Patent
US 9,343,541Patent
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Patent
US 9,343,541Patent drawings and their descriptions. Click a drawing to enlarge it.
FIGS. 1A-1C a re cross-sectiona l side vie w s that illu str a te an exam ple GaN- based HFET de vic e at var ious stag es i n a fa brication pr ocess, in acco …
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
The m eth od o f cla im 1 fu rther co mpris ng' 036 92. B₁₅₅C -13- Application forming, w ithi n the re action ch am ber, a silicon nitride l ayer ato p the oxy-ni tride lay er; a nd removing the wafer from the react ion chamber 13. The m eth od o f c laim 1 w here in the oxy-nitrde la yer is formed wi th a graded nitrogen composition that va n es from a hi ghes t at omi c per centage at or nea r the nitrde la yer to a low est at ormc percentage at or near a top surfac e of the oxy-n itri de layer 14 The m eth od of claim 1 where i n the n itride-b ased sem iconductor la yer compris es AI GaN 15 A method of fab ricating a multvl ayer stru ctu re f or a heter oJunction field- effect trans istor (HFET) device comprising. (a) exposing, wi thin the reacti on chamber, a top surface of a nitride- base d sem iconducto r layer to a first alu min um s ource. (b) exposi ng, withi n the react ion chamber, the w afer to a nitro gen (N) p las m a res ulting in the fo rmat ion o f an alum inum nitrid e (AIN) la yer at op the n i tride-base d se miconductor la yer, (c) exposing, within the react io n cha m ber, a top surface o f the AIN la yer t o a sec ond alu minu m s ou rce and (d) e xposing, within the react io n cha m ber, the wafer t o a nitrogen-ox ygen plas ma, res ulti ng i n the f ormation of an alum inum oxy- nit ri de (AION) layer atop the AIN la yer. wherein the nit ride la yer c ompr ses a p ass i vat ion lay er and the oxy- nit ride layer c omprn ses a gate d i elect ri c of the pow er transistor dev ice 036 92. B₁₅₅C -14-Application 16. The m eth o d of claim 15 wherein the first alu minum sou rce and the second alum inum sourc e b o th compnr se a tn-m eth y l al uminum (TMA) source 17 The m eth o d of cla im 15 furt her c ompnrsing re p eatin g steps (a) and (b) until the A IN l ayer is f o rmed t o a first th i ckness 18 The m eth o d of claim 17 wherein the first th ic kness is i n a ra nge o f a bou t 2-10 nm th ick. 19 The m eth od of claim 15 fu rther com pris ing repe ating steps (c) and (d) until the AI ON layer is f o rmed to a se co nd thi ck ness 20 The method of claim 19 w herein the second th ick ness is in a range of a bout 10 -25 nm th ick. 21 The m eth od of cla im 15 fu rther c om pris ing forming, wi thin the reacti on chamber, a sil ico n n itri de layer atop the AI O N layer 22 The method o f claim 15 w herein the AIO N layer is f o rmed w ith a graded nitro gen c ompositio n that va ri es from a highest at omi c percentage at o r near the nit ri de layer t o a low est at orm c percentage at o r near a t op surface o f the ox y-nitride layer 23 The m eth od o f cla im 15 wherein the nit ride- based se miconductor l ayer comprises AIGaN 036 92. B₁₅₅C -15- Application 24 A nitri de-ba se d heter o-junctio n f i eld-effect tran sis tor (HFVET) device comprising' a f irs t active semiconducto r layer, a sec on d act ive semiconducto r layer d ispos ed at op the f i rst active sem iconducto r layer, a t wo-dimension al electr on g as be ing forme d th e rebet ween, a multi -layer structu re that includes a firs t n itri de-ba s ed passi vat ion layer dispo sed d i rectly on the secon d a ctiv e sem icondu ctor layer, an d a n o xy- nitri de layer dispo sed d i rect ly on the f irst nitr de-ba s ed pa ssi vati on layer, the f irst nitrdeb ased p ass ivation layer hav in g a f i rst th ickn ess a n d the o xy- ni tride l ayer hav ing a sec ond thickness, the oxy-nitrde layer comprsing a g ate d i elect ric o f the nitride- based HFET dev i ce, a nd spaced-apart s ource an d dra in ohmic contacts directly on, or in re ce sses t hat exten d thr oug h t h e sec on d act iv e se miconducto r layer. 25 The nitr de-based HF ET dev ic e of cla im 24 w here in the first nitri de-ba sed pass ivation l ayer compri se AIN 26 The nitri de-ba sed FE T dev ic e of cla im 24 w her ein the first nitride-based pass ivation layer c ompri se SiN 27 The nit ri de- bas ed FE T de vice of claim 24 wherei n t he firs t t hicknesis is in a ran g e of ab out 2 -10 nm thick. 28 The ni tride-based FE T de vice o f cla im 24 w here i n the oxy- nit n de layer comprise s AI ON. 036 92. B₁₅₅C -16- Application 29. The nitrde-based HFET device of a m 24 wherei n the second thicknes s i s in a range of about 10 -25 nm th ick ABSTRA CT O F THE DISCLOSURE A m eth od of fabricating a m ult -layer structu re f or a pow er tr ansistor device incl ude s per forming, withi n a rea ction chamber, a nitrogen pl asma st rk e, result ing in the f ormation of a nitride layer directly on a nitride-based active semiconductor layer A top surf ace o f the n itri de lay er i s the n exp os ed t o a second source A su bsequ ent nitrogen-oxygen plasm a st rik e res ul ts in the f ormation o f a n oxy-nitrde lay er directly o n the nitri de la yer The nitride layer compris es a p assivation lay er and the oxy- nitri de layer compri ses a g ate die lectric o f the p ow er tra nsistor device. 036 92. B₁₅₅C -18- Application SVG 14154355.01-14-2014.HQFF₄ZYVPXXIFW3.SPEC11165086.3.332.3048.2178.3091.svg 0.143 6.153 Drawing Black and white Claims What is claimed is:
