrically generated response is measured in situ through the device electrodes. Harmonic detection isolates the pyroelectric signal from parasitic first-harmonic electromechanical contributions, while finite-element thermal modeling combined with probe calibration enables direct determination of the local pyroelectric coefficient from the measured electrical response. Beyond quantitative characterization, the spatially resolved measurements directly identify electrically inactive regions associated with device defects, revealing local performance-limiting features that remain hidden in conventional spatially averaged pyroelectric measurements. The presented approach establishes a versatile platform for quantitative nanoscale pyroelectric characterization and the optimization of van der Waals pyroelectric devices.

Abstract

Pyroelectric energy conversion offers a route for harvesting time-dependent thermal fluctuations that are abundant in natural and technological environments. Two-dimensional ferroelectrics are particularly attractive for this purpose because reduced dimensionality enables ultrathin, mechanically compliant device architectures. Here, we demonstrate direct nanoscale pyroelectric characterization of an out-of-plane van der Waals nanogenerator based on CuInP₂S₆ (CIPS) encapsulated between few-layer graphene electrodes. A scanning thermal microscopy (SThM) probe is employed as a localized nanoscale heat source while the electrically generated response is measured in situ through the device electrodes. Harmonic detection isolates the pyroelectric signal from parasitic first-harmonic electromechanical contributions, while finite-element thermal modeling combined with probe calibration enables direct determination of the local pyroelectric coefficient from the measured electrical response. Beyond quantitative characterization, the spatially resolved measurements directly identify electrically inactive regions associated with device defects, revealing local performance-limiting features that remain hidden in conventional spatially averaged pyroelectric measurements. The presented approach establishes a versatile platform for quantitative nanoscale pyroelectric characterization and the optimization of van der Waals pyroelectric devices.