(W ith drawn) A ni tri d e-b ased hete ro-junction field-effec t t ransistor ([HF ET) device comprising: a firs t act iv e se miconductor layer; a second activ e semi conducto r l ayer disposed atop the first a cti ve semiconductor l aye r, a two-dimensional electron gas being forme d there between; a multi-la yer structu re that i ncludes a fi rst nitride-based pas sivat ion layer disposed direc tly on the second active semiconductor l ayer, a nd an oxy-n itr ide layer dispo sed d ire ctly on the fi rst nitri de- based pa ssivation l ayer the first nitride-b ased p assi vation layer ha ving a first t hickness and the oxy-n itri d e layer havi ng a se con d thi ckn ess, the oxy-n itride layer comp risi ng a g ate diele ctric of the n itr i de-based HFET de vic e; a nd spac ed-apart s ource and d rai n ohmic contac ts direc tly on, o r in recesses tha t e xten d thr oug h, the s econ d act iv e sem iconducto r layer. withdrawn
The nitride-based HFET device of claim 24 wherein the first nitride-based passivation layer comprise A IN. withdrawn
The nitride-based HFET device of claim 24 wherein the first nitride-based pass ivation layer comprise SiN, withdrawn
The nitride-based H F ET device of claim 24 wherein the first thickness is in a range of about 2-10 nm thick. Atto rn ey Docket No.: 03692.8155 C-2-Amendment and Response ClI ent Re f. No. P L.0 316.US.C001 withdrawn
The n i tride-based HFET device of claim 24 wherein the oxy-nitride layer comprises AION. withdrawn
The nitride-based HFET device of claim 24 wherein the second thickness is in a range of about 10-25 nm thick. withdrawn
A method of fabricating formirn a passivation plus gate dielectric rnultilaver structure for a power-transister hetero-iunction field-effect transistor (HFET) device comprising: (a) exposi n~ g, in a reaction chamber, a top surface of a nitride-based semiconductor wafer to a first source that forms a flm of material on the top surface; (b) performing, within the reaction chamber, a first plasma strike that reacts with the film to form a nitride-based passivation layer on the top surface; (c) exposing, in the reaction chamber, the nitride-based semiconductor wafer to a second source that results in a reaction of a material on a surface of the nitride-based passivation layer; (d) performing, within the reaction chamber, a second plasma strike tha t r eacts with the materi al t o form an oxy-nitride layer directly on the nitride- based passivation layer, t he nitride-based passivation layer and the oxy-nitride layer comprising a gate dielectric of the powertrnsistor HFET device.
(Previousl y pr esented) The method of claim 30 wherein the first source comprises aluminum (Al), the first plasma strike comprises nitrogen (N) and the nitride-based passivation layer comprises AIN. Atto rn ey Docket No.: Q 3692. B 155 C-3-Amendment and Response CIeni t Re f. No. PL 0 316. US.C001
(Pr eviously presented) Th e method of cla im 30 wherein the fi rst source comprises silicon (Si), t he fi rs t p lasma strike comprises n itr ogen (N) and the nitride-based passivation layer comprises SiN. 33, The method of cla im 30 wherein th e fi rst source comprises a tri-methyl aluminum (TMA) source. 34, The method of claim 30 further comprising repeating steps (a) and (b) until the nitride-based passivation layer is formed to a firs t t hickness.
(Previously amended) The metho d of claim 30 further comprising, before step (a), loading the nitride-based semiconductor wafer into a reaction chamber, the n itri de-based semiconductor wafer not being removed from the reaction chamber until completion of steps (a)-d). Docket No.: 03692.8155-4-Amendment and Response SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.3.20.374.3062.532.3100.svg 0.127 0.527 Chemistry Black and white CI ent Re f. No. P L.0 316.US. C 001 39, (Pr evious ly presented) The method of claim 30 further comprises forming a silicon nitride lay er atop the oxy-nitride layer; wherein the oxy-nitride laye r is formed with a graded nitrogen composition that varies from a hi ghest atomic percentag e a t or ne ar the silicon nitride layer to a lowest atomic percentage at or near the oxy-nitride la yer.
(Previous ly presented) The method of claim 30 wherein the t op surface of the ni tri de-based semiconductor wafer comprises an AlGaN layer.
(Previous ly pr esented) The method of claim 30 wherein the f ilm of material comprises al uminum. 45, (Pr evious ly presented) The method of claim 30 wherein the film of materi al comprises silicon. Docket No.: Q3692.B₁₅₅C-- Amendment and Response SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.4.19.1301.3054.1325.3092.svg 0.127 0.08 Chemistry Black and white SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.4.19.374.3062.532.3100.svg 0.127 0.527 Chemistry Black and white CIeni t Re f. No. P L.0 316.US.C 001
(Previously amended) The metho d of c laim 34 further comprising repeating steps (c) and (d) until the oxy-n itri de layer is formed to a second thickness, the second thickness being greater than the fi r st t hickness.
Th e method of claim 34 wherein the fi rst thickness is in a range of about 2-10 nm thick.
The method of cl aim 35 wherein th e s econd thickness is in a range of about 10-25 nnm thick.
(Previous ly presented) Th e method of c lai m 40 wherein the AIGaN layer is formed at o p a GaN layer, a two dimensional ele ctr on gas channel (2- DUG) being formed a an interface between the A IGaN layer a n d t he GaN layer.
canceled
, (Previous ly presented) Th e m eth od of c lai m 30 wherein the r eaction ch amb er comprises an Atomic Layer Deposition (ALD) reaction chamber.
Layer stacks claimed or described, ordered top of device to substrate.
GaN-based hetero-junction field-effect transistor (HFET)
Materials described outside the worked examples.
oxy-nitride layer
aluminum nitride
AlN
silicon nitride
SiN
Additional fabrication and treatment steps described in the patent.
Performance values and ranges asserted in the specification or claims.
| Property | Value | Material |
|---|---|---|
Thickness | 2–10 nm | — |
Thickness |
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US 9,343,541Patent drawings and their descriptions. Click a drawing to enlarge it.
FIGS. 1A-1C a re cross-sectiona l side vie w s that illu str a te an exam ple GaN- based HFET de vic e at var ious stag es i n a fa brication pr ocess, in acco …
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
The m eth od o f cla im 1 fu rther co mpris ng' 036 92. B₁₅₅C -13- Application forming, w ithi n the re action ch am ber, a silicon nitride l ayer ato p the oxy-ni tride lay er; a nd removing the wafer from the react ion chamber 13. The m eth od o f c laim 1 w here in the oxy-nitrde la yer is formed wi th a graded nitrogen composition that va n es from a hi ghes t at omi c per centage at or nea r the nitrde la yer to a low est at ormc percentage at or near a top surfac e of the oxy-n itri de layer 14 The m eth od of claim 1 where i n the n itride-b ased sem iconductor la yer compris es AI GaN 15 A method of fab ricating a multvl ayer stru ctu re f or a heter oJunction field- effect trans istor (HFET) device comprising. (a) exposing, wi thin the reacti on chamber, a top surface of a nitride- base d sem iconducto r layer to a first alu min um s ource. (b) exposi ng, withi n the react ion chamber, the w afer to a nitro gen (N) p las m a res ulting in the fo rmat ion o f an alum inum nitrid e (AIN) la yer at op the n i tride-base d se miconductor la yer, (c) exposing, within the react io n cha m ber, a top surface o f the AIN la yer t o a sec ond alu minu m s ou rce and (d) e xposing, within the react io n cha m ber, the wafer t o a nitrogen-ox ygen plas ma, res ulti ng i n the f ormation of an alum inum oxy- nit ri de (AION) layer atop the AIN la yer. wherein the nit ride la yer c ompr ses a p ass i vat ion lay er and the oxy- nit ride layer c omprn ses a gate d i elect ri c of the pow er transistor dev ice 036 92. B₁₅₅C -14-Application 16. The m eth o d of claim 15 wherein the first alu minum sou rce and the second alum inum sourc e b o th compnr se a tn-m eth y l al uminum (TMA) source 17 The m eth o d of cla im 15 furt her c ompnrsing re p eatin g steps (a) and (b) until the A IN l ayer is f o rmed t o a first th i ckness 18 The m eth o d of claim 17 wherein the first th ic kness is i n a ra nge o f a bou t 2-10 nm th ick. 19 The m eth od of claim 15 fu rther com pris ing repe ating steps (c) and (d) until the AI ON layer is f o rmed to a se co nd thi ck ness 20 The method of claim 19 w herein the second th ick ness is in a range of a bout 10 -25 nm th ick. 21 The m eth od of cla im 15 fu rther c om pris ing forming, wi thin the reacti on chamber, a sil ico n n itri de layer atop the AI O N layer 22 The method o f claim 15 w herein the AIO N layer is f o rmed w ith a graded nitro gen c ompositio n that va ri es from a highest at omi c percentage at o r near the nit ri de layer t o a low est at orm c percentage at o r near a t op surface o f the ox y-nitride layer 23 The m eth od o f cla im 15 wherein the nit ride- based se miconductor l ayer comprises AIGaN 036 92. B₁₅₅C -15- Application 24 A nitri de-ba se d heter o-junctio n f i eld-effect tran sis tor (HFVET) device comprising' a f irs t active semiconducto r layer, a sec on d act ive semiconducto r layer d ispos ed at op the f i rst active sem iconducto r layer, a t wo-dimension al electr on g as be ing forme d th e rebet ween, a multi -layer structu re that includes a firs t n itri de-ba s ed passi vat ion layer dispo sed d i rectly on the secon d a ctiv e sem icondu ctor layer, an d a n o xy- nitri de layer dispo sed d i rect ly on the f irst nitr de-ba s ed pa ssi vati on layer, the f irst nitrdeb ased p ass ivation layer hav in g a f i rst th ickn ess a n d the o xy- ni tride l ayer hav ing a sec ond thickness, the oxy-nitrde layer comprsing a g ate d i elect ric o f the nitride- based HFET dev i ce, a nd spaced-apart s ource an d dra in ohmic contacts directly on, or in re ce sses t hat exten d thr oug h t h e sec on d act iv e se miconducto r layer. 25 The nitr de-based HF ET dev ic e of cla im 24 w here in the first nitri de-ba sed pass ivation l ayer compri se AIN 26 The nitri de-ba sed FE T dev ic e of cla im 24 w her ein the first nitride-based pass ivation layer c ompri se SiN 27 The nit ri de- bas ed FE T de vice of claim 24 wherei n t he firs t t hicknesis is in a ran g e of ab out 2 -10 nm thick. 28 The ni tride-based FE T de vice o f cla im 24 w here i n the oxy- nit n de layer comprise s AI ON. 036 92. B₁₅₅C -16- Application 29. The nitrde-based HFET device of a m 24 wherei n the second thicknes s i s in a range of about 10 -25 nm th ick ABSTRA CT O F THE DISCLOSURE A m eth od of fabricating a m ult -layer structu re f or a pow er tr ansistor device incl ude s per forming, withi n a rea ction chamber, a nitrogen pl asma st rk e, result ing in the f ormation of a nitride layer directly on a nitride-based active semiconductor layer A top surf ace o f the n itri de lay er i s the n exp os ed t o a second source A su bsequ ent nitrogen-oxygen plasm a st rik e res ul ts in the f ormation o f a n oxy-nitrde lay er directly o n the nitri de la yer The nitride layer compris es a p assivation lay er and the oxy- nitri de layer compri ses a g ate die lectric o f the p ow er tra nsistor device. 036 92. B₁₅₅C -18- Application SVG 14154355.01-14-2014.HQFF₄ZYVPXXIFW3.SPEC11165086.3.332.3048.2178.3091.svg 0.143 6.153 Drawing Black and white Claims What is claimed is:
(W ith drawn) A ni tri d e-b ased hete ro-junction field-effec t t ransistor ([HF ET) device comprising: a firs t act iv e se miconductor layer; a second activ e semi conducto r l ayer disposed atop the first a cti ve semiconductor l aye r, a two-dimensional electron gas being forme d there between; a multi-la yer structu re that i ncludes a fi rst nitride-based pas sivat ion layer disposed direc tly on the second active semiconductor l ayer, a nd an oxy-n itr ide layer dispo sed d ire ctly on the fi rst nitri de- based pa ssivation l ayer the first nitride-b ased p assi vation layer ha ving a first t hickness and the oxy-n itri d e layer havi ng a se con d thi ckn ess, the oxy-n itride layer comp risi ng a g ate diele ctric of the n itr i de-based HFET de vic e; a nd spac ed-apart s ource and d rai n ohmic contac ts direc tly on, o r in recesses tha t e xten d thr oug h, the s econ d act iv e sem iconducto r layer. withdrawn
The nitride-based HFET device of claim 24 wherein the first nitride-based passivation layer comprise A IN. withdrawn
The nitride-based HFET device of claim 24 wherein the first nitride-based pass ivation layer comprise SiN, withdrawn
The nitride-based H F ET device of claim 24 wherein the first thickness is in a range of about 2-10 nm thick. Atto rn ey Docket No.: 03692.8155 C-2-Amendment and Response ClI ent Re f. No. P L.0 316.US.C001 withdrawn
The n i tride-based HFET device of claim 24 wherein the oxy-nitride layer comprises AION. withdrawn
The nitride-based HFET device of claim 24 wherein the second thickness is in a range of about 10-25 nm thick. withdrawn
A method of fabricating formirn a passivation plus gate dielectric rnultilaver structure for a power-transister hetero-iunction field-effect transistor (HFET) device comprising: (a) exposi n~ g, in a reaction chamber, a top surface of a nitride-based semiconductor wafer to a first source that forms a flm of material on the top surface; (b) performing, within the reaction chamber, a first plasma strike that reacts with the film to form a nitride-based passivation layer on the top surface; (c) exposing, in the reaction chamber, the nitride-based semiconductor wafer to a second source that results in a reaction of a material on a surface of the nitride-based passivation layer; (d) performing, within the reaction chamber, a second plasma strike tha t r eacts with the materi al t o form an oxy-nitride layer directly on the nitride- based passivation layer, t he nitride-based passivation layer and the oxy-nitride layer comprising a gate dielectric of the powertrnsistor HFET device.
(Previousl y pr esented) The method of claim 30 wherein the first source comprises aluminum (Al), the first plasma strike comprises nitrogen (N) and the nitride-based passivation layer comprises AIN. Atto rn ey Docket No.: Q 3692. B 155 C-3-Amendment and Response CIeni t Re f. No. PL 0 316. US.C001
(Pr eviously presented) Th e method of cla im 30 wherein the fi rst source comprises silicon (Si), t he fi rs t p lasma strike comprises n itr ogen (N) and the nitride-based passivation layer comprises SiN. 33, The method of cla im 30 wherein th e fi rst source comprises a tri-methyl aluminum (TMA) source. 34, The method of claim 30 further comprising repeating steps (a) and (b) until the nitride-based passivation layer is formed to a firs t t hickness.
(Previously amended) The metho d of claim 30 further comprising, before step (a), loading the nitride-based semiconductor wafer into a reaction chamber, the n itri de-based semiconductor wafer not being removed from the reaction chamber until completion of steps (a)-d). Docket No.: 03692.8155-4-Amendment and Response SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.3.20.374.3062.532.3100.svg 0.127 0.527 Chemistry Black and white CI ent Re f. No. P L.0 316.US. C 001 39, (Pr evious ly presented) The method of claim 30 further comprises forming a silicon nitride lay er atop the oxy-nitride layer; wherein the oxy-nitride laye r is formed with a graded nitrogen composition that varies from a hi ghest atomic percentag e a t or ne ar the silicon nitride layer to a lowest atomic percentage at or near the oxy-nitride la yer.
(Previous ly presented) The method of claim 30 wherein the t op surface of the ni tri de-based semiconductor wafer comprises an AlGaN layer.
(Previous ly pr esented) The method of claim 30 wherein the f ilm of material comprises al uminum. 45, (Pr evious ly presented) The method of claim 30 wherein the film of materi al comprises silicon. Docket No.: Q3692.B₁₅₅C-- Amendment and Response SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.4.19.1301.3054.1325.3092.svg 0.127 0.08 Chemistry Black and white SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.4.19.374.3062.532.3100.svg 0.127 0.527 Chemistry Black and white CIeni t Re f. No. P L.0 316.US.C 001
(Previously amended) The metho d of c laim 34 further comprising repeating steps (c) and (d) until the oxy-n itri de layer is formed to a second thickness, the second thickness being greater than the fi r st t hickness.
Th e method of claim 34 wherein the fi rst thickness is in a range of about 2-10 nm thick.
The method of cl aim 35 wherein th e s econd thickness is in a range of about 10-25 nnm thick.
(Previous ly presented) Th e method of c lai m 40 wherein the AIGaN layer is formed at o p a GaN layer, a two dimensional ele ctr on gas channel (2- DUG) being formed a an interface between the A IGaN layer a n d t he GaN layer.
canceled
, (Previous ly presented) Th e m eth od of c lai m 30 wherein the r eaction ch amb er comprises an Atomic Layer Deposition (ALD) reaction chamber.
Layer stacks claimed or described, ordered top of device to substrate.
GaN-based hetero-junction field-effect transistor (HFET)
Materials described outside the worked examples.
oxy-nitride layer
aluminum nitride
AlN
silicon nitride
SiN
Additional fabrication and treatment steps described in the patent.
Performance values and ranges asserted in the specification or claims.
| Property | Value | Material |
|---|---|---|
Thickness | 2–10 nm | — |
Thickness |
Related documents with shared materials, methods, properties, or citations.
Patent
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US 9,343,541Patent drawings and their descriptions. Click a drawing to enlarge it.
FIGS. 1A-1C a re cross-sectiona l side vie w s that illu str a te an exam ple GaN- based HFET de vic e at var ious stag es i n a fa brication pr ocess, in acco …
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
The m eth od o f cla im 1 fu rther co mpris ng' 036 92. B₁₅₅C -13- Application forming, w ithi n the re action ch am ber, a silicon nitride l ayer ato p the oxy-ni tride lay er; a nd removing the wafer from the react ion chamber 13. The m eth od o f c laim 1 w here in the oxy-nitrde la yer is formed wi th a graded nitrogen composition that va n es from a hi ghes t at omi c per centage at or nea r the nitrde la yer to a low est at ormc percentage at or near a top surfac e of the oxy-n itri de layer 14 The m eth od of claim 1 where i n the n itride-b ased sem iconductor la yer compris es AI GaN 15 A method of fab ricating a multvl ayer stru ctu re f or a heter oJunction field- effect trans istor (HFET) device comprising. (a) exposing, wi thin the reacti on chamber, a top surface of a nitride- base d sem iconducto r layer to a first alu min um s ource. (b) exposi ng, withi n the react ion chamber, the w afer to a nitro gen (N) p las m a res ulting in the fo rmat ion o f an alum inum nitrid e (AIN) la yer at op the n i tride-base d se miconductor la yer, (c) exposing, within the react io n cha m ber, a top surface o f the AIN la yer t o a sec ond alu minu m s ou rce and (d) e xposing, within the react io n cha m ber, the wafer t o a nitrogen-ox ygen plas ma, res ulti ng i n the f ormation of an alum inum oxy- nit ri de (AION) layer atop the AIN la yer. wherein the nit ride la yer c ompr ses a p ass i vat ion lay er and the oxy- nit ride layer c omprn ses a gate d i elect ri c of the pow er transistor dev ice 036 92. B₁₅₅C -14-Application 16. The m eth o d of claim 15 wherein the first alu minum sou rce and the second alum inum sourc e b o th compnr se a tn-m eth y l al uminum (TMA) source 17 The m eth o d of cla im 15 furt her c ompnrsing re p eatin g steps (a) and (b) until the A IN l ayer is f o rmed t o a first th i ckness 18 The m eth o d of claim 17 wherein the first th ic kness is i n a ra nge o f a bou t 2-10 nm th ick. 19 The m eth od of claim 15 fu rther com pris ing repe ating steps (c) and (d) until the AI ON layer is f o rmed to a se co nd thi ck ness 20 The method of claim 19 w herein the second th ick ness is in a range of a bout 10 -25 nm th ick. 21 The m eth od of cla im 15 fu rther c om pris ing forming, wi thin the reacti on chamber, a sil ico n n itri de layer atop the AI O N layer 22 The method o f claim 15 w herein the AIO N layer is f o rmed w ith a graded nitro gen c ompositio n that va ri es from a highest at omi c percentage at o r near the nit ri de layer t o a low est at orm c percentage at o r near a t op surface o f the ox y-nitride layer 23 The m eth od o f cla im 15 wherein the nit ride- based se miconductor l ayer comprises AIGaN 036 92. B₁₅₅C -15- Application 24 A nitri de-ba se d heter o-junctio n f i eld-effect tran sis tor (HFVET) device comprising' a f irs t active semiconducto r layer, a sec on d act ive semiconducto r layer d ispos ed at op the f i rst active sem iconducto r layer, a t wo-dimension al electr on g as be ing forme d th e rebet ween, a multi -layer structu re that includes a firs t n itri de-ba s ed passi vat ion layer dispo sed d i rectly on the secon d a ctiv e sem icondu ctor layer, an d a n o xy- nitri de layer dispo sed d i rect ly on the f irst nitr de-ba s ed pa ssi vati on layer, the f irst nitrdeb ased p ass ivation layer hav in g a f i rst th ickn ess a n d the o xy- ni tride l ayer hav ing a sec ond thickness, the oxy-nitrde layer comprsing a g ate d i elect ric o f the nitride- based HFET dev i ce, a nd spaced-apart s ource an d dra in ohmic contacts directly on, or in re ce sses t hat exten d thr oug h t h e sec on d act iv e se miconducto r layer. 25 The nitr de-based HF ET dev ic e of cla im 24 w here in the first nitri de-ba sed pass ivation l ayer compri se AIN 26 The nitri de-ba sed FE T dev ic e of cla im 24 w her ein the first nitride-based pass ivation layer c ompri se SiN 27 The nit ri de- bas ed FE T de vice of claim 24 wherei n t he firs t t hicknesis is in a ran g e of ab out 2 -10 nm thick. 28 The ni tride-based FE T de vice o f cla im 24 w here i n the oxy- nit n de layer comprise s AI ON. 036 92. B₁₅₅C -16- Application 29. The nitrde-based HFET device of a m 24 wherei n the second thicknes s i s in a range of about 10 -25 nm th ick ABSTRA CT O F THE DISCLOSURE A m eth od of fabricating a m ult -layer structu re f or a pow er tr ansistor device incl ude s per forming, withi n a rea ction chamber, a nitrogen pl asma st rk e, result ing in the f ormation of a nitride layer directly on a nitride-based active semiconductor layer A top surf ace o f the n itri de lay er i s the n exp os ed t o a second source A su bsequ ent nitrogen-oxygen plasm a st rik e res ul ts in the f ormation o f a n oxy-nitrde lay er directly o n the nitri de la yer The nitride layer compris es a p assivation lay er and the oxy- nitri de layer compri ses a g ate die lectric o f the p ow er tra nsistor device. 036 92. B₁₅₅C -18- Application SVG 14154355.01-14-2014.HQFF₄ZYVPXXIFW3.SPEC11165086.3.332.3048.2178.3091.svg 0.143 6.153 Drawing Black and white Claims What is claimed is:
(W ith drawn) A ni tri d e-b ased hete ro-junction field-effec t t ransistor ([HF ET) device comprising: a firs t act iv e se miconductor layer; a second activ e semi conducto r l ayer disposed atop the first a cti ve semiconductor l aye r, a two-dimensional electron gas being forme d there between; a multi-la yer structu re that i ncludes a fi rst nitride-based pas sivat ion layer disposed direc tly on the second active semiconductor l ayer, a nd an oxy-n itr ide layer dispo sed d ire ctly on the fi rst nitri de- based pa ssivation l ayer the first nitride-b ased p assi vation layer ha ving a first t hickness and the oxy-n itri d e layer havi ng a se con d thi ckn ess, the oxy-n itride layer comp risi ng a g ate diele ctric of the n itr i de-based HFET de vic e; a nd spac ed-apart s ource and d rai n ohmic contac ts direc tly on, o r in recesses tha t e xten d thr oug h, the s econ d act iv e sem iconducto r layer. withdrawn
The nitride-based HFET device of claim 24 wherein the first nitride-based passivation layer comprise A IN. withdrawn
The nitride-based HFET device of claim 24 wherein the first nitride-based pass ivation layer comprise SiN, withdrawn
The nitride-based H F ET device of claim 24 wherein the first thickness is in a range of about 2-10 nm thick. Atto rn ey Docket No.: 03692.8155 C-2-Amendment and Response ClI ent Re f. No. P L.0 316.US.C001 withdrawn
The n i tride-based HFET device of claim 24 wherein the oxy-nitride layer comprises AION. withdrawn
The nitride-based HFET device of claim 24 wherein the second thickness is in a range of about 10-25 nm thick. withdrawn
A method of fabricating formirn a passivation plus gate dielectric rnultilaver structure for a power-transister hetero-iunction field-effect transistor (HFET) device comprising: (a) exposi n~ g, in a reaction chamber, a top surface of a nitride-based semiconductor wafer to a first source that forms a flm of material on the top surface; (b) performing, within the reaction chamber, a first plasma strike that reacts with the film to form a nitride-based passivation layer on the top surface; (c) exposing, in the reaction chamber, the nitride-based semiconductor wafer to a second source that results in a reaction of a material on a surface of the nitride-based passivation layer; (d) performing, within the reaction chamber, a second plasma strike tha t r eacts with the materi al t o form an oxy-nitride layer directly on the nitride- based passivation layer, t he nitride-based passivation layer and the oxy-nitride layer comprising a gate dielectric of the powertrnsistor HFET device.
(Previousl y pr esented) The method of claim 30 wherein the first source comprises aluminum (Al), the first plasma strike comprises nitrogen (N) and the nitride-based passivation layer comprises AIN. Atto rn ey Docket No.: Q 3692. B 155 C-3-Amendment and Response CIeni t Re f. No. PL 0 316. US.C001
(Pr eviously presented) Th e method of cla im 30 wherein the fi rst source comprises silicon (Si), t he fi rs t p lasma strike comprises n itr ogen (N) and the nitride-based passivation layer comprises SiN. 33, The method of cla im 30 wherein th e fi rst source comprises a tri-methyl aluminum (TMA) source. 34, The method of claim 30 further comprising repeating steps (a) and (b) until the nitride-based passivation layer is formed to a firs t t hickness.
(Previously amended) The metho d of claim 30 further comprising, before step (a), loading the nitride-based semiconductor wafer into a reaction chamber, the n itri de-based semiconductor wafer not being removed from the reaction chamber until completion of steps (a)-d). Docket No.: 03692.8155-4-Amendment and Response SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.3.20.374.3062.532.3100.svg 0.127 0.527 Chemistry Black and white CI ent Re f. No. P L.0 316.US. C 001 39, (Pr evious ly presented) The method of claim 30 further comprises forming a silicon nitride lay er atop the oxy-nitride layer; wherein the oxy-nitride laye r is formed with a graded nitrogen composition that varies from a hi ghest atomic percentag e a t or ne ar the silicon nitride layer to a lowest atomic percentage at or near the oxy-nitride la yer.
(Previous ly presented) The method of claim 30 wherein the t op surface of the ni tri de-based semiconductor wafer comprises an AlGaN layer.
(Previous ly pr esented) The method of claim 30 wherein the f ilm of material comprises al uminum. 45, (Pr evious ly presented) The method of claim 30 wherein the film of materi al comprises silicon. Docket No.: Q3692.B₁₅₅C-- Amendment and Response SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.4.19.1301.3054.1325.3092.svg 0.127 0.08 Chemistry Black and white SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.4.19.374.3062.532.3100.svg 0.127 0.527 Chemistry Black and white CIeni t Re f. No. P L.0 316.US.C 001
(Previously amended) The metho d of c laim 34 further comprising repeating steps (c) and (d) until the oxy-n itri de layer is formed to a second thickness, the second thickness being greater than the fi r st t hickness.
Th e method of claim 34 wherein the fi rst thickness is in a range of about 2-10 nm thick.
The method of cl aim 35 wherein th e s econd thickness is in a range of about 10-25 nnm thick.
(Previous ly presented) Th e method of c lai m 40 wherein the AIGaN layer is formed at o p a GaN layer, a two dimensional ele ctr on gas channel (2- DUG) being formed a an interface between the A IGaN layer a n d t he GaN layer.
canceled
, (Previous ly presented) Th e m eth od of c lai m 30 wherein the r eaction ch amb er comprises an Atomic Layer Deposition (ALD) reaction chamber.
Layer stacks claimed or described, ordered top of device to substrate.
GaN-based hetero-junction field-effect transistor (HFET)
Materials described outside the worked examples.
oxy-nitride layer
aluminum nitride
AlN
silicon nitride
SiN
Additional fabrication and treatment steps described in the patent.
Performance values and ranges asserted in the specification or claims.
| Property | Value | Material |
|---|---|---|
Thickness | 2–10 nm | — |
Thickness |
Related documents with shared materials, methods, properties, or citations.
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Atlas literature
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US 9,343,541Patent drawings and their descriptions. Click a drawing to enlarge it.
FIGS. 1A-1C a re cross-sectiona l side vie w s that illu str a te an exam ple GaN- based HFET de vic e at var ious stag es i n a fa brication pr ocess, in acco …
Claims define the patent's legal scope. Independent claims stand alone; dependent claims (nested) narrow them. Click a claim to expand its dependents.
The m eth od o f cla im 1 fu rther co mpris ng' 036 92. B₁₅₅C -13- Application forming, w ithi n the re action ch am ber, a silicon nitride l ayer ato p the oxy-ni tride lay er; a nd removing the wafer from the react ion chamber 13. The m eth od o f c laim 1 w here in the oxy-nitrde la yer is formed wi th a graded nitrogen composition that va n es from a hi ghes t at omi c per centage at or nea r the nitrde la yer to a low est at ormc percentage at or near a top surfac e of the oxy-n itri de layer 14 The m eth od of claim 1 where i n the n itride-b ased sem iconductor la yer compris es AI GaN 15 A method of fab ricating a multvl ayer stru ctu re f or a heter oJunction field- effect trans istor (HFET) device comprising. (a) exposing, wi thin the reacti on chamber, a top surface of a nitride- base d sem iconducto r layer to a first alu min um s ource. (b) exposi ng, withi n the react ion chamber, the w afer to a nitro gen (N) p las m a res ulting in the fo rmat ion o f an alum inum nitrid e (AIN) la yer at op the n i tride-base d se miconductor la yer, (c) exposing, within the react io n cha m ber, a top surface o f the AIN la yer t o a sec ond alu minu m s ou rce and (d) e xposing, within the react io n cha m ber, the wafer t o a nitrogen-ox ygen plas ma, res ulti ng i n the f ormation of an alum inum oxy- nit ri de (AION) layer atop the AIN la yer. wherein the nit ride la yer c ompr ses a p ass i vat ion lay er and the oxy- nit ride layer c omprn ses a gate d i elect ri c of the pow er transistor dev ice 036 92. B₁₅₅C -14-Application 16. The m eth o d of claim 15 wherein the first alu minum sou rce and the second alum inum sourc e b o th compnr se a tn-m eth y l al uminum (TMA) source 17 The m eth o d of cla im 15 furt her c ompnrsing re p eatin g steps (a) and (b) until the A IN l ayer is f o rmed t o a first th i ckness 18 The m eth o d of claim 17 wherein the first th ic kness is i n a ra nge o f a bou t 2-10 nm th ick. 19 The m eth od of claim 15 fu rther com pris ing repe ating steps (c) and (d) until the AI ON layer is f o rmed to a se co nd thi ck ness 20 The method of claim 19 w herein the second th ick ness is in a range of a bout 10 -25 nm th ick. 21 The m eth od of cla im 15 fu rther c om pris ing forming, wi thin the reacti on chamber, a sil ico n n itri de layer atop the AI O N layer 22 The method o f claim 15 w herein the AIO N layer is f o rmed w ith a graded nitro gen c ompositio n that va ri es from a highest at omi c percentage at o r near the nit ri de layer t o a low est at orm c percentage at o r near a t op surface o f the ox y-nitride layer 23 The m eth od o f cla im 15 wherein the nit ride- based se miconductor l ayer comprises AIGaN 036 92. B₁₅₅C -15- Application 24 A nitri de-ba se d heter o-junctio n f i eld-effect tran sis tor (HFVET) device comprising' a f irs t active semiconducto r layer, a sec on d act ive semiconducto r layer d ispos ed at op the f i rst active sem iconducto r layer, a t wo-dimension al electr on g as be ing forme d th e rebet ween, a multi -layer structu re that includes a firs t n itri de-ba s ed passi vat ion layer dispo sed d i rectly on the secon d a ctiv e sem icondu ctor layer, an d a n o xy- nitri de layer dispo sed d i rect ly on the f irst nitr de-ba s ed pa ssi vati on layer, the f irst nitrdeb ased p ass ivation layer hav in g a f i rst th ickn ess a n d the o xy- ni tride l ayer hav ing a sec ond thickness, the oxy-nitrde layer comprsing a g ate d i elect ric o f the nitride- based HFET dev i ce, a nd spaced-apart s ource an d dra in ohmic contacts directly on, or in re ce sses t hat exten d thr oug h t h e sec on d act iv e se miconducto r layer. 25 The nitr de-based HF ET dev ic e of cla im 24 w here in the first nitri de-ba sed pass ivation l ayer compri se AIN 26 The nitri de-ba sed FE T dev ic e of cla im 24 w her ein the first nitride-based pass ivation layer c ompri se SiN 27 The nit ri de- bas ed FE T de vice of claim 24 wherei n t he firs t t hicknesis is in a ran g e of ab out 2 -10 nm thick. 28 The ni tride-based FE T de vice o f cla im 24 w here i n the oxy- nit n de layer comprise s AI ON. 036 92. B₁₅₅C -16- Application 29. The nitrde-based HFET device of a m 24 wherei n the second thicknes s i s in a range of about 10 -25 nm th ick ABSTRA CT O F THE DISCLOSURE A m eth od of fabricating a m ult -layer structu re f or a pow er tr ansistor device incl ude s per forming, withi n a rea ction chamber, a nitrogen pl asma st rk e, result ing in the f ormation of a nitride layer directly on a nitride-based active semiconductor layer A top surf ace o f the n itri de lay er i s the n exp os ed t o a second source A su bsequ ent nitrogen-oxygen plasm a st rik e res ul ts in the f ormation o f a n oxy-nitrde lay er directly o n the nitri de la yer The nitride layer compris es a p assivation lay er and the oxy- nitri de layer compri ses a g ate die lectric o f the p ow er tra nsistor device. 036 92. B₁₅₅C -18- Application SVG 14154355.01-14-2014.HQFF₄ZYVPXXIFW3.SPEC11165086.3.332.3048.2178.3091.svg 0.143 6.153 Drawing Black and white Claims What is claimed is:
(W ith drawn) A ni tri d e-b ased hete ro-junction field-effec t t ransistor ([HF ET) device comprising: a firs t act iv e se miconductor layer; a second activ e semi conducto r l ayer disposed atop the first a cti ve semiconductor l aye r, a two-dimensional electron gas being forme d there between; a multi-la yer structu re that i ncludes a fi rst nitride-based pas sivat ion layer disposed direc tly on the second active semiconductor l ayer, a nd an oxy-n itr ide layer dispo sed d ire ctly on the fi rst nitri de- based pa ssivation l ayer the first nitride-b ased p assi vation layer ha ving a first t hickness and the oxy-n itri d e layer havi ng a se con d thi ckn ess, the oxy-n itride layer comp risi ng a g ate diele ctric of the n itr i de-based HFET de vic e; a nd spac ed-apart s ource and d rai n ohmic contac ts direc tly on, o r in recesses tha t e xten d thr oug h, the s econ d act iv e sem iconducto r layer. withdrawn
The nitride-based HFET device of claim 24 wherein the first nitride-based passivation layer comprise A IN. withdrawn
The nitride-based HFET device of claim 24 wherein the first nitride-based pass ivation layer comprise SiN, withdrawn
The nitride-based H F ET device of claim 24 wherein the first thickness is in a range of about 2-10 nm thick. Atto rn ey Docket No.: 03692.8155 C-2-Amendment and Response ClI ent Re f. No. P L.0 316.US.C001 withdrawn
The n i tride-based HFET device of claim 24 wherein the oxy-nitride layer comprises AION. withdrawn
The nitride-based HFET device of claim 24 wherein the second thickness is in a range of about 10-25 nm thick. withdrawn
A method of fabricating formirn a passivation plus gate dielectric rnultilaver structure for a power-transister hetero-iunction field-effect transistor (HFET) device comprising: (a) exposi n~ g, in a reaction chamber, a top surface of a nitride-based semiconductor wafer to a first source that forms a flm of material on the top surface; (b) performing, within the reaction chamber, a first plasma strike that reacts with the film to form a nitride-based passivation layer on the top surface; (c) exposing, in the reaction chamber, the nitride-based semiconductor wafer to a second source that results in a reaction of a material on a surface of the nitride-based passivation layer; (d) performing, within the reaction chamber, a second plasma strike tha t r eacts with the materi al t o form an oxy-nitride layer directly on the nitride- based passivation layer, t he nitride-based passivation layer and the oxy-nitride layer comprising a gate dielectric of the powertrnsistor HFET device.
(Previousl y pr esented) The method of claim 30 wherein the first source comprises aluminum (Al), the first plasma strike comprises nitrogen (N) and the nitride-based passivation layer comprises AIN. Atto rn ey Docket No.: Q 3692. B 155 C-3-Amendment and Response CIeni t Re f. No. PL 0 316. US.C001
(Pr eviously presented) Th e method of cla im 30 wherein the fi rst source comprises silicon (Si), t he fi rs t p lasma strike comprises n itr ogen (N) and the nitride-based passivation layer comprises SiN. 33, The method of cla im 30 wherein th e fi rst source comprises a tri-methyl aluminum (TMA) source. 34, The method of claim 30 further comprising repeating steps (a) and (b) until the nitride-based passivation layer is formed to a firs t t hickness.
(Previously amended) The metho d of claim 30 further comprising, before step (a), loading the nitride-based semiconductor wafer into a reaction chamber, the n itri de-based semiconductor wafer not being removed from the reaction chamber until completion of steps (a)-d). Docket No.: 03692.8155-4-Amendment and Response SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.3.20.374.3062.532.3100.svg 0.127 0.527 Chemistry Black and white CI ent Re f. No. P L.0 316.US. C 001 39, (Pr evious ly presented) The method of claim 30 further comprises forming a silicon nitride lay er atop the oxy-nitride layer; wherein the oxy-nitride laye r is formed with a graded nitrogen composition that varies from a hi ghest atomic percentag e a t or ne ar the silicon nitride layer to a lowest atomic percentage at or near the oxy-nitride la yer.
(Previous ly presented) The method of claim 30 wherein the t op surface of the ni tri de-based semiconductor wafer comprises an AlGaN layer.
(Previous ly pr esented) The method of claim 30 wherein the f ilm of material comprises al uminum. 45, (Pr evious ly presented) The method of claim 30 wherein the film of materi al comprises silicon. Docket No.: Q3692.B₁₅₅C-- Amendment and Response SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.4.19.1301.3054.1325.3092.svg 0.127 0.08 Chemistry Black and white SVG 14154355.12-14-2015.II₉₁IMH₅PXXIFW1.CLM.4.19.374.3062.532.3100.svg 0.127 0.527 Chemistry Black and white CIeni t Re f. No. P L.0 316.US.C 001
(Previously amended) The metho d of c laim 34 further comprising repeating steps (c) and (d) until the oxy-n itri de layer is formed to a second thickness, the second thickness being greater than the fi r st t hickness.
Th e method of claim 34 wherein the fi rst thickness is in a range of about 2-10 nm thick.
The method of cl aim 35 wherein th e s econd thickness is in a range of about 10-25 nnm thick.
(Previous ly presented) Th e method of c lai m 40 wherein the AIGaN layer is formed at o p a GaN layer, a two dimensional ele ctr on gas channel (2- DUG) being formed a an interface between the A IGaN layer a n d t he GaN layer.
canceled
, (Previous ly presented) Th e m eth od of c lai m 30 wherein the r eaction ch amb er comprises an Atomic Layer Deposition (ALD) reaction chamber.
Layer stacks claimed or described, ordered top of device to substrate.
GaN-based hetero-junction field-effect transistor (HFET)
Materials described outside the worked examples.
oxy-nitride layer
aluminum nitride
AlN
silicon nitride
SiN
Additional fabrication and treatment steps described in the patent.
Performance values and ranges asserted in the specification or claims.
| Property | Value | Material |
|---|---|---|
Thickness | 2–10 nm | — |
Thickness |
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tri-methyl aluminum
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silicon
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SiON
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| — |
aluminum oxy-nitride
AlON
tri-methyl aluminum
Al(CH₃)3
silicon
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silicon oxy-nitride
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aluminum oxy-nitride
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tri-methyl aluminum
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silicon
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